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In Situ TEM of Two-Phase Lithiation of Amorphous Silicon Nanospheres
Abstract
To utilize high-capacity Si anodes in next-generation Li-ion batteries, the physical and chemical transformations during the Li-Si reaction must be better understood. Here, in situ transmission electron microscopy is used to observe the lithiation/delithiation of amorphous Si nanospheres; amorphous Si is an important anode material that has been less studied than crystalline Si. Unexpectedly, the experiments reveal that the first lithiation occurs via a two-phase mechanism, which is contrary to previous understanding and has important consequences for mechanical stress evolution during lithiation. On the basis of kinetics measurements, this behavior is suggested to be due to the rate-limiting effect of Si-Si bond breaking. In addition, the results show that amorphous Si has more favorable kinetics and fracture behavior when reacting with Li than does crystalline Si, making it advantageous to use in battery electrodes. Amorphous spheres up to 870 nm in diameter do not fracture upon lithiation; this is much larger than the 150 nm critical fracture diameter previously identified for crystalline Si spheres.
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Cites
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Park, G. S. (1975) · Polymer · doi:10.1016/0032-3861(75)90130-5 · Cited by 14,967
High-performance lithium battery anodes using silicon nanowires
Chan, C. K., Peng, H., Liu, G., McIlwrath, K., Zhang, X. F., Huggins, R. A., & Cui, Y. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2007.411 · Cited by 6,683
Self-citationNano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells
Kasavajjula, U., Wang, C., & Appleby, A. J. (2007) · Journal of Power Sources · doi:10.1016/j.jpowsour.2006.09.084 · Cited by 2,491
Self-citationWu, H., Chan, G., Choi, J. W., Ryu, I., Yao, Y., McDowell, M. T., Lee, S. W., Jackson, A., Yang, Y., Hu, L., et al. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.35 · Cited by 2,478
Self-citationSize-Dependent Fracture of Silicon Nanoparticles During Lithiation
Liu, X. H., Zhong, L., Huang, S., Mao, S. X., Zhu, T., & Huang, J. Y. (2012) · ACS Nano · doi:10.1021/nn204476h · Cited by 2,376
Designing nanostructured Si anodes for high energy lithium ion batteries
Wu, H., & Cui, Y. (2012) · Nano Today · doi:10.1016/j.nantod.2012.08.004 · Cited by 2,350
Self-citationHigh-performance lithium-ion anodes using a hierarchical bottom-up approach
Magasinski, A., Dixon, P., Hertzberg, B., Kvit, A., Ayala, J., & Yushin, G. (2010) · Nature Materials · doi:10.1038/nmat2725 · Cited by 2,044
Structural Changes in Silicon Anodes during Lithium Insertion/Extraction
Obrovac, M. N., & Christensen, L. (2004) · Electrochemical and Solid-State Letters · doi:10.1149/1.1652421 · Cited by 1,995
A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes
Liu, N., Wu, H., McDowell, M. T., Yao, Y., Wang, C., & Cui, Y. (2012) · Nano Letters · doi:10.1021/nl3014814 · Cited by 1,842
Self-citationA Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
Kovalenko, I., Zdyrko, B., Magasinski, A., Hertzberg, B., Milicev, Z., Burtovyy, R., Luzinov, I., & Yushin, G. (2011) · Science · doi:10.1126/science.1209150 · Cited by 1,802
Interconnected Silicon Hollow Nanospheres for Lithium-Ion Battery Anodes with Long Cycle Life
Yao, Y., McDowell, M. T., Ryu, I., Wu, H., Liu, N., Hu, L., Nix, W. D., & Cui, Y. (2011) · Nano Letters · doi:10.1021/nl201470j · Cited by 1,456
Self-citationSize Dependent Fracture of Silicon Nanoparticles during Lithiation.
