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Kinetics and reaction chemistry for slow pyrolysis of enzymatic hydrolysislignin and organosolv extracted lignin derived from maplewood
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The kinetics and reaction chemistry for the pyrolysis of Maplewood lignin were investigated using both a pyroprobe reactor and a thermogravimetric analyser mass spectrometry (TGA-MS). Lignin residue after enzymatic hydrolysis and organosolv lignin derived from Maplewood were used to measure the kinetic behaviours of lignin pyrolysis and to analyse pyrolysis product distributions. The enzymatic lignin residue pyrolyzed at lower temperature than that of organosolv lignin. The differential thermogravimetric (DTG) peaks for pyrolysis of the enzymatic residue were more similar to the DTG peaks for pyrolysis of the original Maplewood than DTG of the organosolv lignin. The condensable liquid volatile products were collected from a Pyroprobe reactor with a liquid nitrogen trap. The primary monomeric phenolic compounds were guaiacol, syringol, and vanillic acid. However, only 14–36 carbon% of the sample could be detected by GC-MS. Over 60 carbon% of the condensable products were heavy tar molecules that are not detectable by GC-MS. These heavy tar molecules are the primary products from pyrolysis of lignin. Intermediate solid samples were also collected at various pyrolysis temperatures and characterized by elemental analysis, FT-IR, DP-MAS 13C NMR, and TOC. The methoxy groups and ether linkages decreased and the non-protonated aromatic carbon–carbon bonds increased in the solid residues as the pyrolysis temperature increased. The carbon content of the initial lignin feed (derived from enzymatic hydrolysis) and the solid polyaromatics residue (obtained at 773 K) was 58 wt% and 74 wt% respectively. This polyaromatic residue contained about 69 wt% of the original lignin feed. The solid polyaromatics undergo further slow decomposition accompanied by a constant release of carbon dioxide as the pyrolysis reaction continues. The pyrolysis of the enzymatic lignin residue was modelled by two reactions in series. In the first pyrolysis step the lignin was decomposed with an apparent activation energy of 74 kJ mol−1 and a heat of reaction of −8,780 kJ kg−1. The second pyrolysis step had an apparent activation energy of 110 kJ mol−1 and a heat of reaction of −2,819 kJ kg−1. Lignin pyrolysis has lower activation energies and higher heats of reaction than cellulose pyrolysis.
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“In this range, the degradation started easily on the aliphatic side chains attached to phenylpropane polymers, such as –OH bond, C–C bond of aliphatic groups. Small molecule gas products such as H2, H2O, CO, CO2 and C2-C4 hydrocarbons were correspondingly generated [43].”
From Evaluation of pyrolysis characteristics and product distribution of black liquor using Py-GC/MS and down tube reactor: Comparison with lignin (2021) · cites this paper as [43]
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Citations
Cites
Reaction Kinetics in Differential Thermal Analysis
Kissinger, H. E. (1957) · Analytical Chemistry · doi:10.1021/ac60131a045 · Cited by 13,216
Characteristics of hemicellulose, cellulose and lignin pyrolysis
