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Water-induced shape memory effect of graphene oxide reinforced polyvinyl alcohol nanocomposites
Abstract
A novel water-induced shape memory polymer based on polyvinyl alcohol (PVA) was prepared by introducing graphene oxide (GO). Due to the strong hydrogen bonding interaction between PVA and GO, some additional physically cross-linked points could be formed in PVA, which largely improved shape memory properties of PVA. Solvent-induced shape memory behavior was observed by immersing PVA/GO nanocomposites in water. The water-induced shape recovery was due to the decrease of glass transition temperature and storage modulus. This could be explained by the swelling plasticizing effect of water on PVA, as indicated by the obvious expansion in volume of PVA. On the other hand, the weakened hydrogen bonding between PVA and GO was also observed after immersing the PVA/GO nanocomposites in water. Thus both the plasticizing effect and the competitive hydrogen bonding were the two main reasons for the shape recovery of PVA/GO nanocomposites. This study provides a framework for developing new shape memory polymers (SMPs) and for better understanding the shape recovery mechanism in solvent-induced SMPs.
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“Graphene can be incorporated by direct mixing with the polymer matrix for the production of PVA water-induced SMP [134]”
From Shape-memory polymers for multiple applications in the materials world (2016) · cites this paper as [134]
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Cites
Preparation of Graphitic Oxide
Hummers, W. S., & Offeman, R. E. (1958) · Journal of the American Chemical Society · doi:10.1021/ja01539a017 · Cited by 30,194
Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
Stankovich, S., Dikin, D. A., Piner, R. D., Kohlhaas, K. M., Kleinhammes, A., Jia, Y., Wu, Y., Nguyen, S. T., & Ruoff, R. S. (2007) · Carbon · doi:10.1016/j.carbon.2007.02.034 · Cited by 13,979
Lendlein, A., Kelch, S., Kratz, K., Schulte, J., & Schauer, S. (2002) · Elsevier eBooks · doi:10.1002/0471238961.1908011612051404.a01 · Cited by 2,687
Light-induced shape-memory polymers
Lendlein, A., Jiang, H., Jünger, O., & Langer, R. (2005) · Nature · doi:10.1038/nature03496 · Cited by 2,006
Review of progress in shape-memory polymers
Liu, C., Qin, H., & Mather, P. T. (2007) · Journal of Materials Chemistry · doi:10.1039/b615954k · Cited by 1,942
Liang, J., Huang, Y., Zhang, L., Wang, Y., Ma, Y., Guo, T., & Chen, Y. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200801776 · Cited by 1,623
Hu, J., Zhu, Y., Huang, H., & Lu, J. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.001 · Cited by 1,279
Stimulus-responsive shape memory materials: a review
Sun, L., Huang, W. M., Ding, Z., Zhao, Y., Wang, C. C., Purnawali, H., & Tang, C. (2012) · Materials & Design · doi:10.1016/j.matdes.2011.04.065 · Cited by 1,105
Mather, P. T., Luo, X., & Rousseau, I. A. (2009) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-082908-145419 · Cited by 911
A pH-sensitive graphene oxide composite hydrogel
Bai, H., Li, C., Wang, X., & Shi, G. (2010) · Chemical Communications · doi:10.1039/c000051e · Cited by 669
Water-driven programmable polyurethane shape memory polymer: Demonstration and mechanism
Huang, W. M., Yang, B., An, L., Li, C., & Chan, Y. S. (2005) · Applied Physics Letters · doi:10.1063/1.1880448 · Cited by 616
A review of shape memory polymer composites and blends
Meng, Q., & Hu, J. (2009) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2009.08.011 · Cited by 609
Review of electro-active shape-memory polymer composite
