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Cited by 408

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Suppression of Kasha's rule as a mechanism for fluorescent molecular rotors and aggregation-induced emission

Qian, Hai, Cousins, Morgan E., Horak, Erik H., Wakefield, Audrey, Liptak, Matthew D., Aprahamian, Ivan·2017·Nature Chemistry
DOI 10.1038/nchem.2612
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Research works printed but not linked: 34

  1. Haidekker, M. A. & Theodorakis, E. A. Environment-sensitive behavior of fluorescent molecular rotors. J. Biol. Eng. 4, 11–24 (2010). · DOI · Paper page
  2. Kuimova, M. K. Mapping viscosity in cells using molecular rotors. Phys. Chem. Chem. Phys. 14, 12671–12686 (2012). · DOI · Paper page
  3. Srivatsan, S. G., Greco, N. J. & Tor, Y. A highly emissive fluorescent nucleoside that signals the activity of toxic ribosome-inactivating proteins. Angew. Chem. Int. Ed. 47, 6661–6665 (2008). · DOI
  4. Kuimova, M. K. et al. Imaging intracellular viscosity of a single cell during photoinduced cell death. Nat. Chem. 1, 69–73 (2009). · DOI · Paper page
  5. Cao, K. et al. Aminonaphthalene 2-cyanoacrylate (ANCA) probes fluorescently discriminate between amyloid-β and prion plaques in brain. J. Am. Chem. Soc. 134, 17338–17341 (2012). · DOI
  6. Wang, L., Xiao, Y., Tian, W. & Deng, L. Activatable rotor for quantifying lysosomal viscosity in living cells. J. Am. Chem. Soc. 135, 2903–2906 (2013). · DOI · Paper page
  7. Cui, M. C. et al. Smart near-infrared fluorescence probes with donor–acceptor structure for in vivo detection of β-amyloid deposits. J. Am. Chem. Soc. 136, 3388–3394 (2014). · DOI · Paper page
  8. Levitt, J. A. et al. Membrane-bound molecular rotors measure viscosity in live cells via fluorescence lifetime imaging. J. Phys. Chem. C 113, 11634–11642 (2009). · DOI · Paper page
  9. Hosny, N. A. et al. Mapping microbubble viscosity using fluorescence lifetime imaging of molecular rotors. Proc. Natl Acad. Sci. USA 110, 9225–9230 (2013). · DOI
  10. Shiraishi, Y., Inoue, T. & Hirai, T. Local viscosity analysis of triblock copolymer micelle with cyanine dyes as a fluorescent probe. Langmuir 26, 17505–17512 (2010). · DOI
  11. Vaccaro, G. et al. Direct monitoring of self-assembly of copolymeric micelles by a luminescent molecular rotor. Chem. Commun. 49, 8474–8476 (2013). · DOI
  12. Feng, J. et al. A triarylboron-based fluorescent thermometer: sensitive over a wide temperature range. Angew. Chem. Int. Ed. 50, 8072–8076 (2011). · doi:10.1002/anie.201102390
  13. Peng, X. J. et al. Fluorescence ratiometry and fluorescence lifetime imaging: using a single molecular sensor for dual mode imaging of cellular viscosity. J. Am. Chem. Soc. 133, 6626–6635 (2011). · DOI · Paper page
  14. Gatzogiannis, E. et al. Mapping protein-specific micro-environments in live cells by fluorescence lifetime imaging of a hybrid genetic-chemical molecular rotor tag. Chem. Commun. 48, 8694–8696 (2012). · doi:10.1039/c2cc33133k
  15. Haidekker, M. A., Brady, T. P., Lichlyter, D. & Theodorakis, E. A. Effects of solvent polarity and solvent viscosity on the fluorescent properties of molecular rotors and related probes. Bioorg. Chem. 33, 415–425 (2005). · doi:10.1016/j.bioorg.2005.07.005
  16. Bochkov, A. Y., Akchurin, I. O., Dyachenko, O. A. & Traven, V. F. NIR-fluorescent coumarin-fused BODIPY dyes with large Stokes shifts. Chem. Commun. 49, 11653–11655 (2013). · DOI
  17. Cosgrave, L., Devocelle, M., Forster, R. J. & Keyes, T. E. Multimodal cell imaging by ruthenium polypyridyl labelled cell penetrating peptides. Chem. Commun. 46, 103–105 (2010). · doi:10.1039/b918611e
  18. Zhou, Y., Xiao, Y., Chi, S. M. & Qian, X. H. Isomeric boron–fluorine complexes with donor–acceptor architecture: strong solid/liquid fluorescence and large Stokes shift. Org. Lett. 10, 633–636 (2008). · DOI · Paper page