Yang, H., Yan, R., Chen, H., Lee, D. H., & Zheng, C. (2007) · Fuel · doi:10.1016/j.fuel.2006.12.013 · Cited by 8,155
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
Huber, G. W., Iborra, S., & Corma, A. (2006) · Chemical Reviews · doi:10.1021/cr068360d · Cited by 7,810
Self-citationThe Catalytic Valorization of Lignin for the Production of Renewable Chemicals
Zakzeski, J., Bruijnincx, P. C. A., Jongerius, A. L., & Weckhuysen, B. M. (2010) · Chemical Reviews · doi:10.1021/cr900354u · Cited by 4,468
Comprehensive Handbook of Chemical Bond Energies
Luo, Y. (2007) · CRC Press eBooks · doi:10.1201/9781420007282 · Cited by 3,933
Wood-chemistry, ultrastructure, reactions
Nimz, H. (1984) · European Journal of Wood and Wood Products · doi:10.1007/bf02608943 · Cited by 2,774
The Art, Science, and Technology of Charcoal Production
Antal, M. J., & Grønli, M. (2003) · Industrial & Engineering Chemistry Research · doi:10.1021/ie0207919 · Cited by 1,623
Synergies between Bio‐ and Oil Refineries for the Production of Fuels from Biomass
Huber, G. W., & Corma, A. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200604504 · Cited by 1,420
Self-citationReview of current and future softwood kraft lignin process chemistry
Chakar, F. S., & Ragauskas, A. J. (2004) · Industrial Crops and Products · doi:10.1016/j.indcrop.2004.04.016 · Cited by 1,203
Renewable Chemical Commodity Feedstocks from Integrated Catalytic Processing of Pyrolysis Oils
Vispute, T. P., Zhang, H., Sanna, A., Xiao, R., & Huber, G. W. (2010) · Science · doi:10.1126/science.1194218 · Cited by 1,094
Self-citation
Research works printed but not linked: 7
- Kilzer, 1965, Pyrodynamics, 2, 151
- A. Broido , ed. F. Shafizadeh, K. V. Sarkanen and D. A. Tillman, Academic, New York, 1976, pp. 19–36
- Hirata, 1974, Ringyo Shikenjo Kenkyu Hokoku, 263, 1
- King, 1983, Preprint Papers - American Chemical Society, Division of Fuel Chemistry, 28, 319
- Avni, 1983, Preprint Papers - American Chemical Society, Division of Fuel Chemistry, 28, 307
- Chen, 1986, Chemtech., 16, 506
- R. M. Rowell, ed., Handbook of Wood Chemistry and Wood Composites, CRC Press, Boca Raton, 2005
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Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Self-citationChemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading
Schutyser, W., Renders, T., den Bosch, S. V., Koelewijn, S.-F., Beckham, G. T., & Sels, B. F. (2018) · Chemical Society Reviews · doi:10.1039/c7cs00566k · Cited by 2,628
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Liu, W.-J., Jiang, H., & Yu, H.-Q. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00195 · Cited by 1,754
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Azadi, P., Inderwildi, O. R., Farnood, R., & King, D. A. (2013) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2012.12.022 · Cited by 1,105
Insights into Biochar and Hydrochar Production and Applications: A Review
Zhang, Z., Zhu, Z., Shen, B., & Liu, L. (2019) · Energy · doi:10.1016/j.energy.2019.01.035 · Cited by 687
Fates of Chemical Elements in Biomass during Its Pyrolysis
Liu, W., Li, W., Jiang, H. T., & Yu, H. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00647 · Cited by 617
Biological valorization of low molecular weight lignin
