The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis
Open accessAbstract
Engineering the surface structure at the atomic level can be used to precisely and effectively manipulate the reactivity and durability of catalysts. Here we report tuning of the atomic structure of one-dimensional single-crystal cobalt (II) oxide (CoO) nanorods by creating oxygen vacancies on pyramidal nanofacets. These CoO nanorods exhibit superior catalytic activity and durability towards oxygen reduction/evolution reactions. The combined experimental studies, microscopic and spectroscopic characterization, and density functional theory calculations reveal that the origins of the electrochemical activity of single-crystal CoO nanorods are in the oxygen vacancies that can be readily created on the oxygen-terminated {111} nanofacets, which favourably affect the electronic structure of CoO, assuring a rapid charge transfer and optimal adsorption energies for intermediates of oxygen reduction/evolution reactions. These results show that the surface atomic structure engineering is important for the fabrication of efficient and durable electrocatalysts.
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
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Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
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Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
Chen, C., Kang, Y., Huo, Z., Zhu, Z., Huang, W., Xin, H. L., Snyder, J. D., Li, D., Herron, J. A., Mavrikakis, M., et al. (2014) · Science · doi:10.1126/science.1249061 · Cited by 2,765 · cited 1×
“Currently, noble metals and their complexes are the most efficient catalysts 7–9 , but their high cost and scarcity greatly restricts commercial applications 10 .”
Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Self-citationHigh-Performance Electrocatalysis Using Metallic Cobalt Pyrite (CoS2) Micro- and Nanostructures
Faber, M. S., Dziedzic, R., Lukowski, M. A., Kaiser, N. S., Ding, Q., & Jin, S. (2014) · Journal of the American Chemical Society · doi:10.1021/ja504099w · Cited by 1,372
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Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
A review on fundamentals for designing oxygen evolution electrocatalysts
Song, J., Wei, C., Huang, Z.-F., Liu, C., Zeng, L., Wang, X., & Xu, Z. J. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00607a · Cited by 2,936
Oxygen Evolution Reaction in Alkaline Environment: Material Challenges and Solutions
Xie, X., Du, L., Yan, L., Park, S., Qiu, Y., Sokolowski, J., Wang, W., & Shao, Y. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202110036 · Cited by 792
Duan, Y., Yu, Z., Hu, S., Zheng, X., Zhang, C., Ding, H., Hu, B., Fu, Q., Yu, Z., Zheng, X., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201909939 · Cited by 625
Self-citationLiang, H., Gandi, A. N., Xia, C., Hedhili, M. N., Anjum, D. H., Schwingenschlögl, U., & Alshareef, H. N. (2017) · ACS Energy Letters · doi:10.1021/acsenergylett.7b00206 · Cited by 588
Metadata
- Authors
- Ling, T., Yan, D.-Y., Jiao, Y., Wang, H., Zheng, Y., Zheng, X., Mao, J., Du, X.-W., Hu, Z., Jaroniec, M., & Qiao, S.-Z.
- Venue
- Nature Communications
- Published
- 2016-09-21
- Volume
- 7
- Issue
- 1
- Pages
- 12876-12876
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2523696440
- Cited by
- 674
- References
- 7
- FWCI
- 24.31
- Type
- journal article
- Language
- en
- Open access
- gold
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