The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
The edge- and basal-plane-specific electrochemistry of a single-layer graphene sheet
Open accessAbstract
Graphene has a unique atom-thick two-dimensional structure and excellent properties, making it attractive for a variety of electrochemical applications, including electrosynthesis, electrochemical sensors or electrocatalysis, and energy conversion and storage. However, the electrochemistry of single-layer graphene has not yet been well understood, possibly due to the technical difficulties in handling individual graphene sheet. Here, we report the electrochemical behavior at single-layer graphene-based electrodes, comparing the basal plane of graphene to its edge. The graphene edge showed 4 orders of magnitude higher specific capacitance, much faster electron transfer rate and stronger electrocatalytic activity than those of graphene basal plane. A convergent diffusion effect was observed at the sub-nanometer thick graphene edge-electrode to accelerate the electrochemical reactions. Coupling with the high conductivity of a high-quality graphene basal plane, graphene edge is an ideal electrode for electrocatalysis and for the storage of capacitive charges.
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Cites
Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils
Li, X., Cai, W., An, J., Kim, S., Nah, J., Yang, D., Piner, R., Velamakanni, A., Jung, I., Tutuc, E., et al. (2009) · Science · doi:10.1126/science.1171245 · Cited by 11,220
Carbon-Based Supercapacitors Produced by Activation of Graphene
Zhu, Y., Murali, S., Stoller, M. D., Ganesh, K. J., Cai, W., Ferreira, P. J., Pirkle, A., Wallace, R. M., Cychosz, K. A., Thommes, M., et al. (2011) · Science · doi:10.1126/science.1200770 · Cited by 6,140
Huang, X., Qi, X., Boey, F., & Zhang, H. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15078b · Cited by 3,837
Graphene-Based Supercapacitor with an Ultrahigh Energy Density
Liu, C., Yu, Z., Neff, D., Zhamu, A., & Jang, B. Z. (2010) · Nano Letters · doi:10.1021/nl102661q · Cited by 3,207
Transfer of CVD-Grown Monolayer Graphene onto Arbitrary Substrates
Suk, J. W., Kitt, A., Magnuson, C. W., Hao, Y., Ahmed, S., An, J., Swan, A. K., Goldberg, B. B., & Ruoff, R. S. (2011) · ACS Nano · doi:10.1021/nn201207c · Cited by 1,495
Ultrathin Planar Graphene Supercapacitors
Yoo, J. J., Balakrishnan, K., Huang, J., Meunier, V., Sumpter, B. G., Srivastava, A., Conway, M., Mohana Reddy, A. L., Yu, J., Vajtai, R., et al. (2011) · Nano Letters · doi:10.1021/nl200225j · Cited by 1,236
Graphene for electrochemical sensing and biosensing
Pumera, M., Ambrosi, A., Bonanni, A., Chng, E. L. K., & Poh, H. L. (2010) · TrAC Trends in Analytical Chemistry · doi:10.1016/j.trac.2010.05.011 · Cited by 1,199
Banks, C. E., Davies, T. J., Wildgoose, G. G., & Compton, R. G. (2005) · Chemical Communications · doi:10.1039/b413177k · Cited by 1,023
Protein Electrochemistry Using Aligned Carbon Nanotube Arrays
Gooding, J. J., Wibowo, R., Liu, Yang, W., Losic, D., Orbons, S., Mearns, F. J., Shapter, J. G., & Hibbert, D. B. (2003) · Journal of the American Chemical Society · doi:10.1021/ja035722f · Cited by 881
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Self-citationWu, G., Santandreu, A., Kellogg, W., Gupta, S., Ogoke, O., Zhang, H., Wang, H.-L., & Dai, L. (2016) · Nano Energy · doi:10.1016/j.nanoen.2015.12.032 · Cited by 744
Self-citationCarbon-based electrocatalysts for advanced energy conversion and storage
Zhang, J., Xia, Z., & Dai, L. (2015) · Science Advances · doi:10.1126/sciadv.1500564 · Cited by 735
Self-citationZhang, J., & Dai, L. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01563 · Cited by 590
Self-citationCheng, Q., Hu, C., Wang, G., Zou, Z., Yang, H., & Dai, L. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b11524 · Cited by 303
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Metadata
- Authors
- Yuan, W., Zhou, Y., Li, Y., Li, C., Peng, H., Zhang, J., Liu, Z., Dai, L., & Shi, G.
- Venue
- Scientific Reports
- Published
- 2013-07-30
- Volume
- 3
- Issue
- 1
- Pages
- 2248-2248
- ISSN
- 2045-2322 (ISSN-L)
- OpenAlex
- W1967276707
- Cited by
- 527
- References
- 33
- FWCI
- 20.43
- Type
- journal article
- Language
- en
- Open access
- gold
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- Yuan, W., Zhou, Y., Li, Y., Li, C., Peng, H., Zhang, J., Liu, Z., Dai, L., & Shi, G. (2013). The edge- and basal-plane-specific electrochemistry of a single-layer graphene sheet. Scientific Reports. https://doi.org/10.1038/srep02248
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