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Hydrogen Production by Photocatalytic Water Splitting over Pt/TiO2 Nanosheets with Exposed (001) Facets
Abstract
Pt/TiO 2 nanosheets with exposed (001) facets were fabricated by a simple hydrothermal route in a Ti(OC 4 H 9 ) 4 -HF-H 2 O mixed solution followed by a photochemical reduction deposition of Pt nanoparticles on TiO 2 nanosheets under xenon lamp irradiation. The prepared samples were characterized by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption−desorption isotherms, UV−vis diffuse reflectance spectroscopy, and photoluminescence (PL) spectroscopy. Production of • OH radicals on the TiO 2 surface was detected by the PL technique using coumarin as a probe molecule. The effects of Pt loading on the rates of photocatalytic hydrogen production of the as-prepared samples in ethanol aqueous solution were investigated and discussed. The results showed that the photocatalytic hydrogen production rates of TiO 2 nanosheets from the ethanol aqueous solutions were significantly enhanced by loaded Pt on the TiO 2 nanosheets, and the latter with a 2 wt % of deposited Pt exhibited the highest photocatalytic activity. All fluorinated TiO 2 nanosheets exhibited much higher photocatalytic activity than Degussa P25 TiO 2 and pure TiO 2 nanoparticles prepared in pure water due to the synergistic effect of surface fluorination and exposed (001) facets.
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Metadata
- Authors
- Yu, J., Qi, L., & Jaroniec, M.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-07-13
- Volume
- 114
- Issue
- 30
- Pages
- 13118-13125
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2074466629
- Cited by
- 1,174
- References
- 4
- FWCI
- 27.28
- Type
- journal article
- Language
- en
- Open access
- closed
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