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High-Performance Liquid Chromatography (HPLC) Analysis of Phenolic Compounds in Berries with Diode Array and Electrospray Ionization Mass Spectrometric (MS) Detection: Ribes Species

Määttä, Kaisu R., Kamal-Eldin, Afaf, Törrönen, A. Riitta·2003·Journal of Agricultural and Food Chemistry

Abstract

High-performance liquid chromatography combined with diode array and electrospray ionization mass spectrometric (MS) detection was used to study phenolic compounds in berries of black, green, red, and white currants (Ribes spp.). UV-visible spectrometry was a valuable tool for the identification of the class of the phenolic compound, whereas MS and MS-MS fragmentation data were useful for further structural characterization. Distinct similarities were found in the relative distribution of conjugated forms of phenolic compounds among the four currants. Phenolic acids were found mainly as hexose esters. Flavonol glycosides and anthocyanin pigments were mainly found as 3-O-rutinosides and second as 3-O-glucosides. However, cyanidin 3-O-sambubioside and quercetin hexoside-malonate were notable phenolic compounds in red currant. Flavonol hexoside-malonates were identified and quantified in the berries of currants for the first time.

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Metadata

Authors
Määttä, K. R., Kamal-Eldin, A., & Törrönen, A. R.
Venue
Journal of Agricultural and Food Chemistry
Published
2003-10-09
Volume
51
Issue
23
Pages
6736-6744
ISSN
  • 0021-8561 (ISSN-L)
  • 1520-5118
OpenAlex
W2022205176
Cited by
266
References
2
FWCI
5.71
Type
journal article
Language
en
Open access
closed

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