Abdelaziz, O. Y., Brink, D. P., Prothmann, J., Ravi, K., Sun, M., García-Hidalgo, J., Sandahl, M., Hulteberg, C., Turner, C., Lidén, G., et al. (2016) · Biotechnology Advances · doi:10.1016/j.biotechadv.2016.10.001 · Cited by 434
Bond, J. Q., Upadhye, A. A., Olcay, H., Tompsett, G. A., Jae, J., Xing, R., Alonso, D. M., Wang, D., Zhang, T., Kumar, R., et al. (2014) · Energy & Environmental Science · doi:10.1039/c3ee43846e · Cited by 413
Self-citationRecent Advances in the Catalytic Depolymerization of Lignin towards Phenolic Chemicals: A Review
Liu, X., Bouxin, F. P., Fan, J., Budarin, V. L., Hu, C., & Clark, J. H. (2020) · ChemSusChem · doi:10.1002/cssc.202001213 · Cited by 408
Cheng, Y., & Huber, G. W. (2012) · Green Chemistry · doi:10.1039/c2gc35767d · Cited by 390
Self-citationThe pyrolysis chemistry of a β-O-4 type oligomeric lignin model compound
Chu, S., Subrahmanyam, A. V., & Huber, G. W. (2012) · Green Chemistry · doi:10.1039/c2gc36332a · Cited by 339
Self-citationA distributed activation energy model for the pyrolysis of lignocellulosic biomass
Cai, J., Wu, W., Liu, R., & Huber, G. W. (2013) · Green Chemistry · doi:10.1039/c3gc36958g · Cited by 287
Self-citationFormation of phenolic oligomers during fast pyrolysis of lignin
Bai, X., Kim, K. H., Brown, R. C., Dalluge, E. A., Hutchinson, C. P., Lee, Y., & Dalluge, D. L. (2014) · Fuel · doi:10.1016/j.fuel.2014.03.013 · Cited by 239
Qin, F., Zhang, C., Zeng, G., Huang, D., Tan, X., & Duan, A. (2022) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2021.112056 · Cited by 220
Bu, Q., Lei, H., Wang, L., Wei, Y., Zhu, L., Zhang, X., Liu, Y., Yadavalli, G., & Tang, J. (2014) · Bioresource Technology · doi:10.1016/j.biortech.2014.03.103 · Cited by 200
Zhou, H., Long, Y., Meng, A., Chen, S., Li, Q., & Zhang, Y. (2015) · RSC Advances · doi:10.1039/c5ra02715b · Cited by 173
Kinetics and reaction chemistry of pyrolysis and combustion of tobacco waste
Wu, W., Mei, Y., Zhang, L., Liu, R., & Cai, J. (2015) · Fuel · doi:10.1016/j.fuel.2015.04.016 · Cited by 167
Schutyser, W., den Bosch, S. V., Dijkmans, J., Turner, S., Meledina, M., Tendeloo, G. V., Debecker, D. P., & Sels, B. F. (2015) · ChemSusChem · doi:10.1002/cssc.201403375 · Cited by 166
Selectively transform lignin into value-added chemicals
Mei, Q., Shen, X., Liu, H., & Han, B. (2018) · Chinese Chemical Letters · doi:10.1016/j.cclet.2018.04.032 · Cited by 163
Du, S., Valla, J. A., & Bollas, G. M. (2013) · Green Chemistry · doi:10.1039/c3gc41581c · Cited by 163
CO 2 -looping in biomass pyrolysis or gasification
Shen, Y., Ma, D., & Ge, X. (2017) · Sustainable Energy & Fuels · doi:10.1039/c7se00279c · Cited by 150
Ma, Z., Wang, J., Zhou, H., Zhang, Y., Yang, Y., Liu, X., Ye, J., Chen, D., & Wang, S. (2018) · Fuel Processing Technology · doi:10.1016/j.fuproc.2018.09.020 · Cited by 121
A novel Gaussian-DAEM-reaction model for the pyrolysis of cellulose, hemicellulose and lignin
Zhang, J., Chen, T., Wu, J., & Wu, J. (2014) · RSC Advances · doi:10.1039/c4ra01445f · Cited by 111
Using Apparent Activation Energy as a Reactivity Criterion for Biomass Pyrolysis
Carrier, M., Auret, L., Bridgwater, A. V., & Knoetze, J. H. (2016) · Energy & Fuels · doi:10.1021/acs.energyfuels.6b00794 · Cited by 103
Huang, M., Xu, J., Ma, Z., Yang, Y., Zhou, B., Wu, C., Ye, J., Zhao, C., Liu, X., Chen, D., et al. (2021) · Fuel Processing Technology · doi:10.1016/j.fuproc.2021.106792 · Cited by 102
