The DOI matches its Crossref record; 42 of the 42 references it cites were found in a registry or an index.
Nitrogen-doped graphene: beyond single substitution and enhanced molecular sensing
Open accessAbstract
Graphene is a two-dimensional network in which sp(2)-hybridized carbon atoms are arranged in two different triangular sub-lattices (A and B). By incorporating nitrogen atoms into graphene, its physico-chemical properties could be significantly altered depending on the doping configuration within the sub-lattices. Here, we describe the synthesis of large-area, highly-crystalline monolayer N-doped graphene (NG) sheets via atmospheric-pressure chemical vapor deposition, yielding a unique N-doping site composed of two quasi-adjacent substitutional nitrogen atoms within the same graphene sub-lattice (N(2)(AA)). Scanning tunneling microscopy and spectroscopy (STM and STS) of NG revealed the presence of localized states in the conduction band induced by N(2)(AA)-doping, which was confirmed by ab initio calculations. Furthermore, we demonstrated for the first time that NG could be used to efficiently probe organic molecules via a highly improved graphene enhanced Raman scattering.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Self-Consistent Equations Including Exchange and Correlation Effects
Kohn, W., & Sham, L. J. (1965) · Physical Review · doi:10.1103/physrev.140.a1133 · Cited by 64,135
Hohenberg, P., & Kohn, W. (1964) · Physical Review · doi:10.1103/physrev.136.b864 · Cited by 53,541
Efficient pseudopotentials for plane-wave calculations
Troullier, N., & Martins, J. L. (1991) · Physical Review B · doi:10.1103/physrevb.43.1993 · Cited by 16,148
Raman Spectrum of Graphene and Graphene Layers
Ferrari, A. C., Meyer, J. C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K. S., Roth, S., et al. (2006) · Physical Review Letters · doi:10.1103/physrevlett.97.187401 · Cited by 15,047
The SIESTA method for ab initio order-N materials simulation
Soler, J. M., Artacho, E., Gale, J. D., García, A., Junquera, J., Ordejón, P., & Sánchez-Portal, D. (2002) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/14/11/302 · Cited by 12,218
Large Area, Few-Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition
Reina, A., Jia, X., Ho, J., Nezich, D., Son, H., Bulovic, V., Dresselhaus, M. S., & Kong, J. (2009) · Nano Letters · doi:10.1021/nl801827v · Cited by 5,881
Theory of the scanning tunneling microscope
Tersoff, J., & Hamann, D. R. (1985) · Physical Review B · doi:10.1103/physrevb.31.805 · Cited by 4,411
Nitrogen-Doped Graphene as Efficient Metal-Free Electrocatalyst for Oxygen Reduction in Fuel Cells
Qu, L., Liu, Y., Baek, J.-B., & Dai, L. (2010) · ACS Nano · doi:10.1021/nn901850u · Cited by 3,948
Monitoring dopants by Raman scattering in an electrochemically top-gated graphene transistor
Das, A., Pisana, S., Chakraborty, B., Piscanec, S., Saha, S. K., Waghmare, U. V., Novoselov, K. S., Krishnamurthy, H. R., Geim, A. K., Ferrari, A. C., et al. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.67 · Cited by 3,621
Synthesis of N-Doped Graphene by Chemical Vapor Deposition and Its Electrical Properties
Wei, D., Liu, Y., Wang, Y., Zhang, H., Huang, L., & Yu, G. (2009) · Nano Letters · doi:10.1021/nl803279t · Cited by 3,074
Doping Graphene with Metal Contacts
Giovannetti, G., Khomyakov, P. A., Brocks, G., Karpan, V. M., van den Brink, J., & Kelly, P. J. (2008) · Physical Review Letters · doi:10.1103/physrevlett.101.026803 · Cited by 2,605
Nitrogen-Doped Graphene and Its Application in Electrochemical Biosensing
Wang, Y., Shao, Y., Matson, D. W., Li, J., & Lin, Y. (2010) · ACS Nano · doi:10.1021/nn100315s · Cited by 2,155
N-Doping of Graphene Through Electrothermal Reactions with Ammonia
Wang, X., Li, X., Zhang, L., Yoon, Y., Weber, P. K., Wang, H., Guo, J., & Dai, H. (2009) · Science · doi:10.1126/science.1170335 · Cited by 2,152