  19. Yang, Y., Su, X., Carroll, C. N. & Aprahamian, I. Aggregation-induced emission in BF2-hydrazone (BODIHY) complexes. Chem. Sci. 3, 610–613 (2012). · DOI · Paper page
  20. Yang, Y. Hydrazone-Based Macrocycles, Fluorophores and Light-Activated Switches PhD Thesis, Dartmouth College (2014).
  21. Su, X. & Aprahamian, I. Hydrazone-based switches, metallo-assemblies and sensors. Chem. Soc. Rev. 43, 1963–1981 (2014). · DOI · Paper page
  22. Tatum, L. A., Su, X. & Aprahamian, I. Simple hydrazone building blocks for complicated functional materials. Acc. Chem. Res. 47, 2141–2149 (2014). · DOI · Paper page
  23. Leung, N. L. C. et al. Restriction of intramolecular motions: the general mechanism behind aggregation-induced emission. Chem. Eur. J. 20, 15349–15353 (2014). · DOI · Paper page
  24. Born, M. & Oppenheimer, R. Zur Quantentheorie der Molekeln [in German]. Ann. Phys. 389, 457–484 (1927). · DOI · Paper page
  25. Kee, H. L. et al. Structural control of the photodynamics of boron–dipyrrin complexes. J. Phys. Chem. B 109, 20433–20443 (2005). · DOI · Paper page
  26. Shao, J. Y. et al. Thiophene-inserted aryl-dicyanovinyl compounds: the second generation of fluorescent molecular rotors with significantly redshifted emission and large Stokes shift. Eur. J. Org. Chem. 6100–6109 (2011). · doi:10.1002/ejoc.201100891
  27. Peng, Q., Niu, Y. L., Deng, C. M. & Shuai, Z. G. Vibration correlation function formalism of radiative and non-radiative rates for complex molecules. Chem. Phys. 370, 215–222 (2010). · DOI
  28. Shuai, Z. G. & Peng, Q. Excited states structure and processes: understanding organic light-emitting diodes at the molecular level. Phys. Rep. 537, 123–156 (2014). · DOI · Paper page
  29. Kasha, M. Characterization of electronic transitions in complex molecules. Disc. Faraday Soc. 14–19 (1950). · DOI · Paper page
  30. Munkholm, C., Parkinson, D. R. & Walt, D. R. Intramolecular fluorescence self-quenching of fluoresceinamine. J. Am. Chem. Soc. 112, 2608–2612 (1990). · doi:10.1021/ja00163a021
  31. Ueno, T., Urano, Y., Kojima, H. & Nagano, T. Mechanism-based molecular design of highly selective fluorescence probes for nitrative stress. J. Am. Chem. Soc. 128, 10640–10641 (2006). · DOI · Paper page
  32. Jacquemin, D., Mennucci, B. & Adamo, C. Excited-state calculations with TD-DFT: from benchmarks to simulations in complex environments. Phys. Chem. Chem. Phys. 13, 16987–16998 (2011). · DOI · Paper page
  33. Itoh, T. Fluorescence and phosphorescence from higher excited states of organic molecules. Chem. Rev. 112, 4541–4568 (2012). · DOI · Paper page
  34. Mei, J. et al. Aggregation-induced emission: the whole is more brilliant than the parts. Adv. Mater. 26, 5429–5479 (2014). · DOI · Paper page

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Metadata

Authors
Qian, H., Cousins, M. E., Horak, E. H., Wakefield, A., Liptak, M. D., & Aprahamian, I.
Venue
Nature Chemistry
Publisher
Springer Science and Business Media LLC
Published
2016-09-26
Volume
9
Issue
1
Pages
83-87
ISSN
  • 1755-4330 (ISSN-L)
  • 1755-4349
DOI
10.1038/nchem.2612
OpenAlex
W2523886286
Cited by
408
References
3
FWCI
19.50
Type
journal article
Language
en
Open access
closed
Licence
www.springer.com/tdm (tdm)

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CoChat. (2026). Citation check: Suppression of Kasha's rule as a mechanism for fluorescent molecular rotors and aggregation-induced emission. https://app.cochat.ai/papers/10.1038/nchem.2612
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Qian, H., Cousins, M. E., Horak, E. H., Wakefield, A., Liptak, M. D., & Aprahamian, I. (2017). Suppression of Kasha's rule as a mechanism for fluorescent molecular rotors and aggregation-induced emission. Nature Chemistry. https://doi.org/10.1038/nchem.2612

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