Huang, J., Liu, X., Zhong, L. S., Huang, S., Mao, S. X., & Zhu, T. (2011) · Nano Letters · Cited by 1,316
A review of advanced and practical lithium battery materials
Marom, R., Amalraj, S. F., Leifer, N., Jacob, D., & Aurbach, D. (2011) · Journal of Materials Chemistry · doi:10.1039/c0jm04225k · Cited by 1,075
Carbon−Silicon Core−Shell Nanowires as High Capacity Electrode for Lithium Ion Batteries
Cui, L.-F., Yang, Y., Hsu, C.-M., & Cui, Y. (2009) · Nano Letters · doi:10.1021/nl901670t · Cited by 1,054
Self-citationArrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries
Song, T., Xia, J., Lee, J.-H., Lee, D. H., Kwon, M.-S., Choi, J.-M., Wu, J., Doo, S. K., Chang, H., Park, W. I., et al. (2010) · Nano Letters · doi:10.1021/nl100086e · Cited by 894
Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation
Liu, X. H., Zheng, H., Zhong, L., Huang, S., Karki, K., Zhang, L. Q., Liu, Y., Kushima, A., Liang, W. T., Wang, J. W., et al. (2011) · Nano Letters · doi:10.1021/nl201684d · Cited by 809
Self-citationReal-Time NMR Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries
Key, B., Bhattacharyya, R., Morcrette, M., Seznéc, V., Tarascon, J.-M., & Grey, C. P. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8086278 · Cited by 752
Materials Challenges Facing Electrical Energy Storage
Whittingham, M. S. (2008) · MRS Bulletin · doi:10.1557/mrs2008.82 · Cited by 703
Electrospun Core–Shell Fibers for Robust Silicon Nanoparticle-Based Lithium Ion Battery Anodes
Hwang, T. H., Lee, Y. M., Kong, B.-S., Seo, J.-S., & Choi, J. W. (2012) · Nano Letters · doi:10.1021/nl203817r · Cited by 658
In situ atomic-scale imaging of electrochemical lithiation in silicon
Liu, X. H., Wang, J. W., Huang, S., Fan, F., Huang, X., Liu, Y., Krylyuk, S., Yoo, J., Dayeh, S. A., Davydov, A. V., et al. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2012.170 · Cited by 657
McDowell, M. T., Ryu, I., Lee, S. W., Wang, C., Nix, W. D., & Cui, Y. (2012) · Advanced Materials · doi:10.1002/adma.201202744 · Cited by 626
Self-citationDetermination of the diffusion coefficient of lithium ions in nano-Si
Ding, N., Xu, J., Yao, Y. X., Wegner, G., Fang, X., Chen, C. H., & Lieberwirth, I. (2009) · Solid State Ionics · doi:10.1016/j.ssi.2008.12.015 · Cited by 621
Limthongkul, P., Jang, Y.-I., Dudney, N. J., & Chiang, Y. (2003) · Acta Materialia · doi:10.1016/s1359-6454(02)00514-1 · Cited by 511
Cheng, Y.-T., & Verbrugge, M. W. (2009) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.01.021 · Cited by 469
Anomalous Shape Changes of Silicon Nanopillars by Electrochemical Lithiation
Lee, S. W., McDowell, M. T., Choi, J. W., & Cui, Y. (2011) · Nano Letters · doi:10.1021/nl201787r · Cited by 449
Self-citationFracture of crystalline silicon nanopillars during electrochemical lithium insertion
Lee, S. W., McDowell, M. T., Berla, L. A., Nix, W. D., & Cui, Y. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1201088109 · Cited by 432
Self-citationSize-dependent fracture of Si nanowire battery anodes
Ryu, I., Choi, J. W., Cui, Y., & Nix, W. D. (2011) · Journal of the Mechanics and Physics of Solids · doi:10.1016/j.jmps.2011.06.003 · Cited by 421
Self-citationUltrafast Electrochemical Lithiation of Individual Si Nanowire Anodes
Liu, X. H., Zhang, L. Q., Zhong, L., Liu, Y., Zheng, H., Wang, J. W., Cho, J.-H., Dayeh, S. A., Picraux, S. T., Sullivan, J. P., et al. (2011) · Nano Letters · doi:10.1021/nl200412p · Cited by 411
In Situ TEM Experiments of Electrochemical Lithiation and Delithiation of Individual Nanostructures
Liu, X. H., Liu, Y., Kushima, A., Zhang, S., Zhu, T., Li, J., & Huang, J. Y. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200024 · Cited by 408
