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Copper-on-nitride enhances the stable electrosynthesis of multi-carbon products from CO2
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Copper-based materials are promising electrocatalysts for CO 2 reduction. Prior studies show that the mixture of copper (I) and copper (0) at the catalyst surface enhances multi-carbon products from CO 2 reduction; however, the stable presence of copper (I) remains the subject of debate. Here we report a copper on copper (I) composite that stabilizes copper (I) during CO 2 reduction through the use of copper nitride as an underlying copper (I) species. We synthesize a copper-on-nitride catalyst that exhibits a Faradaic efficiency of 64 ± 2% for C 2+ products. We achieve a 40-fold enhancement in the ratio of C 2+ to the competing CH 4 compared to the case of pure copper. We further show that the copper-on-nitride catalyst performs stable CO 2 reduction over 30 h. Mechanistic studies suggest that the use of copper nitride contributes to reducing the CO dimerization energy barrier—a rate-limiting step in CO 2 reduction to multi-carbon products.
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“Thus, by altering the reaction environment through increased electric fields (e.g.larger cations in the electrolyte), increased CO coverage (e.g. higher CO2 pressure), and/or increased catalyst strain (e.g.engineering a core-shell structure [63] ) it is possible to improve the catalytic activity towards multi-carbon products.”
From Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [63]
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Self-citationImproved performance of TiN nano buds decorated MoS2 sheets in asymmetric supercapacitors
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Self-citation
Metadata
- Authors
- Liang, Z.-Q., Zhuang, T.-T., Seifitokaldani, A., Li, J., Huang, C.-W., Tan, C.-S., Li, Y., De Luna, P., Dinh, C. T., Hu, Y., Xiao, Q., Hsieh, P.-L., Wang, Y., Li, F., Quintero-Bermudez, R., Zhou, Y., Chen, P., Pang, Y., Lo, S.-C., Chen, L.-J., Tan, H., Xu, Z., Zhao, S., Sinton, D., & Sargent, E. H.
- Affiliations
- University of Toronto (CA)
- Industrial Technology Research Institute (TW)
- University of Science and Technology of China (CN)
- Canadian Light Source (Canada) (CA)
- National Tsing Hua University (TW)
- Beijing Jiaotong University (CN)
- Corresponding author
- Sargent, Edward H.
- ORCID
- Venue
- Nature Communications
- Published
- 2018-09-20
- Volume
- 9
- Issue
- 1
- Pages
- 3828-3828
- ISSN
- 2041-1723 (ISSN-L)
- PMC
- PMC6148248
- OpenAlex
- W2889577864
- Cited by
- 393
- References
- 48
- Citations by year
- 2026: 22 · 2025: 48 · 2024: 62 · 2023: 64 · 2022: 58 · 2021: 59 · 2020: 54 · 2019: 25 · 2018: 1
- FWCI
- 8.03
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Locations
- Nature Communications (publishedVersion, cc-by)
- Europe PMC (PubMed Central) (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- Canadian Institute for Advanced Research
- Canadian Light Source
- University of Saskatchewan
- Ontario Centres of Excellence
- Nederlandse Organisatie voor Wetenschappelijk Onderzoek (680-50-1511, 680-50-151)
- University of Toronto
- Mitacs
- China Scholarship Council
- Beijing Jiaotong University
- Canadian Institutes of Health Research
- Natural Sciences and Engineering Research Council of Canada
- Western Economic Diversification Canada
- National Research Council Canada
- Fonds de recherche du Québec – Nature et technologies
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Keywords
- CO2 reduction, copper electrocatalysts, copper nitride, multi-carbon products, Faradaic efficiency, CO dimerization, reaction mechanism, catalyst stability, methane selectivity
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