Synthesis, Structure, and Properties of Boron‐ and Nitrogen‐Doped Graphene
Panchakarla, L. S., Subrahmanyam, K. S., Saha, S. K., Govindaraj, A., Krishnamurthy, H. R., Waghmare, U. V., & Rao, C. N. R. (2009) · Advanced Materials · doi:10.1002/adma.200901285 · Cited by 1,804
Quantifying ion-induced defects and Raman relaxation length in graphene
Lucchese, M. M., Stavale, F., Ferreira, E. H. M., Vilani, C., Moutinho, M. V. O., Capaz, R. B., Achete, C. A., & Jorio, A. (2010) · Carbon · doi:10.1016/j.carbon.2009.12.057 · Cited by 1,784
Synthesis Of Nitrogen-Doped Graphene Films For Lithium Battery Application
Reddy, A. L. M., Srivastava, A., Gowda, S. R., Gullapalli, H., Dubey, M., & Ajayan, P. M. (2010) · ACS Nano · doi:10.1021/nn101926g · Cited by 1,642
Yu, Q., Jauregui, L. A., Wu, W., Colby, R., Tian, J., Su, Z., Cao, H., Liu, Z., Pandey, D., Wei, D., et al. (2011) · Nature Materials · doi:10.1038/nmat3010 · Cited by 1,497
Surface-enhanced Raman scattering
Otto, A., Mrozek, I., Grabhorn, H., & Akemann, W. (1992) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/4/5/001 · Cited by 1,428
Growth of graphene from solid carbon sources
Sun, Z., Yan, Z., Yao, J., Beitler, E., Zhu, Y., & Tour, J. M. (2010) · Nature · doi:10.1038/nature09579 · Cited by 1,363
First-principles study of the interaction and charge transfer between graphene and metals
Khomyakov, P. A., Giovannetti, G., Rusu, P. C., Brocks, G., van den Brink, J., & Kelly, P. J. (2009) · Physical Review B · doi:10.1103/physrevb.79.195425 · Cited by 1,230
Can Graphene be used as a Substrate for Raman Enhancement?
Ling, X., Xie, L., Fang, Y., Xu, H., Zhang, H., Kong, J., Dresselhaus, M. S., Zhang, J., & Liu, Z. (2010) · Nano Letters · doi:10.1021/nl903414x · Cited by 1,067
Toward N-Doped Graphene via Solvothermal Synthesis
Deng, D., Pan, X., Yu, L., Cui, Y., Jiang, Y., Qi, J., Li, W.-X., Fu, Q., Ma, X., Xue, Q., et al. (2011) · Chemistry of Materials · doi:10.1021/cm102666r · Cited by 1,064
Visualizing Individual Nitrogen Dopants in Monolayer Graphene
Zhao, L., He, R., Rim, K. T., Schiros, T., Kim, K. S., Zhou, H., Gutiérrez, C., Chockalingam, S. P., Arguello, C. J., Pálová, L., et al. (2011) · Science · doi:10.1126/science.1208759 · Cited by 872
Scattering and Interference in Epitaxial Graphene
Rutter, G. M., Crain, J. N., Guisinger, N. P., Li, T., First, P. N., & Stroscio, J. A. (2007) · Science · doi:10.1126/science.1142882 · Cited by 743
Gas adsorption on graphene doped with B, N, Al, and S: A theoretical study
Dai, J., Yuan, J., & Giannozzi, P. (2009) · Applied Physics Letters · doi:10.1063/1.3272008 · Cited by 734
Large-Scale Growth and Characterizations of Nitrogen-Doped Monolayer Graphene Sheets
Jin, Z., Yao, J., Kittrell, C., & Tour, J. M. (2011) · ACS Nano · doi:10.1021/nn200766e · Cited by 642
Graphene as a Substrate To Suppress Fluorescence in Resonance Raman Spectroscopy
Xie, L., Ling, X., Fang, Y., Zhang, J., & Liu, Z. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9037593 · Cited by 523
Giant phonon-induced conductance in scanning tunnelling spectroscopy of gate-tunable graphene
Zhang, Y., Brar, V. W., Wang, F., Girit, C., Yayon, Y., Panlasigui, M., Zettl, A., & Crommie, M. F. (2008) · Nature Physics · doi:10.1038/nphys1022 · Cited by 476
N-doping and coalescence of carbon nanotubes: synthesis and electronic properties
Terrones, M., Ajayan, P. M., Banhart, F., Blase, X., Carroll, D. L., Charlier, J. C., Czerw, R., Foley, B., Grobert, N., Kamalakaran, R., et al. (2002) · Applied Physics A: Materials Science & Processing · doi:10.1007/s003390201278 · Cited by 415
Self-citationA direct transfer of layer-area graphene
Regan, W., Alem, N., Alemán, B., Geng, B., Girit, Ç., Maserati, L., Wang, F., Crommie, M., & Zettl, A. (2010) · Applied Physics Letters · doi:10.1063/1.3337091 · Cited by 390
