The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Surface passivation for highly active, selective, stable, and scalable CO2 electroreduction
Open accessAbstract
Electrochemical conversion of CO 2 to formic acid using Bismuth catalysts is one the most promising pathways for industrialization. However, it is still difficult to achieve high formic acid production at wide voltage intervals and industrial current densities because the Bi catalysts are often poisoned by oxygenated species. Herein, we report a Bi 3 S 2 nanowire-ascorbic acid hybrid catalyst that simultaneously improves formic acid selectivity, activity, and stability at high applied voltages. Specifically, a more than 95% faraday efficiency was achieved for the formate formation over a wide potential range above 1.0 V and at ampere-level current densities. The observed excellent catalytic performance was attributable to a unique reconstruction mechanism to form more defective sites while the ascorbic acid layer further stabilized the defective sites by trapping the poisoning hydroxyl groups. When used in an all-solid-state reactor system, the newly developed catalyst achieved efficient production of pure formic acid over 120 hours at 50 mA cm–2 (200 mA cell current).
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Citations
Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
What would it take for renewably powered electrosynthesis to displace petrochemical processes?
De Luna, P., Hahn, C., Higgins, D., Jaffer, S. A., Jaramillo, T. F., & Sargent, E. H. (2019) · Science · doi:10.1126/science.aav3506 · Cited by 3,052
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
What Should We Make with CO2 and How Can We Make It?
Bushuyev, O. S., De Luna, P., Dinh, C. T., Tao, L., Saur, G., van de Lagemaat, J., Kelley, S. O., & Sargent, E. H. (2018) · Joule · doi:10.1016/j.joule.2017.09.003 · Cited by 1,593
CO 2 electrolysis to multicarbon products at activities greater than 1 A cm −2
García de Arquer, F. P., Dinh, C.-T., Ozden, A., Wicks, J., McCallum, C., Kirmani, A. R., Nam, D.-H., Gabardo, C., Seifitokaldani, A., Wang, X., et al. (2020) · Science · doi:10.1126/science.aay4217 · Cited by 1,517
CO 2 electrolysis to multicarbon products in strong acid
Huang, J. E., Li, F., Ozden, A., Sedighian Rasouli, A., García de Arquer, F. P., Liu, S., Zhang, S., Luo, M., Wang, X., Lum, Y., et al. (2021) · Science · doi:10.1126/science.abg6582 · Cited by 1,359
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Xia, C., Zhu, P., Jiang, Q., Pan, Y., Liang, W., Stavitski, E., Alshareef, H. N., & Wang, H. (2019) · Nature Energy · doi:10.1038/s41560-019-0451-x · Cited by 782
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Cited by
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y., Wang, M., Wu, C., Zhang, L., Li, X., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 299
Metadata
- Authors
- Zhu, J., Li, J., Lu, R., Yu, R., Zhao, S., Li, C., Lv, L., Xia, L., Chen, X., Cai, W., Meng, J., Zhang, W., Pan, X., Hong, X., Dai, Y., Mao, Y., Li, J., Zhou, L., He, G., Pang, Q., Zhao, Y., Xia, C., Wang, Z., Dai, L., & Mai, L.
- Venue
- Nature Communications
- Published
- 2023-08-03
- Volume
- 14
- Issue
- 1
- Pages
- 4670-4670
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4385515842
- Cited by
- 163
- References
- 9
- FWCI
- 7.63
- Type
- journal article
- Language
- en
- Open access
- gold
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- Zhu, J., Li, J., Lu, R., Yu, R., Zhao, S., Li, C., Lv, L., Xia, L., Chen, X., Cai, W., Meng, J., Zhang, W., Pan, X., Hong, X., Dai, Y., Mao, Y., Li, J., Zhou, L., He, G., . . . Mai, L. (2023). Surface passivation for highly active, selective, stable, and scalable CO2 electroreduction. Nature Communications. https://doi.org/10.1038/s41467-023-40342-6
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.