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Carbon dioxide electroreduction to C2 products over copper-cuprous oxide derived from electrosynthesized copper complex
Open accessAbstract
Efficient electroreduction of carbon dioxide to multicarbon products in aqueous solution is of great importance and challenging. Unfortunately, the low efficiency of the production of C 2 products limits implementation at scale. Here, we report reduction of carbon dioxide to C 2 products (acetic acid and ethanol) over a 3D dendritic copper-cuprous oxide composite fabricated by in situ reduction of an electrodeposited copper complex. In potassium chloride aqueous electrolyte, the applied potential was as low as −0.4 V vs reversible hydrogen electrode, the overpotential is only 0.53 V (for acetic acid) and 0.48 V (for ethanol) with high C 2 Faradaic efficiency of 80% and a current density of 11.5 mA cm−2. The outstanding performance of the electrode for producing the C 2 products results mainly from near zero contacting resistance between the electrocatalysts and copper substrate, abundant exposed active sites in the 3D dendritic structure and suitable copper(I)/copper(0) ratio of the electrocatalysts.
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A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
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Self-citationCO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
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Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
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Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
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Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
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Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Highly Electrocatalytic Ethylene Production from CO2 on Nanodefective Cu Nanosheets
Zhang, B., Zhang, J., Hua, M., Wan, Q., Su, Z., Tan, X., Liu, L., Zhang, F., Chen, G., Tan, D., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c06420 · Cited by 459
Self-citationElectrocatalytic CO2 hydrogenation to C2+ alcohols catalysed by Pr–Cu oxide heterointerfaces
Liu, J., Li, P., Jia, S., Wang, Y., Jing, L., Liu, Z., Zhang, J., Qian, Q., Kang, X., Sun, X., et al. (2025) · Nature Synthesis · doi:10.1038/s44160-025-00752-4 · Cited by 96
Self-citationBeyazay, T., Belthle, K. S., Farès, C., Preiner, M., Moran, J., Martin, W. F., & Tüysüz, H. (2023) · Nature Communications · doi:10.1038/s41467-023-36088-w · Cited by 72
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Metadata
- Authors
- Zhu, Q., Sun, X., Yang, D., Ma, J., Kang, X., Zheng, L., Zhang, J., Wu, Z., & Han, B.
- Venue
- Nature Communications
- Published
- 2019-08-26
- Volume
- 10
- Issue
- 1
- Pages
- 3851-3851
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2970220256
- Cited by
- 440
- References
- 14
- FWCI
- 11.44
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhu, Q., Sun, X., Yang, D., Ma, J., Kang, X., Zheng, L., Zhang, J., Wu, Z., & Han, B. (2019). Carbon dioxide electroreduction to C2 products over copper-cuprous oxide derived from electrosynthesized copper complex. Nature Communications. https://doi.org/10.1038/s41467-019-11599-7
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