Immortal CO2/Propylene Oxide Copolymerization: Precise Control of Molecular Weight and Architecture of Various Block Copolymers
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTImmortal CO2/Propylene Oxide Copolymerization: Precise Control of Molecular Weight and Architecture of Various Block CopolymersAnish Cyriac, Sang Hwan Lee, Jobi Kodiyan Varghese, Eun Seok Park, Ji Hae Park, and Bun Yeoul Lee*View Author Information Department of Molecular Science and Technology, Ajou University, Suwon 443-749, Korea*Corresponding author. E-mail: [email protected]Cite this: Macromolecules 2010, 43, 18, 7398–7401Publication Date (Web):August 27, 2010Publication History Received6 June 2010Revised5 August 2010Published online27 August 2010Published inissue 28 September 2010https://pubs.acs.org/doi/10.1021/ma101259khttps://doi.org/10.1021/ma101259krapid-communicationACS PublicationsCopyright © 2010 American Chemical SocietyRequest reuse permissionsArticle Views3990Altmetric-Citations142LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information SUBJECTS:Alcohols,Anions,Copolymerization,Gel permeation chromatography,Polymers Get e-Alerts
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The exploitation of chain transfer phenomenon enables immortal polymerization conditions, where chain transfer agents are added in large excess compared to the catalyst to increase the polymerization rate and control the molecular weight of products.
“On the other hand, the exploitation of chain transfer phenomenon enables immortal polymerization conditions, where the chain transfer agents are added in large excess compared to the catalyst to increase the polymerization rate and control the molecular weight of products.360”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [360]
Cites
Darensbourg, D. J. (2007) · Chemical Reviews · doi:10.1021/cr068363q · Cited by 1,593 · see citing works
Coates, G. W., & Moore, D. R. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200460442 · Cited by 1,154 · see citing works
Cohen, C. T., Chu, T., & Coates, G. W. (2005) · Journal of the American Chemical Society · doi:10.1021/ja051744l · Cited by 524 · see citing works
Lu, X., Shi, L., Wang, Y., Zhang, R., Ying-ju, Z., Peng, X., Zhang, Z., & Li, B. (2006) · Journal of the American Chemical Society · doi:10.1021/ja056383o · Cited by 427 · see citing works
Luinstra, G. A. (2008) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1080/15583720701834240 · Cited by 410 · see citing works
Nakano, K., Kamada, T., & Nozaki, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200603132 · Cited by 389 · see citing works
Lu, X., & Wang, Y. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200453998 · Cited by 346 · see citing works
Ren, W., Liu, Z.-W., Wen, Y., et al. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9033999 · Cited by 342 · see citing works
Kember, M. R., Knight, P. D., Reung, P. T. R., & Williams, C. K. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803896 · Cited by 339 · see citing works
A Highly Active and Recyclable Catalytic System for CO2/Propylene Oxide Copolymerization
Sujith, S., Min, J. K., Seong, J. E., Na, S. J., & Lee, B. Y. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200801852 · Cited by 330 · see citing works
Self-citationNoh, E. K., Na, S. J., Sujith, S., Kim, S., & Lee, B. Y. (2007) · Journal of the American Chemical Society · doi:10.1021/ja071290n · Cited by 315 · see citing works
Self-citationBimetallic Anilido-Aldimine Zinc Complexes for Epoxide/CO2 Copolymerization
Lee, B. Y., Kwon, H. Y., Lee, S. Y., Na, S. J., Han, S., Yun, H., Lee, H., & Park, Y.-W. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0435135 · Cited by 295 · see citing works
Self-citationControlled and Living Polymerizations
(2009) · Wiley eBooks · doi:10.1002/9783527629091 · Cited by 221 · see citing works
Kember, M. R., White, A. J. P., & Williams, C. K. (2010) · Macromolecules · doi:10.1021/ma902582m · Cited by 194 · see citing works
Sugimoto, H., Ohtsuka, H., & Inoue, S. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20894 · Cited by 165 · see citing works