Chon, M. J., Sethuraman, V. A., McCormick, A. W., Srinivasan, V., & Guduru, P. R. (2011) · Physical Review Letters · doi:10.1103/physrevlett.107.045503 · Cited by 403
Gu, M., Li, Y., Li, X., Hu, S., Zhang, X., Xu, W., Thevuthasan, S., Baer, D. R., Zhang, J.-G., Liu, J., et al. (2012) · ACS Nano · doi:10.1021/nn303312m · Cited by 361
Self-citationLarge Plastic Deformation in High‐Capacity Lithium‐Ion Batteries Caused by Charge and Discharge
Zhao, K., Pharr, M., Cai, S., Vlassak, J. J., & Suo, Z. (2011) · Journal of the American Ceramic Society · doi:10.1111/j.1551-2916.2011.04432.x · Cited by 322
Zhao, K., Pharr, M., Wan, Q., Wang, W. L., Kaxiras, E., Vlassak, J. J., & Suo, Z. (2011) · Journal of The Electrochemical Society · doi:10.1149/2.020203jes · Cited by 307
Baranchugov, V., Markevich, E., Pollak, E., Salitra, G., & Aurbach, D. (2007) · Electrochemistry Communications · doi:10.1016/j.elecom.2006.11.014 · Cited by 290
Wang, C.-M., Li, X., Wang, Z., Xu, W., Liu, J., Gao, F., Kovarik, L., Zhang, J.-G., Howe, J., Burton, D. J., et al. (2012) · Nano Letters · doi:10.1021/nl204559u · Cited by 277
Self-citationSilicon Inverse‐Opal‐Based Macroporous Materials as Negative Electrodes for Lithium Ion Batteries
Esmanski, A., & Ozin, G. A. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200900306 · Cited by 269
Materials for Rechargeable Lithium-Ion Batteries
Hayner, C. M., Zhao, X., & Kung, H. H. (2012) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-062011-081024 · Cited by 263
Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries
Pharr, M., Zhao, K., Wang, X., Suo, Z., & Vlassak, J. J. (2012) · Nano Letters · doi:10.1021/nl302841y · Cited by 256
In Situ X-ray Diffraction Studies of (De)lithiation Mechanism in Silicon Nanowire Anodes
Misra, S., Liu, N., Nelson, J., Hong, S. S., Cui, Y., & Toney, M. F. (2012) · ACS Nano · doi:10.1021/nn301339g · Cited by 188
Self-citationIn Situ Electrochemical Lithiation/Delithiation Observation of Individual Amorphous Si Nanorods
Ghassemi, H., Au, M., Chen, N., Heiden, P. A., & Yassar, R. S. (2011) · ACS Nano · doi:10.1021/nn2029814 · Cited by 167
Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes
Karki, K., Epstein, E. S., Cho, J., Jia, Z., Li, T., Picraux, S. T., Wang, C., & Cumings, J. (2012) · Nano Letters · doi:10.1021/nl204063u · Cited by 117
Self-citationPressure-Gradient Dependent Diffusion and Crack Propagation in Lithiated Silicon Nanowires
Grantab, R., & Shenoy, V. B. (2012) · Journal of The Electrochemical Society · doi:10.1149/2.072205jes · Cited by 90
McDowell, M. T., & Cui, Y. (2011) · Advanced Energy Materials · doi:10.1002/aenm.201100258 · Cited by 62
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Self-citationReview on recent progress of nanostructured anode materials for Li-ion batteries
Goriparti, S., Miele, E., De Angelis, F., Di Fabrizio, E., Proietti Zaccaria, R., & Capiglia, C. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.11.103 · Cited by 2,092
Interconnected hollow carbon nanospheres for stable lithium metal anodes
Zheng, G., Lee, S. W., Liang, Z., Lee, H.-W., Yan, K., Yao, H., Wang, H., Li, W., Chu, S., & Cui, Y. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.152 · Cited by 1,764
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Metadata
- Authors
- McDowell, M. T., Lee, S. W., Harris, J. T., Korgel, B. A., Wang, C., Nix, W. D., & Cui, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-01-17
- Volume
- 13
- Issue
- 2
- Pages
- 758-764
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1977828436
- Cited by
- 869
- References
- 44
- FWCI
- 46.33
- Type
- journal article
- Language
- en
- Open access
- closed
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