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Cited by 290

The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.

Water Immobilization at Surfactant Interfaces in Reverse Micelles

Riter, Ruth E., Willard, Dale M., Levinger, Nancy E.·1998·The Journal of Physical Chemistry B
DOI 10.1021/jp973330n
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Abstract

The mobility of water in water/Aerosol OT (AOT)/isooctane reverse micelles has been investigated via polar solvation dynamics measurements using ultrafast, time-resolved fluorescence-upconversion spectroscopy. For the smallest reverse micelles studied, w 0 = 1.1, no solvation dynamics are observed on the time scale of the instrument, suggesting that the water is essentially frozen. As w 0 increases, the mobility of water increases, and the time-correlation functions exhibit multiexponential decays. A subpicosecond component is observed on a time scale similar to that of diffusive bulk-water motion. 1 The other components decay on time scales of a few picoseconds to hundreds of picoseconds. The amplitude of the solvent response increases as w 0 increases, which is attributed to increased mobility of the water inside the reverse micelles. Because the micellar interior is highly ionic, the solvation dynamics of coumarin 343 in a 1 M Na + (Na 2 SO 4 ) solution were also investigated to compare the dynamics of water in the reverse micelles with the dynamics of bulk water in an ionic solution.

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Metadata

Authors
Riter, R. E., Willard, D. M., & Levinger, N. E.
Venue
The Journal of Physical Chemistry B
Publisher
American Chemical Society (ACS)
Published
1998-03-20
Volume
102
Issue
15
Pages
2705-2714
ISSN
  • 1520-5207 (ISSN-L)
  • 1520-6106
DOI
10.1021/jp973330n
OpenAlex
W1989286540
Cited by
290
References
27
FWCI
8.84
Type
journal article
Language
en
Open access
closed

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

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