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Boron–nitrogen–hydrogen (BNH) compounds: recent developments in hydrogen storage, applications in hydrogenation and catalysis, and new syntheses
Abstract
The strong efforts devoted to the exploration of BNH compounds for hydrogen storage have led to impressive advances in the field of boron chemistry. This review summarizes progress in this field from three aspects. It starts with the most recent developments in using BNH compounds for hydrogen storage, covering NH3BH3, B3H8− containing compounds, and CBN compounds. The following section then highlights interesting applications of BNH compounds in hydrogenation and catalysis. The last part is focused on breakthroughs in the syntheses and discovery of new BNH organic analogues. The role of N–Hδ+⋯Hδ−–B dihydrogen interactions in molecule packing, thermal hydrogen evolution, and syntheses is also discussed within the review.
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Metadata
- Authors
- Huang, Z., & Autrey, T.
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 5
- Issue
- 11
- Pages
- 9257
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W2051381279
- Cited by
- 268
- References
- 89
- FWCI
- 8.98
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.