Kinetic study of regional agro-industrial wastes pyrolysis using non-isothermal TGA analysis
Fernandez, A., Saffe, A., Pereyra, R., Mazza, G., & Rodríguez, R. (2016) · Applied Thermal Engineering · doi:10.1016/j.applthermaleng.2016.06.084 · Cited by 99
Promising Techniques for Depolymerization of Lignin into Value‐added Chemicals
Ren, T., Qi, W. D., Su, R., & He, Z. (2018) · ChemCatChem · doi:10.1002/cctc.201801428 · Cited by 93
Production and Formation of Biochar
Lee, J., Sarmah, A. K., & Kwon, E. E. (2018) · Elsevier eBooks · doi:10.1016/b978-0-12-811729-3.00001-7 · Cited by 103
In situ Observation of Radicals and Molecular Products During Lignin Pyrolysis
Bährle, C., Custodis, V. B. F., Jeschke, G., van Bokhoven, J. A., & Vogel, F. (2014) · ChemSusChem · doi:10.1002/cssc.201400079 · Cited by 90
Bianasari, A. A., Khaled, M. S., Hoang, T., Reza, M. S., Bakar, M. S. A., & Азад, А. К. (2024) · Energy Conversion and Management · doi:10.1016/j.enconman.2024.118437 · Cited by 90
Sousa, L. D. C., Foston, M. B., Bokade, V. V., Azarpira, A., Lu, F., Ragauskas, A. J., Ralph, J., Dale, B. E., & Balan, V. (2016) · Green Chemistry · doi:10.1039/c6gc00298f · Cited by 84
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Jin, T., Wang, H., Peng, J., Wu, Y., Huang, Z., Tian, X., & Ding, M. (2022) · Fuel Processing Technology · doi:10.1016/j.fuproc.2022.107201 · Cited by 71
Evolved Gas Analysis by Mass Spectrometry
Materazzi, S., & Ciprioti, S. V. (2011) · Applied Spectroscopy Reviews · doi:10.1080/05704928.2011.565533 · Cited by 71
Huo, Y., Guo, Z., Liu, Y., Wu, D., Ding, X., Zhao, Z., Wu, M., Wang, L., Feng, Y., Chen, Y., et al. (2021) · Journal of Geophysical Research Atmospheres · doi:10.1029/2021jd035835 · Cited by 69
Guo, Z., Li, D., You, T., Zhang, X., Xu, F., Zhang, X., & Yang, Y. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c03491 · Cited by 68
Kinetic Modelling of Hydrothermal Lignin Depolymerisation
Forchheim, D., Hornung, U., Kruse, A., & Sutter, T. (2014) · Waste and Biomass Valorization · doi:10.1007/s12649-014-9307-6 · Cited by 67
High Resolution Solid State 2D NMR Analysis of Biomass and Biochar
Brech, Y. L., Delmotte, L., Raya, J., Brosse, N., Gadiou, R., & Dufour, A. (2014) · Analytical Chemistry · doi:10.1021/ac504237c · Cited by 67
Maduskar, S., Facas, G. G., Papageorgiou, C. S., Williams, C. L., & Dauenhauer, P. J. (2017) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.7b03785 · Cited by 66
Self-citationLu, Q., Yuan, S., Liu, C., Zhang, T., Xie, X., Deng, X., & He, R. (2020) · Fuel · doi:10.1016/j.fuel.2020.118500 · Cited by 65
Zhang, H., Zheng, J., Xiao, R., Shen, D., Jin, B., Xiao, G., & Chen, R. (2013) · RSC Advances · doi:10.1039/c3ra40694f · Cited by 66
Forchheim, D., Gasson, J. R., Hornung, U., Kruse, A., & Barth, T. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie3026407 · Cited by 66
Yang, H.-M., Appari, S., Kudo, S., Hayashi, J., & Norinaga, K. (2015) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.5b01289 · Cited by 63
Fan, H., Yang, Y., Song, J., Ding, G., Wu, C., Yang, G., & Han, B. (2013) · Green Chemistry · doi:10.1039/c3gc41363b · Cited by 59
Shen, X., Bertón, P., Shamshina, J. L., & Rogers, R. D. (2016) · Green Chemistry · doi:10.1039/c6gc01339b · Cited by 59
Nan, H., Mašek, O., Yang, F., Xu, X., Qiu, H., Cao, X., & Zhao, L. (2022) · Earth-Science Reviews · doi:10.1016/j.earscirev.2022.104215 · Cited by 59
