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Mesoporous Amorphous FePO4Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries
Abstract
FePO4 nanospheres are synthesized successfully through a simple chemically induced precipitation method. The nanospheres present a mesoporous amorphous structure. Electrochemical experiments show that the FePO4/C electrode demonstrates a high initial discharging capacity of 151 mAh g(-1) at 20 mA g(-1), stable cyclablilty (94% capacity retention ratio over 160 cycles), as well as high rate capability (44 mAh g(-1) at 1000 mA g(-1)) for Na-ion storage. The superior electrochemical performance of the FePO4/C nanocomposite is due to its particular mesoporous amorphous structure and close contact with the carbon framework, which significantly improve the ionic and electronic transport and intercalation kinetics of Na ions.
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Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Cited by
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Understanding electrochemical potentials of cathode materials in rechargeable batteries
Liu, C., Neale, Z. G., & Cao, G. (2016) · Materials Today · doi:10.1016/j.mattod.2015.10.009 · Cited by 1,156
Recent Progress in Electrode Materials for Sodium‐Ion Batteries
Kim, H., Kim, H., Ding, Z., Lee, M. H., Lim, K., Yoon, G., & Kang, K. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201600943 · Cited by 986
Polyanion‐Type Electrode Materials for Sodium‐Ion Batteries
Ni, Q., Bai, Y., Wu, F., & Wu, C. (2017) · Advanced Science · doi:10.1002/advs.201600275 · Cited by 586
Fang, Y., Xiao, L., Ai, X., Cao, Y., & Yang, H. (2015) · Advanced Materials · doi:10.1002/adma.201502018 · Cited by 549
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Metadata
- Authors
- Fang, Y., Xiao, L., Qian, J., Ai, X., Yang, H., & Cao, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-28
- Volume
- 14
- Issue
- 6
- Pages
- 3539-3543
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2410434855
- Cited by
- 268
- References
- 1
- FWCI
- 19.99
- Type
- journal article
- Language
- en
- Open access
- closed
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- Fang, Y., Xiao, L., Qian, J., Ai, X., Yang, H., & Cao, Y. (2014). Mesoporous Amorphous FePO4Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries. Nano Letters. https://doi.org/10.1021/nl501152f
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