The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide
Open accessAbstract
A key challenge in the field of electrochemical carbon dioxide reduction is the design of catalytic materials featuring high product selectivity, stability, and a composition of earth-abundant elements. In this work, we introduce thin films of nanosized metal-organic frameworks (MOFs) as atomically defined and nanoscopic materials that function as catalysts for the efficient and selective reduction of carbon dioxide to carbon monoxide in aqueous electrolytes. Detailed examination of a cobalt-porphyrin MOF, Al2(OH)2TCPP-Co (TCPP-H2 = 4,4',4″,4‴-(porphyrin-5,10,15,20-tetrayl)tetrabenzoate) revealed a selectivity for CO production in excess of 76% and stability over 7 h with a per-site turnover number (TON) of 1400. In situ spectroelectrochemical measurements provided insights into the cobalt oxidation state during the course of reaction and showed that the majority of catalytic centers in this MOF are redox-accessible where Co(II) is reduced to Co(I) during catalysis.
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Metal-organic framework materials as catalysts
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Self-citationActive and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires
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General Techno-Economic Analysis of CO 2 Electrolysis Systems
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Fundamentals and challenges of electrochemical CO2 reduction using two-dimensional materials
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Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Single Pt Atoms Confined into a Metal–Organic Framework for Efficient Photocatalysis
Fang, X., Shang, Q., Wang, Y., Jiao, L., Yao, T., Li, Y., Zhang, Q., Luo, Y., & Jiang, H. (2018) · Advanced Materials · doi:10.1002/adma.201705112 · Cited by 837
Design Strategies toward Advanced MOF‐Derived Electrocatalysts for Energy‐Conversion Reactions
Liu, J., Zhu, D., Guo, C., Vasileff, A., & Qiao, S. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700518 · Cited by 668
Metadata
- Authors
- Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-10-28
- Volume
- 137
- Issue
- 44
- Pages
- 14129-14135
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2340814919
- Cited by
- 1,158
- References
- 12
- FWCI
- 26.69
- Type
- journal article
- Language
- en
- Open access
- green
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- Kornienko, N., Zhao, Y., Kley, C. S., Zhu, C., Kim, D., Lin, S., Chang, C. J., Yaghi, O. M., & Yang, P. (2015). Metal–Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.5b08212
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