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Mechanistic Insight into the TiO2Photocatalytic Reactions: Design of New Photocatalysts
Abstract
Titanium dioxide (TiO 2 ) has been extensively investigated for the photocatalytic purification of air and water. In this article, we have focused on the mechanisms of the one-electron redox reactions of organic compounds during the TiO 2 photocatalytic reactions and on the development of TiO 2 -based materials. It was clearly demonstrated that the adsorption dynamics of substrates and intermediates, the electronic interaction between TiO 2 and adsorbates, and the band structure and morphology of TiO 2 nanomaterials are crucial factors for establishing efficient photocatalytic reaction systems. The TiO 2 -based hybrid nanoparticles with various functional materials, such as polyoxometalates (POMs) and cyclodextrins (CDs), have been fabricated on the basis of the mechanistic aspects. New experimental methods, such as two-color two-laser flash photolysis and single-molecule fluorescence techniques, for the investigation of the TiO 2 photocatalytic reactions have been demonstrated.
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Self-citationPhotocatalytic Reaction Sites at the TiO2 Surface as Studied by Solid-State 1H NMR Spectroscopy
Nosaka, A. Y., Fujiwara, T., Yagi, H., et al. (2003) · Langmuir · doi:10.1021/la0268146 · Cited by 40
Single-Molecule Fluorescence Imaging of the Remote TiO2 Photocatalytic Oxidation
Naito, K., Tachikawa, T., Fujitsuka, M., & Majima, T. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0556005 · Cited by 39
Self-citationDas, T. N., Ghanty, T. K., & Pal, H. (2003) · The Journal of Physical Chemistry A · doi:10.1021/jp022614r · Cited by 35
Tachikawa, T., Yui, T., Fujitsuka, M., Takagi, K., & Majima, T. (2005) · Chemistry Letters · doi:10.1246/cl.2005.1522 · Cited by 19
Self-citation
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Metadata
- Authors
- Tachikawa, T., Fujitsuka, M., & Majima, T.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-21
- Volume
- 111
- Issue
- 14
- Pages
- 5259-5275
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2034336389
- Cited by
- 668
- References
- 126
- FWCI
- 22.44
- Type
- journal article
- Language
- en
- Open access
- closed
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Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.