Fabricating Microarrays of Functional Proteins Using Affinity Contact Printing
Renault, J., Bernard, A., Juncker, D., Michel, B., Bosshard, H. R., & Delamarche, E. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020703)41:13 · Cited by 148 · see citing works
Na, S. J., Sujith, S., Cyriac, A., Kim, B. E., Yoo, J., Kang, Y. K., Han, S. J., Lee, C., & Lee, B. Y. (2009) · Inorganic Chemistry · doi:10.1021/ic901584u · Cited by 113 · see citing works
Self-citationYoo, J., Na, S. J., Park, H. C., et al. (2010) · Dalton Transactions · doi:10.1039/b920992a · Cited by 80 · see citing works
Crosslinking of Poly(L-lactide) by γ-Irradiation
Jin, F., Hyon, S., Iwata, H., & Tsutsumi, S. (2002) · Macromolecular Rapid Communications · doi:10.1002/1521-3927(20021001)23:15 · Cited by 73 · see citing works
Thermal and weathering degradation of poly(propylene carbonate)
Varghese, J. K., Na, S. J., Park, J. H., et al. (2010) · Polymer Degradation and Stability · doi:10.1016/j.polymdegradstab.2010.03.006 · Cited by 58 · see citing works
Self-citationEfficient Synthesis of a Highly Active Catalyst for CO2/Epoxide Copolymerization
Min, J. K. (2009) · Bulletin of the Korean Chemical Society · doi:10.5012/bkcs.2009.30.3.745 · Cited by 20 · see citing works
Crosslinked polycarbonate polyurethanes: preparation and physical properties
Cao, N., Pegoraro, M., Severini, F., et al. (1992) · Polymer · doi:10.1016/0032-3861(92)90111-9 · Cited by 16 · see citing works
A relatively simple method for calculating Mark‐Houwink parameters using basic definitions
Braun, J. L., & Kadla, J. F. (2009) · Journal of Applied Polymer Science · doi:10.1002/app.30710 · Cited by 6 · see citing works
Immortal polymerization: The outset, development, and application
Inoue, S. (2000) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/1099-0518(20000815)38:16
Flagged first, then by citations
Cited by
Sorted by citations
Catalysis as an Enabling Science for Sustainable Polymers
Zhang, X., Fevre, M., Jones, G. O., & Waymouth, R. M. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00329 · Cited by 936 · see citing works
Ring-opening copolymerization (ROCOP): synthesis and properties of polyesters and polycarbonates
Paul, S., Zhu, Y., Romain, C., Brooks, R., Saini, P. K., & Williams, C. K. (2015) · Chemical Communications · doi:10.1039/c4cc10113h · Cited by 593 · see citing works
Carbon dioxide (CO <sub>2</sub> ) as sustainable feedstock for polyurethane production
Langanke, J., Wolf, A., Hofmann, J., Böhm, K., Subhani, M. A., Müller, T. E., Leitner, W., & Gürtler, C. (2014) · Green Chem. · doi:10.1039/c3gc41788c · Cited by 361 · see citing works
Catalysts for CO <sub>2</sub> /epoxide ring-opening copolymerization
Trott, G., Saini, P. K., & Williams, C. K. (2016) · Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2015.0085 · Cited by 201 · see citing works
Green polycarbonates prepared by the copolymerization of CO<sub>2</sub> with epoxides
Taherimehr, M., & Pescarmona, P. P. (2014) · Journal of Applied Polymer Science · doi:10.1002/app.41141 · Cited by 194 · see citing works
Park, J. H., Jeon, J. Y., Lee, J. J., Jang, Y., Varghese, J. K., & Lee, B. Y. (2013) · Macromolecules · doi:10.1021/ma400360w · Cited by 158 · see citing works
Self-citation
- Authors
- Cyriac, A., Lee, S. H., Varghese, J. K., Park, E. S., Park, J. H., & Lee, B. Y.
- Affiliations
- Ajou University (KR)
- Corresponding author
- Lee, Bun Yeoul
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-08-27
- Volume
- 43
- Issue
- 18
- Pages
- 7398-7401
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2000828353
- Cited by
- 161
- References
- 25
- Citations by year
- 2026: 4 · 2025: 7 · 2024: 14 · 2023: 4 · 2022: 12 · 2021: 11 · 2020: 11 · 2019: 11 · 2018: 12 · 2017: 9 · 2016: 11 · 2015: 11 · 2014: 10 · 2013: 14 · 2012: 11
- FWCI
- 5.39
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Keywords
- block copolymers, molecular weight control, copolymer architecture, CO2 polymerization, anionic polymerization, CO2 utilization, poly(ethylene glycol) monomethacrylate
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