Rational Design of Efficient Palladium Catalysts for Electroreduction of Carbon Dioxide to Formate
Open accessAbstract
The electrochemical reduction of CO 2 into renewable chemical products such as formic acid is an important and challenging goal. Traditional Pd catalysts suffer from CO poisoning, which leads to current density decay and short operating lifetimes. Here we explored the ability to control Pd nanoparticle surface morphology to amplify catalytic activity and increase stability in the electroreduction of CO 2 to formate. Through computational studies we have elucidated trends in intermediate binding which govern the selectivity and catalytic activity. We then rationally synthesized Pd nanoparticles having an abundance of high-index surfaces to maximize electrocatalytic performance. This catalyst displays a record current density of 22 mA/cm 2 at a low overpotential of −0.2 V with a Faradaic efficiency of 97%, outperforming all previous Pd catalysts in formate electrosynthesis. The findings presented in this work provide rational design principles which highlight morphological control of high-index surfaces for the effective and stable catalytic electroreduction of CO 2 to liquid fuels.
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GBs create catalytically active strained regions in polycrystalline Au by stabilizing dislocations.
“It was revealed that GBs create catalytically active strained regions in polycrystalline Au by stabilizing dislocations.”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [80]
Mariano et al. verified high CO2RR selectivity for GBs using scanning electrochemical cell microscopy.
“Recently, Mariano et al. verified the high CO2RR selectivity for GBs using scanning electrochemical cell microscopy.[80]”
From Electrochemical CO <sub>2</sub> Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [80]
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Self-citation
- Authors
- Klinkova, A., De Luna, P., Dinh, C.-T., Voznyy, O., Larin, E. M., Kumacheva, E., & Sargent, E. H.
- Affiliations
- University of Toronto (CA)
- Department of Materials Science & Engineering, University of Toronto , 184 College Street, Toronto, Ontario M5S 3E4, Canada
- Corresponding author
- Kumacheva, Eugenia
- Sargent, Edward H.
- ORCID
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2016-11-02
- Volume
- 6
- Issue
- 12
- Pages
- 8115-8120
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2531985189
- Cited by
- 342
- References
- 32
- Citations by year
- 2026: 9 · 2025: 31 · 2024: 28 · 2023: 36 · 2022: 41 · 2021: 48 · 2020: 48 · 2019: 45 · 2018: 40 · 2017: 16
- FWCI
- 9.15
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Locations
- ACS Catalysis (publishedVersion)
- TSpace (University of Toronto) (submittedVersion)
- Funders
- Connaught Fund
- Natural Sciences and Engineering Research Council of Canada
- Canadian Institute for Advanced Research
- Ontario Research Fund
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- palladium electrocatalysts, electrochemical CO2 reduction, CO poisoning, high-index surfaces, Faradaic efficiency, catalyst stability, liquid fuels
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