Lv, R., Cui, T., Jun, M., Zhang, Q., Cao, A., Su, D. S., Zhang, Z., Yoon, S., Miyawaki, J., Mochida, I., et al. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201001602 · Cited by 375
Self-citationYu, X., Cai, H., Zhang, W., Li, X., Pan, N., Luo, Y., Wang, X., & Hou, J. G. (2011) · ACS Nano · doi:10.1021/nn102291j · Cited by 373
Biocompatibility and Toxicological Studies of Carbon Nanotubes Doped with Nitrogen
Carrero-Sánchez, J. C., Elías, A. L., Mancilla, R., Arrellín, G., Terrones, H., Laclette, J. P., & Terrones, M. (2006) · Nano Letters · doi:10.1021/nl060548p · Cited by 353
Self-citationMeasuring disorder in graphene with the G and D bands
Jorio, A., Ferreira, E. H. M., Moutinho, M. V. O., Stavale, F., Achete, C. A., & Capaz, R. B. (2010) · physica status solidi (b) · doi:10.1002/pssb.201000247 · Cited by 307
Meyer, J. C., Kurasch, S., Park, H. J., Skakalova, V., Künzel, D., Groß, A., Chuvilin, A., Algara-Siller, G., Roth, S., Iwasaki, T., et al. (2011) · Nature Materials · doi:10.1038/nmat2941 · Cited by 296
Chemical Contribution to Surface-Enhanced Raman Scattering
Persson, B. N. J., Zhao, K., & Zhang, Z. (2006) · Physical Review Letters · doi:10.1103/physrevlett.96.207401 · Cited by 226
Effect of Graphene Fermi Level on the Raman Scattering Intensity of Molecules on Graphene
Xu, H., Xie, L., Zhang, H., & Zhang, J. (2011) · ACS Nano · doi:10.1021/nn103237x · Cited by 218
Grain boundary loops in graphene
Cockayne, E., Rutter, G. M., Guisinger, N. P., Crain, J. N., First, P. N., & Stroscio, J. A. (2011) · Physical Review B · doi:10.1103/physrevb.83.195425 · Cited by 187
Raman spectroscopy as a probe of graphene and carbon nanotubes
Dresselhaus, M. S., Dresselhaus, G., & Hofmann, M. (2008) · Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2007.2155 · Cited by 165
Enhanced Electron Field Emission in B-doped Carbon Nanotubes
Charlier, J., Terrones, M., Baxendale, M., Meunier, V., Zacharia, T., Rupesinghe, N. L., Hsu, W. K., Grobert, N., Terrones, H., & Amaratunga, G. (2002) · Nano Letters · doi:10.1021/nl0256457 · Cited by 142
Self-citationElías, A. L., Carrero, J. C., Terrones, H., Endo, M., Laclette, J. P., & Terrones, M. (2007) · Small · doi:10.1002/smll.200700331 · Cited by 59
Self-citation
Cited by
Heteroatom-doped graphene materials: syntheses, properties and applications
Wang, X., Sun, G., Routh, P., Kim, D.-H., Huang, W., & Chen, P. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00141a · Cited by 1,891
Nitrogen-doped carbon materials
Inagaki, M., Toyoda, M., Soneda, Y., & Morishita, T. (2018) · Carbon · doi:10.1016/j.carbon.2018.02.024 · Cited by 867
High Performance Fe- and N- Doped Carbon Catalyst with Graphene Structure for Oxygen Reduction
Peng, H., Mo, Z., Liao, S., Liang, H., Yang, L., Luo, F., Song, H., Zhong, Y., & Zhang, B. (2013) · Scientific Reports · doi:10.1038/srep01765 · Cited by 601
Chemical functionalization and characterization of graphene-based materials
Bottari, G., Herranz, M. Á., Wibmer, L., Volland, M., Rodríguez-Pérez, L., Guldi, D. M., Hirsch, A., Martín, N., D'Souza, F., & Torres, T. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00229g · Cited by 441
Graphene-based flexible electronic devices
Han, T.-H., Kim, H., Kwon, S.-J., & Lee, T.-W. (2017) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2017.05.001 · Cited by 304
Metadata
- Authors
- Lv, R., Li, Q., Botello-Méndez, A. R., Hayashi, T., Wang, B., Berkdemir, A., Hao, Q., Elías, A. L., Cruz-Silva, R., Gutiérrez, H. R., Kim, Y. A., Muramatsu, H., Zhu, J., Endo, M., Terrones, H., Charlier, J.-C., Pan, M., & Terrones, M.
- Venue
- Scientific Reports
- Published
- 2012-08-17
- Volume
- 2
- Issue
- 1
- Pages
- 586-586
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W2025110867
- Cited by
- 655
- References
- 42
- FWCI
- 27.37
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
