The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
A molecular catalyst for water oxidation that binds to metal oxide surfaces
Open accessAbstract
Molecular catalysts are known for their high activity and tunability, but their solubility and limited stability often restrict their use in practical applications. Here we describe how a molecular iridium catalyst for water oxidation directly and robustly binds to oxide surfaces without the need for any external stimulus or additional linking groups. On conductive electrode surfaces, this heterogenized molecular catalyst oxidizes water with low overpotential, high turnover frequency and minimal degradation. Spectroscopic and electrochemical studies show that it does not decompose into iridium oxide, thus preserving its molecular identity, and that it is capable of sustaining high activity towards water oxidation with stability comparable to state-of-the-art bulk metal oxide catalysts.
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Cites
Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Comparing Photosynthetic and Photovoltaic Efficiencies and Recognizing the Potential for Improvement
Blankenship, R. E., Tiede, D. M., Barber, J., Brudvig, G. W., Fleming, G., Ghirardi, M., Gunner, M. R., Junge, W., Kramer, D. M., Melis, A., et al. (2011) · Science · doi:10.1126/science.1200165 · Cited by 1,638
Self-citation
Cited by
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Ultrathin metal–organic framework nanosheets for electrocatalytic oxygen evolution
Zhao, S., Wang, Y., Dong, J., He, C.-T., Yin, H., An, P., Zhao, K., Zhang, X., Gao, C., Zhang, L., et al. (2016) · Nature Energy · doi:10.1038/nenergy.2016.184 · Cited by 2,602
Wu, Y., Zhou, W., Zhao, J., Dong, W., Lan, Y., Li, D., Sun, C., & Bu, X. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201707238 · Cited by 386
Recent advances in single atom catalysts for the electrochemical carbon dioxide reduction reaction
Zhang, J., Cai, W., Hu, F. X., Yang, H., & Liu, B. (2021) · Chemical Science · doi:10.1039/d1sc01375k · Cited by 284
Stability limits of tin-based electrocatalyst supports
Geiger, S., Kasian, O., Mingers, A. M., Mayrhofer, K. J. J., & Cherevko, S. (2017) · Scientific Reports · doi:10.1038/s41598-017-04079-9 · Cited by 182
Metadata
- Authors
- Sheehan, S. W., Thomsen, J. M., Hintermair, U., Crabtree, R. H., Brudvig, G. W., & Schmuttenmaer, C. A.
- Venue
- Nature Communications
- Published
- 2015-03-11
- Volume
- 6
- Issue
- 1
- Pages
- 6469-6469
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W1995566836
- Cited by
- 284
- References
- 4
- FWCI
- 12.90
- Type
- journal article
- Language
- en
- Open access
- gold
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
