The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Interfacial Frustrated Lewis Pairs of CeO2 Activate CO2 for Selective Tandem Transformation of Olefins and CO2 into Cyclic Carbonates
Abstract
Effective activation of CO 2 is a prerequisite for efficient utilization of CO 2 in organic synthesis. Precisely controlling the interfacial events of solids shows potential for activation. Herein, defect-enriched CeO 2 with constructed interfacial frustrated Lewis pairs (FLPs, two adjacent Ce 3+ ···O 2– ) effectively activates CO 2 via the interactions between C/Lewis basic lattice O 2– and the two O atoms in CO 2 /two adjacent Lewis acidic Ce 3+ ions. Selective cyclic carbonate production from a catalytically tandem protocol of olefins and CO 2 is used to demonstrate FLP-inspired CO 2 activation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Aresta, M., Dibenedetto, A., & Angelini, A. (2014) · Chemical Reviews · doi:10.1021/cr4002758 · Cited by 3,143
Fundamentals and Catalytic Applications of CeO 2 -Based Materials
Montini, T., Melchionna, M., Monai, M., & Fornasiero, P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00603 · Cited by 2,766
Using carbon dioxide as a building block in organic synthesis
Liu, Q., Wu, L., Jackstell, R., & Beller, M. (2015) · Nature Communications · doi:10.1038/ncomms6933 · Cited by 2,169
Mai, H.-X., Sun, L.-D., Zhang, Y.-W., Si, R., Feng, W., Zhang, H.-P., Liu, H.-C., & Yan, C.-H. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp055584b · Cited by 1,625
Oxygen Vacancy Clusters Promoting Reducibility and Activity of Ceria Nanorods
Liu, X., Zhou, K., Wang, L., Wang, B., & Li, Y. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808433d · Cited by 1,276
Stephan, D. W. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06794 · Cited by 1,178
Frustrated Lewis Pairs: From Concept to Catalysis
Stephan, D. W. (2015) · Accounts of Chemical Research · doi:10.1021/ar500375j · Cited by 1,147
Zhang, L., Zhao, Z., & Gong, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201612214 · Cited by 1,048
Low-dimensional catalysts for hydrogen evolution and CO2 reduction
Voiry, D., Shin, H. S., Loh, K. P., & Chhowalla, M. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-017-0105 · Cited by 848
Nolan, M., Grigoleit, S., Sayle, D. C., Parker, S. C., & Watson, G. W. (2005) · Surface Science · doi:10.1016/j.susc.2004.12.016 · Cited by 779
Single-Atomic Cu with Multiple Oxygen Vacancies on Ceria for Electrocatalytic CO2 Reduction to CH4
Wang, Y., Chen, Z., Han, P., Du, Y., Gu, Z., Xu, X., & Zheng, G. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b01014 · Cited by 682
On the structure dependence of CO oxidation over CeO2 nanocrystals with well-defined surface planes
Wu, Z., Li, M., & Overbury, S. H. (2012) · Journal of Catalysis · doi:10.1016/j.jcat.2011.09.011 · Cited by 647
Room Temperature Reduction of CO2 to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane
Ménard, G., & Stephan, D. W. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9104792 · Cited by 572
Zhang, S., Huang, Z.-Q., Ma, Y., Gao, W., Li, J., Cao, F., Li, L., Chang, C.-R., & Qu, Y. (2017) · Nature Communications · doi:10.1038/ncomms15266 · Cited by 508
Self-citationCeria‐Based Solid Catalysts for Organic Chemistry
Vivier, L., & Duprez, D. (2010) · ChemSusChem · doi:10.1002/cssc.201000054 · Cited by 391
Wang, Y., Wang, F., Song, Q., Xin, Q., Xu, S., & Xu, J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja310498c · Cited by 324
Han, Q., Qi, B., Ren, W., He, C., Niu, J., & Duan, C. (2015) · Nature Communications · doi:10.1038/ncomms10007 · Cited by 318
Fast CO2 Sequestration, Activation, and Catalytic Transformation Using N-Heterocyclic Olefins
Wang, Y.-B., Wang, Y.-M., Zhang, W.-Z., & Lu, X.-B. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405114e · Cited by 314
Tian, Z., Li, J., Zhang, Z., Gao, W., Zhou, X., & Qu, Y. (2015) · Biomaterials · doi:10.1016/j.biomaterials.2015.04.039 · Cited by 261
Self-citationMorphology-dependent surface chemistry and catalysis of CeO2nanocrystals
Huang, W., & Gao, Y. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00679h · Cited by 242
Nano-designed semiconductors for electro- and photoelectro-catalytic conversion of carbon dioxide
Zhang, L., Zhao, Z.-J., Wang, T., & Gong, J. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00016f · Cited by 233
Stoichiometric Reduction of CO2 to CO by Aluminum‐Based Frustrated Lewis Pairs
Ménard, G., & Stephan, D. W. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103600 · Cited by 214
Jiang, Y., Blacque, O., Fox, T., & Berke, H. (2013) · Journal of the American Chemical Society · doi:10.1021/ja402381d · Cited by 196
Carbon Dioxide Reduction to Methylamines under Metal‐Free Conditions
Blondiaux, E., Pouessel, J., & Cantat, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201407357 · Cited by 192
Probing Surface Structures of CeO2, TiO2, and Cu2O Nanocrystals with CO and CO2 Chemisorption
Chen, S., Cao, T., Gao, Y., Li, D., Xiong, F., & Huang, W. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b06158 · Cited by 192
Selective Reduction of CO2 to CH4 by Tandem Hydrosilylation with Mixed Al/B Catalysts
Chen, J., Falivene, L., Caporaso, L., Cavallo, L., & Chen, E. Y.-X. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01497 · Cited by 171
Bregante, D. T., & Flaherty, D. W. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b01422 · Cited by 168
Caballero, A., Holgado, J. P., Gonzalez-delaCruz, V. M., Habas, S. E., Herranz, T., & Salmeron, M. (2010) · Chem. Commun. · doi:10.1039/b920803h · Cited by 162
Lewis base-CO2 adducts as organocatalysts for CO2 transformation
Zhou, H., & Lu, X. (2017) · Science China Chemistry · doi:10.1007/s11426-016-0442-5 · Cited by 73
Microfluidic Studies of CO2 Sequestration by Frustrated Lewis Pairs
Voicu, D., Abolhasani, M., Choueiri, R. M., Lestari, G., Seiler, C., Ménard, G., Greener, J., Günther, A., Stephan, D. W., & Kumacheva, E. (2014) · Journal of the American Chemical Society · doi:10.1021/ja411601a · Cited by 72
A Free Energy Landscape of CO 2 Capture by Frustrated Lewis Pairs
Liu, L., Lukose, B., & Ensing, B. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b04072 · Cited by 48
Cited by
Zhao, X., Chang, G., Xu, H., Yao, Y., Dong, D., Yang, S., Tian, G., & Yang, X. (2024) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.3c18885 · Cited by 33
Hierarchical Amino-Functionalized Ionic Liquids@MOF Composite Gel for Catalytic Conversion of CO2
Dong, D., Zhao, X., Pu, C., Yao, Y., Zhao, B., Tian, G., Chang, G., & Yang, X. (2023) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03923 · Cited by 17
Metadata
- Authors
- Zhang, S., Xia, Z., Zou, Y., Cao, F., Liu, Y., Ma, Y., & Qu, Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-07-10
- Volume
- 141
- Issue
- 29
- Pages
- 11353-11357
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2957108895
- Cited by
- 304
- References
- 31
- FWCI
- 5.95
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.