The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Design and Synthesis of Dual Thermoresponsive and Antifouling Hybrid Polymer/Gold Nanoparticles
Abstract
A series of thermosensitive copoly(oligoethylene oxide) acrylates with narrow polydispersities were prepared by the copolymerization of oligo(ethylene oxide) acrylate and di(ethylene oxide) ethyl ether acrylate using reversible addition−fragmentation chain transfer polymerization (RAFT). These copolymers exhibit tunable LCST behavior over the range of 15−90 °C dependent on their monomer compositions. Subsequently, these copolymers were grafted onto gold nanoparticle (GNP) surfaces yielding thermosensitive gold nanoparticles. The thermoresponsive properties of these hybrid GNPs/poly(OEG-A- co -DEG-A) nanoparticles were evaluated in solution using dynamic light scattering and UV−vis spectroscopy. In addition, the susceptibility of these GNPs to protein fouling was assessed by a Bradford’s assay and found to be significantly reduced by the copolymer stabilizing layer. We also demonstrate, in a unique one-pot assembly process, the synthesis of a hybrid nanoparticle that shows dual temperature responsiveness. These hybrid nanoparticles open new applications in biotechnology and medicine.
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Cites
Nanocarriers as an emerging platform for cancer therapy
Peer, D., Karp, J. M., Hong, S., Farokhzad, O. C., Margalit, R., & Langer, R. (2007) · Nature Nanotechnology · doi:10.1038/nnano.2007.387 · Cited by 8,710
Effect of pegylation on pharmaceuticals
Harris, J. M., & Chess, R. B. (2003) · Nature Reviews Drug Discovery · doi:10.1038/nrd1033 · Cited by 3,431
In vivo tumor targeting and spectroscopic detection with surface-enhanced Raman nanoparticle tags
Qian, X., Peng, X.-H., Ansari, D. O., Yin-Goen, Q., Chen, G. Z., Shin, D. M., Yang, L., Young, A. N., Wang, M. D., & Nie, S. (2008) · Nature Biotechnology · doi:10.1038/nbt1377 · Cited by 2,201
Applications of Nanoparticles in Biology
De, M., Ghosh, P. S., & Rotello, V. M. (2008) · Advanced Materials · doi:10.1002/adma.200703183 · Cited by 1,547
Cited by
New directions in thermoresponsive polymers
Roy, D., Brooks, W. L. A., & Sumerlin, B. S. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35499g · Cited by 1,311
Bioapplications of RAFT Polymerization
Boyer, C., Bulmus, V., Davis, T. P., Ladmiral, V., Liu, J., & Perrier, S. (2009) · Chemical Reviews · doi:10.1021/cr9001403 · Cited by 1,015
Self-citationThermo‐Switchable Materials Prepared Using the OEGMA‐Platform
Lutz, J. (2011) · Advanced Materials · doi:10.1002/adma.201100597 · Cited by 411
Metadata
- Authors
- Boyer, C., Whittaker, M. R., Luzon, M., & Davis, T. P.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-07-10
- Volume
- 42
- Issue
- 18
- Pages
- 6917-6926
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1999890986
- Cited by
- 194
- References
- 4
- FWCI
- 9.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Boyer, C., Whittaker, M. R., Luzon, M., & Davis, T. P. (2009). Design and Synthesis of Dual Thermoresponsive and Antifouling Hybrid Polymer/Gold Nanoparticles. Macromolecules. https://doi.org/10.1021/ma9013127
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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