The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Silicon Solid Electrolyte Interphase (SEI) of Lithium Ion Battery Characterized by Microscopy and Spectroscopy
Open accessAbstract
The surface reactions of electrolytes with a silicon anode in lithium ion cells have been investigated. The investigation utilizes two novel techniques that are enabled by the use of binder-free silicon (BF-Si) nanoparticle anodes. The first method, transmission electron microscopy with energy dispersive X-ray spectroscopy, allows straightforward analysis of the BF-Si solid electrolyte interphase (SEI). The second method utilizes multi-nuclear magnetic resonance spectroscopy of D 2 O extracts from the cycled anodes. The TEM and NMR data are complemented by XPS and FTIR data, which are routinely used for SEI studies. Coin cells (BF-Si/Li) were cycled in electrolytes containing LiPF 6 salt and ethylene carbonate or fluoroethylene carbonate solvent. Capacity retention was significantly better for cells cycled with LiPF 6 /FEC electrolyte than for cells cycled with LiPF 6 /EC electrolyte. Our unique combination of techniques establishes that for LiPF 6 /EC electrolyte the BF-Si SEI continuously grows during the first 20 cycles and the SEI becomes integrated with the BF-Si nanoparticles. The SEI predominantly contains lithium ethylene dicarbonate, LiF, and Li x SiO y . BF-Si electrodes cycled with LiPF 6 /FEC electrolyte have a different behavior; the BF-Si nanoparticles remain relatively distinct from the SEI. The SEI predominantly contains LiF, Li x SiO y, and an insoluble polymeric species.
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Metadata
- Authors
- Nie, M., Abraham, D. P., Chen, Y., Bose, A., & Lucht, B. L.
- Venue
- The Journal of Physical Chemistry C
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-06-19
- Volume
- 117
- Issue
- 26
- Pages
- 13403-13412
- ISSN
- 1932-7447 (ISSN-L)
- 1932-7455
- OpenAlex
- W2051699520
- Cited by
- 578
- References
- 28
- FWCI
- 23.76
- Type
- journal article
- Language
- en
- Open access
- green
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