The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Electrochemical CO2 and CO Reduction on Metal-Functionalized Porphyrin-like Graphene
Abstract
Porphyrin-like metal-functionalized graphene structures have been investigated as possible catalysts for CO 2 and CO reduction to methane or methanol. The late transition metals (Cu, Ag, Au, Ni, Pd, Pt, Co, Rh, Ir, Fe, Ru, Os) and some p (B, Al, Ga) and s (Mg) metals comprised the center of the porphyrin ring. A clear difference in catalytic properties compared to extended metal surfaces was observed owing to a different electronic nature of the active site. The preference to bind hydrogen, however, becomes a major obstacle in the reaction path. A possible solution to this problem is to reduce CO instead of CO 2 . Volcano plots were constructed on the basis of scaling relations of reaction intermediates, and from these plots the reaction steps with the highest overpotentials were deduced. The Rh–porphyrin-like functionalized graphene was identified as the most active catalyst for producing methanol from CO, featuring an overpotential of 0.22 V. Additionally, we have also examined the hydrogen evolution and oxidation reaction, and in their case, too, Rh–porphyrin turned out to be the best catalyst with an overpotential of 0.15 V.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
Self-citationGasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Self-citationHori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Abild-Pedersen, F., Greeley, J., Studt, F., Rossmeisl, J., Munter, T. R., Moses, P. G., Skúlason, E., Bligaard, T., & Nørskov, J. K. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.016105 · Cited by 1,678
Self-citationActivity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Skúlason, E., Tripkovic, V., Björketun, M. E., Gudmundsdóttir, S., Karlberg, G., Rossmeisl, J., Bligaard, T., Jónsson, H., & Nørskov, J. K. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1048887 · Cited by 1,271
Self-citation
Cited by
Zheng, Y., Jiao, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407031 · Cited by 2,046
Fei, H., Dong, J., Feng, Y., Allen, C. S., Wan, C., Volosskiy, B., Li, M., Zhao, Z., Wang, Y., Sun, H., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0008-y · Cited by 1,973
Ju, W., Bagger, A., Hao, G.-P., Varela, A. S., Sinev, I., Bon, V., Roldan Cuenya, B., Kaskel, S., Rossmeisl, J., & Strasser, P. (2017) · Nature Communications · doi:10.1038/s41467-017-01035-z · Cited by 1,203
Self-citationDomino electroreduction of CO2 to methanol on a molecular catalyst
Wu, Y., Jiang, Z., Lu, X., Liang, Y., & Wang, H. (2019) · Nature · doi:10.1038/s41586-019-1760-8 · Cited by 1,194
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08212 · Cited by 1,158
Hydrolysis of Electrolyte Cations Enhances the Electrochemical Reduction of CO 2 over Ag and Cu
Singh, M. R., Kwon, Y., Lum, Y., Ager, J. W., & Bell, A. T. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b07612 · Cited by 985
In Situ/Operando Electrocatalyst Characterization by X-ray Absorption Spectroscopy
Timoshenko, J., & Roldan Cuenya, B. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00396 · Cited by 931
Coordinatively unsaturated nickel–nitrogen sites towards selective and high-rate CO2electroreduction
Yan, C., Li, H., Ye, Y., Wu, H., Cai, F., Si, R., Xiao, J., Miao, S., Xie, S., Yang, F., et al. (2018) · Energy & Environmental Science · doi:10.1039/c8ee00133b · Cited by 768
Single atom electrocatalysts supported on graphene or graphene-like carbons
Fei, H., Dong, J., Chen, D., Hu, T., Duan, X., Shakir, I., Huang, Y., & Duan, X. (2019) · Chemical Society Reviews · doi:10.1039/c9cs00422j · Cited by 673
Pan, F., Zhang, H., Liu, K., Cullen, D., More, K., Wang, M., Feng, Z., Wang, G., Wu, G., & Li, Y. (2018) · ACS Catalysis · doi:10.1021/acscatal.8b00398 · Cited by 512
Atomic layer confined vacancies for atomic-level insights into carbon dioxide electroreduction
Gao, S., Sun, Z., Liu, W., Jiao, X., Zu, X., Hu, Q., Sun, Y., Yao, T., Zhang, W., Wei, S., et al. (2017) · Nature Communications · doi:10.1038/ncomms14503 · Cited by 469
Lim, R. J., Xie, M., Sk, M. A., Lee, J.-M., Fisher, A., Wang, X., & Lim, K. H. (2014) · Catalysis Today · doi:10.1016/j.cattod.2013.11.037 · Cited by 460
Electrocatalytic reduction of carbon dioxide: opportunities with heterogeneous molecular catalysts
Sun, L., Reddu, V., Fisher, A. C., & Wang, X. (2020) · Energy & Environmental Science · doi:10.1039/c9ee03660a · Cited by 452
Electrochemical Reduction of CO2 Catalyzed by Fe-N-C Materials: A Structure–Selectivity Study
Huan, T. N., Ranjbar, N., Rousse, G., Sougrati, M., Zitolo, A., Mougel, V., Jaouen, F., & Fontecave, M. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b03353 · Cited by 444
Jiang, K., Siahrostami, S., Akey, A. J., Li, Y., Lu, Z., Lattimer, J., Hu, Y., Stokes, C., Gangishetty, M., Chen, G., et al. (2017) · Chem · doi:10.1016/j.chempr.2017.09.014 · Cited by 406
Wu, J., Sharifi, T., Gao, Y., Zhang, T., & Ajayan, P. M. (2019) · Advanced Materials · doi:10.1002/adma.201804257 · Cited by 325
Mikulčić, H., Ridjan Skov, I., Dominković, D. F., Wan Alwi, S. R., Manan, Z. A., Tan, R., Duić, N., Hidayah Mohamad, S. N., & Wang, X. (2019) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2019.109338 · Cited by 299
Zhao, Y., Liang, J., Wang, C., Ma, J., & Wallace, G. G. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702524 · Cited by 283
Li, Y., Su, H., Chan, S. H., & Sun, Q. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01165 · Cited by 265
Selective Heterogeneous CO2 Electroreduction to Methanol
Back, S., Kim, H., & Jung, Y. (2015) · ACS Catalysis · doi:10.1021/cs501600x · Cited by 201
Intermetallic Alloys as CO Electroreduction Catalysts—Role of Isolated Active Sites
Karamad, M., Tripkovic, V., & Rossmeisl, J. (2014) · ACS Catalysis · doi:10.1021/cs500328c · Cited by 125
Self-citation
Metadata
- Authors
- Tripkovic, V., Vanin, M., Karamad, M., Björketun, M. E., Jacobsen, K. W., Thygesen, K. S., & Rossmeisl, J.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-26
- Volume
- 117
- Issue
- 18
- Pages
- 9187-9195
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2012180862
- Cited by
- 304
- References
- 7
- FWCI
- 6.25
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
