The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts
Open accessAbstract
The electrochemical carbon dioxide reduction reaction to syngas with controlled CO/H 2 ratios has been studied on Pd-based bimetallic hydrides using a combination of in situ characterization and density functional theory calculations. When compared with pure Pd hydride, the bimetallic Pd hydride formation occurs at more negative potentials for Pd-Ag, Pd-Cu, and Pd-Ni. Theoretical calculations show that the choice of the second metal has a more significant effect on the adsorption strength of *H than *HOCO, with the free energies between these two key intermediates (i.e., ΔG(*H)–ΔG(*HOCO)) correlating well with the carbon dioxide reduction reaction activity and selectivity observed in the experiments, and thus can be used as a descriptor to search for other bimetallic catalysts. The results also demonstrate the possibility of alloying Pd with non-precious transition metals to promote the electrochemical conversion of CO 2 to syngas.
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Cites
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
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Density functional theory studies of transition metal carbides and nitrides as electrocatalysts
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Self-citationRecent Progress on Rational Design of Bimetallic Pd Based Catalysts and Their Advanced Catalysis
Fan, J., Du, H., Zhao, Y., Wang, Q., Liu, Y., Li, D., & Feng, J. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c03280 · Cited by 265
Accelerating CO2 Electroreduction to CO Over Pd Single‐Atom Catalyst
He, Q., Lee, J. H., Liu, D., Liu, Y., Lin, Z., Xie, Z., Hwang, S., Kattel, S., Song, L., & Chen, J. G. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000407 · Cited by 257
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Metadata
- Authors
- Lee, J. H., Kattel, S., Jiang, Z., Xie, Z., Yao, S., Tackett, B. M., Xu, W., Marinkovic, N. S., & Chen, J. G.
- Venue
- Nature Communications
- Published
- 2019-08-19
- Volume
- 10
- Issue
- 1
- Pages
- 3724-3724
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2969921980
- Cited by
- 244
- References
- 10
- FWCI
- 6.65
- Type
- journal article
- Language
- en
- Open access
- gold
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- Lee, J. H., Kattel, S., Jiang, Z., Xie, Z., Yao, S., Tackett, B. M., Xu, W., Marinkovic, N. S., & Chen, J. G. (2019). Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts. Nature Communications. https://doi.org/10.1038/s41467-019-11352-0
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