The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
In situ dual doping for constructing efficient CO2-to-methanol electrocatalysts
Open accessAbstract
Methanol is a highly desirable product of CO 2 electroreduction due to its wide array of industrial applications. However, the development of CO 2-to-methanol electrocatalysts with high performance is still challenging. Here we report an operationally simple in situ dual doping strategy to construct efficient CO 2-to-methanol electrocatalysts. In particular, when using Ag,S-Cu 2 O/Cu as electrocatalyst, the methanol Faradaic efficiency (FE) could reach 67.4% with a current density as high as 122.7 mA cm−2 in an H-type cell using 1-butyl-3-methylimidazolium tetrafluoroborate/H 2 O as the electrolyte, while the current density was below 50 mA cm−2 when the FE was greater than 50% over the reported catalysts. Experimental and theoretical studies suggest that the anion S can effectively adjust the electronic structure and morphology of the catalysts in favor of the methanol pathway, whereas the cation Ag suppresses the hydrogen evolution reaction. Their synergistic interactions with host material enhance the selectivity and current density for methanol formation. This work opens a way for designing efficient catalysts for CO 2 electroreduction to methanol.
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Cites
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Cited by
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y., Wang, M., Wu, C., Zhang, L., Li, X., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 299
Engineering Cu(I)/Cu(0) interfaces for efficient ethanol production from CO2 electroreduction
Cai, R., Sun, M., Yang, F., Ju, M., Chen, Y., Gu, M. D., Huang, B., & Yang, S. (2024) · Chem · doi:10.1016/j.chempr.2023.08.027 · Cited by 142
Nicole, S. L. D., Li, Y., Xie, W., Wang, G., & Lee, J. (2023) · Small · doi:10.1002/smll.202206844 · Cited by 132
Sui, N. L. D., & Lee, J. (2025) · Small · doi:10.1002/smll.202410390 · Cited by 12
Metadata
- Authors
- Li, P., Bi, J., Liu, J., Zhu, Q., Chen, C., Sun, X., Zhang, J., & Han, B.
- Venue
- Nature Communications
- Published
- 2022-04-12
- Volume
- 13
- Issue
- 1
- Pages
- 1965-1965
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4223555807
- Cited by
- 241
- References
- 8
- FWCI
- 9.51
- Type
- journal article
- Language
- en
- Open access
- gold
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- Li, P., Bi, J., Liu, J., Zhu, Q., Chen, C., Sun, X., Zhang, J., & Han, B. (2022). In situ dual doping for constructing efficient CO2-to-methanol electrocatalysts. Nature Communications. https://doi.org/10.1038/s41467-022-29698-3
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