Oxygen isotope behavior in the Sulfate-Water System
Abstract
Fundamental data on oxygen isotope behavior in the sulfate-water system are given. Oxygen exchange rates between sulfate ions and water are very slow and show a marked pH dependence. Of the order of 10/sup +3/ to 10/sup +5/ years are required to closely approach isotopic equilibrium at earth surface conditions. Oxygen isotope fractionation experiments yielded the following relationships: Ln alpha = 3878/(t+2) -0.0034 anhydrite water (and) Ln alpha = 3251/(t+2) -0.0056 dissolved sulfate water. During progressive evaporation of saturated CaSO/sub 4/ solution the gypsum formed tends to concentrate oxygen-18 relative to dissolved sulfate by 2%. Sulfate reducing bacteria preferentially metabolize oxygen-16 by about 4.6% in both pure and natural cultures. Oxidation of sulfide to sulfate in natural environments is a complex process making use of both water oxygen and molecular oxygen.
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The present calculation result of 18O-enrichment in anhydrite relative to barite is consistent with the hydrothermal experiments of Lloyd (1968), Kusakabe and Robinson (1977) and Chiba et al. (1981).
“This is consistent with the hydrothermal experiments of Lloyd (1968), Kusakabe and Robinson (1977) and Chiba et al. (1981).”
From Oxygen isotope fractionation in carbonate and sulfate minerals. (1999) · cites this paper as Lloyd (1968)
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Mangalo, M., Meckenstock, R. U., Stichler, W., & Einsiedl, F. (2007) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2007.06.058 · Cited by 84 · see citing works
A vibrational spectroscopic 18O tracer study of pyrite oxidation
Reedy, B. J., Beattie, J. K., & Lowson, R. T. (1991) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(91)90132-o · Cited by 82 · see citing works
Isotopic evidence for the origin of sulphate in coastal rain
Wadleigh, M. A., Schwarcz, H. P., & Kramer, J. R. (1996) · Tellus B · doi:10.3402/tellusb.v48i1.15665 · Cited by 81 · see citing works
Knöller, K., Vogt, C., Haupt, M., Feisthauer, S., & Richnow, H. H. (2010) · Biogeochemistry · doi:10.1007/s10533-010-9483-9 · Cited by 80 · see citing works
Climate driven changes in the oxidation pathways of atmospheric sulfur
Alexander, B., Savarino, J., Barkov, N. I., Delmas, R. J., & Thiemens, M. H. (2002) · Geophysical Research Letters · doi:10.1029/2002gl014879 · Cited by 80 · see citing works
- Authors
- Lloyd, R. M.
- Corresponding author
- Lloyd, R. M.
- Venue
- Journal of Geophysical Research
- Publisher
- American Geophysical Union (AGU)
- Published
- 1968-09-15
- Volume
- 73
- Issue
- 18
- Pages
- 6099-6110
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2112478326
- Cited by
- 499
- References
- 13
- Citations by year
- 2026: 8 · 2025: 18 · 2024: 10 · 2023: 8 · 2022: 8 · 2021: 27 · 2020: 14 · 2019: 15 · 2018: 11 · 2017: 17 · 2016: 19 · 2015: 16 · 2014: 16 · 2013: 15 · 2012: 15
- FWCI
- 12.57
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
- Keywords
- oxygen isotopes, oxygen exchange kinetics, isotope fractionation, anhydrite, gypsum, evaporation, pH dependence, sulfate-reducing bacteria, oxygen-16, sulfide oxidation, molecular oxygen, dissolved sulfate
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