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Mesoporous Amorphous FePO4Nanospheres as High-Performance Cathode Material for Sodium-Ion Batteries
Abstract
FePO4 nanospheres are synthesized successfully through a simple chemically induced precipitation method. The nanospheres present a mesoporous amorphous structure. Electrochemical experiments show that the FePO4/C electrode demonstrates a high initial discharging capacity of 151 mAh g(-1) at 20 mA g(-1), stable cyclablilty (94% capacity retention ratio over 160 cycles), as well as high rate capability (44 mAh g(-1) at 1000 mA g(-1)) for Na-ion storage. The superior electrochemical performance of the FePO4/C nanocomposite is due to its particular mesoporous amorphous structure and close contact with the carbon framework, which significantly improve the ionic and electronic transport and intercalation kinetics of Na ions.
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Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
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Ni, Q., Bai, Y., Wu, F., & Wu, C. (2017) · Advanced Science · doi:10.1002/advs.201600275 · Cited by 586
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Self-citationChen, M., Hua, W., Xiao, J., Cortie, D., Chen, W., Wang, E., Hu, Z., Gu, Q., Wang, X., Indris, S., et al. (2019) · Nature Communications · doi:10.1038/s41467-019-09170-5 · Cited by 522
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Synthesis of CuS@CoS2 Double‐Shelled Nanoboxes with Enhanced Sodium Storage Properties
Fang, Y., Guan, B. Y., Luan, D., & Lou, X. W. (. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201902583 · Cited by 257
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Metadata
- Authors
- Fang, Y., Xiao, L., Qian, J., Ai, X., Yang, H., & Cao, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-05-28
- Volume
- 14
- Issue
- 6
- Pages
- 3539-3543
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2410434855
- Cited by
- 268
- References
- 1
- FWCI
- 19.99
- Type
- journal article
- Language
- en
- Open access
- closed
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