The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Bismuth atom tailoring of indium oxide surface frustrated Lewis pairs boosts heterogeneous CO2 photocatalytic hydrogenation
Open accessAbstract
The surface frustrated Lewis pairs (SFLPs) on defect-laden metal oxides provide catalytic sites to activate H 2 and CO 2 molecules and enable efficient gas-phase CO 2 photocatalysis. Lattice engineering of metal oxides provides a useful strategy to tailor the reactivity of SFLPs. Herein, a one-step solvothermal synthesis is developed that enables isomorphic replacement of Lewis acidic site In 3+ ions in In 2 O 3 by single-site Bi 3+ ions, thereby enhancing the propensity to activate CO 2 molecules. The so-formed Bi x In 2-x O 3 materials prove to be three orders of magnitude more photoactive for the reverse water gas shift reaction than In 2 O 3 itself, while also exhibiting notable photoactivity towards methanol production. The increased solar absorption efficiency and efficient charge-separation and transfer of Bi x In 2-x O 3 also contribute to the improved photocatalytic performance. These traits exemplify the opportunities that exist for atom-scale engineering in heterogeneous CO 2 photocatalysis, another step towards the vision of the solar CO 2 refinery.
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Cites
Recent advances in catalytic hydrogenation of carbon dioxide
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Cited by
Fang, S., Rahaman, M., Bharti, J., Reisner, E., Robert, M., Ozin, G. A., & Hu, Y. H. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00243-w · Cited by 834
Self-citationSingle-atom catalysts for photocatalytic energy conversion
Xue, Z.-H., Luan, D., Zhang, H., & (David) Lou, X. W. (2022) · Joule · doi:10.1016/j.joule.2021.12.011 · Cited by 567
Role of oxygen vacancy in metal oxides for photocatalytic CO2 reduction
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Metadata
- Authors
- Yan, T., Li, N., Wang, L., Ran, W., Duchesne, P. N., Wan, L., Nguyen, N. T., Wang, L., Xia, M., & Ozin, G. A.
- Venue
- Nature Communications
- Published
- 2020-11-30
- Volume
- 11
- Issue
- 1
- Pages
- 6095-6095
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W3108606708
- Cited by
- 292
- References
- 36
- FWCI
- 5.54
- Type
- journal article
- Language
- en
- Open access
- gold
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- Yan, T., Li, N., Wang, L., Ran, W., Duchesne, P. N., Wan, L., Nguyen, N. T., Wang, L., Xia, M., & Ozin, G. A. (2020). Bismuth atom tailoring of indium oxide surface frustrated Lewis pairs boosts heterogeneous CO2 photocatalytic hydrogenation. Nature Communications. https://doi.org/10.1038/s41467-020-19997-y
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