Naron, D. R., Collard, F., Tyhoda, L., & Görgens, J. F. (2018) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2018.12.015 · Cited by 56
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Evolved Gas Analysis by Mass Spectrometry
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Interactions among biomass components during co-pyrolysis in (macro)thermogravimetric analyzers
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Kim, H., Lee, J.-H., Kim, Y., Ha, J., Park, Y., Vlachos, D. G., Suh, Y., & Jae, J. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.148328 · Cited by 42
Xing, Y., Bu, L., Zheng, T., Liu, S., & Jiang, J. (2016) · Bioresource Technology · doi:10.1016/j.biortech.2016.09.086 · Cited by 42
Chen, C., Zheng, N., Wu, W., Tang, M., Feng, W., Zhang, W., Li, X., Jiang, Y. P., Pang, J., Min, D., et al. (2022) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.2c12914 · Cited by 40
Yu, H., Liu, F., Ke, M., & Zhang, X. (2015) · Bioresource Technology · doi:10.1016/j.biortech.2015.03.005 · Cited by 38
Singh, J., & Verma, M. (2023) · Environmental Research · doi:10.1016/j.envres.2023.117999 · Cited by 40
Yuan, Z., Tymchyshyn, M., & Xu, C. C. (2016) · ChemCatChem · doi:10.1002/cctc.201600187 · Cited by 38
Zhao, Y., Zhang, H., Zong, P., Zhou, H., & Tian, Y. (2021) · Fuel · doi:10.1016/j.fuel.2021.120286 · Cited by 36
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Combustion characteristics of typical model components in solid waste on a macro-TGA
Luo, J., Li, Q., Meng, A., Long, Y., & Zhang, Y. (2017) · Journal of Thermal Analysis and Calorimetry · doi:10.1007/s10973-017-6909-9 · Cited by 34
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Extraction and Comparative Analysis of Lignin Extract from Alkali and Ionic Liquid Pretreatment
Rahim, A. H. A., Man, Z. B., Sarwono, A., Hamzah, W. S. W., Yunus, N. M., & Wilfred, C. D. (2018) · Journal of Physics Conference Series · doi:10.1088/1742-6596/1123/1/012052 · Cited by 32
Liu, Q., Bai, Y., Chen, H., Chen, M., Sang, Y., Wu, K., Ma, Z., Ma, Y., & Li, Y. (2020) · Bioresource Technology · doi:10.1016/j.biortech.2020.124634 · Cited by 32
Structural changes of chars produced from fast pyrolysis of lignin at 100–300 °C
Chua, Y. W., Yu, Y., & Wu, H. (2019) · Fuel · doi:10.1016/j.fuel.2019.115754 · Cited by 31
Nde, D. B., Muley, P. D., Sabliov, C. M., Nokes, S. E., & Boldor, D. (2021) · Energy Conversion and Management · doi:10.1016/j.enconman.2020.113754 · Cited by 31
Lignin Depolymerization with Alkaline Ionic Liquids and Ethylene Glycol in a Continuous Flow Reactor
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Javaid, S. F., Dai, M., Wu, Y., Luo, H., Amjed, M. A., Ali, I., Peng, C., & Naz, I. (2024) · Arabian Journal for Science and Engineering · doi:10.1007/s13369-023-08549-3 · Cited by 29
Valorisation of woody biomass by combining enzymatic saccharification and pyrolysis
Kalyani, D. C., Fakin, T., Horn, S. J., & Tschentscher, R. (2017) · Green Chemistry · doi:10.1039/c7gc00936d · Cited by 27
Lee, T., Nam, I.-H., Kim, J.-H., Zhang, M., Jeong, T. Y., Baek, K., & Kwon, E. E. (2018) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2018.10.017 · Cited by 24
The Efficient and Sustainable Pyrolysis and Gasification of Biomass by Catalytic Processes
