The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Electrocatalytic and Photocatalytic Hydrogen Production from Acidic and Neutral-pH Aqueous Solutions Using Iron Phosphide Nanoparticles
Abstract
Nanostructured transition-metal phosphides have recently emerged as Earth-abundant alternatives to platinum for catalyzing the hydrogen-evolution reaction (HER), which is central to several clean energy technologies because it produces molecular hydrogen through the electrochemical reduction of water. Iron-based catalysts are very attractive targets because iron is the most abundant and least expensive transition metal. We report herein that iron phosphide (FeP), synthesized as nanoparticles having a uniform, hollow morphology, exhibits among the highest HER activities reported to date in both acidic and neutral-pH aqueous solutions. As an electrocatalyst operating at a current density of -10 mA cm(-2), FeP nanoparticles deposited at a mass loading of ∼1 mg cm(-2) on Ti substrates exhibited overpotentials of -50 mV in 0.50 M H2SO4 and -102 mV in 1.0 M phosphate buffered saline. The FeP nanoparticles supported sustained hydrogen production with essentially quantitative faradaic yields for extended time periods under galvanostatic control. Under UV illumination in both acidic and neutral-pH solutions, FeP nanoparticles deposited on TiO2 produced H2 at rates and amounts that begin to approach those of Pt/TiO2. FeP therefore is a highly Earth-abundant material for efficiently facilitating the HER both electrocatalytically and photocatalytically.
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Cites
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Self-citationTian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Xiang, Q., Yu, J., & Jaroniec, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302846n · Cited by 2,360
Kong, D., Wang, H., Lu, Z., & Cui, Y. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501497n · Cited by 1,392
High-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
Faber, M. S., Dziedzic, R., Lukowski, M. A., Kaiser, N. S., Ding, Q., & Jin, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504099w · Cited by 1,372
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Self-citationFirst-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031
Cao, B., Veith, G. M., Neuefeind, J. C., Adzic, R. R., & Khalifah, P. G. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4081056 · Cited by 998
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Wang, C., Daimon, H., Onodera, T., Koda, T., & Sun, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800073 · Cited by 849
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Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
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Metadata
- Authors
- Callejas, J. F., McEnaney, J. M., Read, C. G., Crompton, J. C., Biacchi, A. J., Popczun, E. J., Gordon, T. R., Lewis, N. S., & Schaak, R. E.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-01
- Volume
- 8
- Issue
- 11
- Pages
- 11101-11107
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1977466903
- Cited by
- 464
- References
- 12
- FWCI
- 19.21
- Type
- journal article
- Language
- en
- Open access
- closed
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