A review on the electrochemical reduction of CO2 in fuel cells, metal electrodes and molecular catalysts
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Larger cation concentrations can greatly reduce charge transfer resistances by helping to stabilize the *CO2- anion radical and leading to higher current densities at the same applied potentials.
“Moreover, larger cation concentrations can greatly reduce charge transfer resistances by helping to stabilize the *CO2 -anion radical and leading to higher current densities at the same applied potentials.[190,210,211]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [190]
Verma et al. discovered that the best selectivity and lowest overpotentials for CO production were obtained in the order OH- > HCO3- > Cl-.
“Verma et al. discovered that the best selectivity and lowest overpotentials for CO production were obtained in the order: OH -> HCO3 -> Cl -. [190]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [190]
Verma et al. suggested that weakly solvated anions, such as Cl-, interact directly with the electrode surface and can destabilize the *CO2- intermediate, unlike smaller, more-hydrated anions which are located further away.
“They suggested that weakly solvated anions, such as Cl -, interact directly with the electrode surface and can destabilize the *CO2 - intermediate, unlike smaller, more-hydrated, anions which are located further away (Figure .11).”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [190]
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Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
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- Authors
- Lim, R. J., Xie, M., Sk, M. A., Lee, J.-M., Fisher, A., Wang, X., & Lim, K. H.
- Affiliations
- Nanyang Technological University (SG)
- University of Cambridge (GB)
- Corresponding author
- Lim, Kok Hwa
- Venue
- Catalysis Today
- Publisher
- Elsevier BV
- Published
- 2014-09
- Volume
- 233
- Pages
- 169-180
- ISSN
- 0920-5861 (ISSN-L)
- OpenAlex
- W2044804811
- Cited by
- 460
- References
- 141
- Citations by year
- 2026: 11 · 2025: 19 · 2024: 31 · 2023: 32 · 2022: 26 · 2021: 64 · 2020: 58 · 2019: 50 · 2018: 49 · 2017: 33 · 2016: 46 · 2015: 36 · 2014: 5
- FWCI
- 10.55
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Catalysis Today (publishedVersion)
- DR-NTU (Nanyang Technological University) (submittedVersion)
- Funders
- National Research Foundation Singapore
- Ministry of Education - Singapore (RG73/10, RG8/12)
- Nanyang Technological University
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, fuel cells, metal electrodes, molecular catalysts, aqueous electrolyte solutions, reaction mechanism, density functional theory, current density
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