Tong, X., Chen, H., Hu, J., Bi, Y., Sun, Z., & Fan, W. (2015) · ChemBioEng Reviews · doi:10.1002/cben.201400028 · Cited by 24
Williams, C. L., Emerson, R., Hernandez, S., Klinger, J. L., Fillerup, E. P., & Thomas, B. J. (2018) · Frontiers in Energy Research · doi:10.3389/fenrg.2018.00074 · Cited by 23
Chen, H., Xu, G., Xiao, C., Bi, Y., & Hu, J. (2019) · Energy & Fuels · doi:10.1021/acs.energyfuels.9b01486 · Cited by 22
Mankar, A. R., Ahmạd, E., & Pant, K. K. (2021) · Materials Science for Energy Technologies · doi:10.1016/j.mset.2021.08.006 · Cited by 20
Thermal degradation of extractive-based bio-epoxy monomer and network: Kinetics and mechanism
Kuo, P., Barros, L. D. A., Sheen, Y., Sain, M. M., Tjong, J., & Yan, N. (2015) · Journal of Analytical and Applied Pyrolysis · doi:10.1016/j.jaap.2015.11.014 · Cited by 20
Kaneko, H., Ishii, R., Suzuki, A., Nakamura, T., Ebina, T., Nge, T. T., & Yamada, T. (2016) · Applied Clay Science · doi:10.1016/j.clay.2016.07.009 · Cited by 19
Oladzadabbasabadi, N., Dheyab, M. A., Tavassoli, M., Naebe, M., Jafarzadeh, S., Ghasemlou, M., Ivanova, E. P., & Adhikari, B. (2025) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2025.145029 · Cited by 19
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Tao, Y., Li, S., Li, P., & Wu, Q. (2016) · Holzforschung · doi:10.1515/hf-2016-0022 · Cited by 18
Puss, K. K., Loog, M., & Salmar, S. (2023) · Ultrasonics Sonochemistry · doi:10.1016/j.ultsonch.2022.106288 · Cited by 19
Feng, Q., Xu, L., Liu, C., Hao, Y., Yang, Z., Zhang, T., Liu, Y., & Su, H. (2021) · Sustainable Energy & Fuels · doi:10.1039/d1se01470f · Cited by 17
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Metadata
- Authors
- Cho, J., Chu, S., Dauenhauer, P. J., & Huber, G. W.
- Affiliations
- University of Massachusetts Amherst (US)
- Corresponding author
- Huber, George W.
- Venue
- Green Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 14
- Issue
- 2
- Pages
- 428-439
- ISSN
- 1463-9262 (ISSN-L)
- 1463-9270
- OpenAlex
- W2065713566
- Cited by
- 130
- References
- 71
- Citations by year
- 2026: 3 · 2025: 9 · 2024: 3 · 2023: 9 · 2022: 10 · 2021: 14 · 2020: 4 · 2019: 8 · 2018: 12 · 2017: 8 · 2016: 14 · 2015: 14 · 2014: 12 · 2013: 6 · 2012: 3
- FWCI
- 4.17
- Type
- journal article
- Language
- en
- Open access
- green
- works.bepress.com
- Locations
- Green Chemistry (publishedVersion)
- ScholarWorks@UMassAmherst (University of Massachusetts Amherst) (submittedVersion)
- Funders
- National Science Foundation (0937895)
- U.S. Department of Defense
- Royal Society
- Royal Society of Chemistry
- Defense Advanced Research Projects Agency (W911NF-09-2-0010)
- Advanced Research Projects Agency
- Division of Emerging Frontiers in Research and Innovation (0937895, EFRI-0937895)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Lignin and Wood Chemistry
- Physical Sciences › Energy › Fuel Technology › Thermochemical Biomass Conversion Processes
- Physical Sciences › Materials Science › Materials Chemistry › Thermal and Kinetic Analysis
- Keywords
- lignin pyrolysis, enzymatic hydrolysis lignin, organosolv lignin, pyrolysis kinetics, reaction mechanism, tar formation, guaiacol, syringol, vanillic acid, activation energy, two-step reaction model, pyrolysis product distribution, lignin degradation, carbon dioxide release
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