Liu, Y., Lv, H., Lan, X., Leng, J., & Du, S. (2009) · Composites Science and Technology · doi:10.1016/j.compscitech.2008.08.016 · Cited by 548
Facile tailoring of thermal transition temperatures of epoxy shape memory polymers
Xie, T., & Rousseau, I. A. (2009) · Polymer · doi:10.1016/j.polymer.2009.02.035 · Cited by 535
Effects of moisture on the thermomechanical properties of a polyurethane shape memory polymer
Yang, B., Huang, W. M., Li, C., & Li, L. (2006) · Polymer · doi:10.1016/j.polymer.2005.12.051 · Cited by 477
Bao, C., Guo, Y., Song, L., & Hu, Y. Z. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm11662b · Cited by 401
Thermo-moisture responsive polyurethane shape-memory polymer and composites: a review
Huang, W. M., Yang, B., Zhao, Y., & Ding, Z. (2010) · Journal of Materials Chemistry · doi:10.1039/b922943d · Cited by 382
Synthesis and characterization of layer-aligned poly(vinyl alcohol)/graphene nanocomposites
Yang, X., Li, L., Shang, S., & Tao, X. (2010) · Polymer · doi:10.1016/j.polymer.2010.05.034 · Cited by 376
High barrier graphene oxide nanosheet/poly(vinyl alcohol) nanocomposite films
Huang, H., Ren, P., Chen, J., Zhang, W., Ji, X., & Li, Z. (2012) · Journal of Membrane Science · doi:10.1016/j.memsci.2012.03.051 · Cited by 321
Bioinspired mechanically adaptive polymer nanocomposites with water-activated shape-memory effect
Mendez, J., Annamalai, P. K., Eichhorn, S. J., Rusli, R., Rowan, S. J., Foster, E. J., & Weder, C. (2011) · Macromolecules · doi:10.1021/ma201502k · Cited by 319
Huang, W., Zhao, Y., Wang, C. C., Ding, Z., Purnawali, H., Tang, C., & Zhang, J. (2012) · Journal of Polymer Research · doi:10.1007/s10965-012-9952-z · Cited by 302
Wang, J., Wang, X., Xu, C., Zhang, M., & Shang, X. (2011) · Polymer International · doi:10.1002/pi.3025 · Cited by 299
Shape‐Memory Effects in Polymer Networks Containing Reversibly Associating Side‐Groups
Li, J., Viveros, J., Wrue, M. H., & Anthamatten, M. (2007) · Advanced Materials · doi:10.1002/adma.200602260 · Cited by 283
Du, H., & Zhang, J. (2010) · Soft Matter · doi:10.1039/b922220k · Cited by 261
Rapidly switchable water-sensitive shape-memory cellulose/elastomer nano-composites
Zhu, Y., Hu, J., Luo, H., Young, R. J., Deng, L., Zhang, S., Fan, Y., & Ye, G. (2012) · Soft Matter · doi:10.1039/c2sm07035a · Cited by 208
Dependency of the shape memory properties of a polyurethane upon thermomechanical cyclic conditions
Hu, J. L., Ji, F. L., & Wong, Y. W. (2004) · Polymer International · doi:10.1002/pi.1745 · Cited by 164
Ye, S., Feng, J., & Wu, P. (2013) · Journal of Materials Chemistry A · doi:10.1039/c2ta01142e · Cited by 163
Reduction of graphene oxide with substituted borohydrides
Chua, C. K., & Pumera, M. (2012) · Journal of Materials Chemistry A · doi:10.1039/c2ta00665k · Cited by 158
Lu, H., Liu, Y., Leng, J., & Du, S. (2010) · European Polymer Journal · doi:10.1016/j.eurpolymj.2010.06.013 · Cited by 120
Shape Memory of Hydrogen-Bonded Polymer Network/Poly(ethylene glycol) Complexes
Liu, G., Ding, X., Cao, Y., Zheng, Z., & Peng, Y. (2004) · Macromolecules · doi:10.1021/ma035717w · Cited by 119
Zhou, T., Chen, F., Tang, C., Bai, H., Zhang, Q., Deng, H., & Fu, Q. (2011) · Composites Science and Technology · doi:10.1016/j.compscitech.2011.04.016 · Cited by 118
Self-citationSize-specified graphene oxide sheets: ultrasonication assisted preparation and characterization
Qi, X., Zhou, T., Deng, S., Zong, G., Yao, X., & Fu, Q. (2013) · Journal of Materials Science · doi:10.1007/s10853-013-7866-8 · Cited by 113
Self-citationThermo-mechanical properties of polystyrene-based shape memory nanocomposites
Xu, B., Fu, Y. Q., Ahmad, M., Luo, J. K., Huang, W. M., Kraft, A., Reuben, R., Pei, Y. T., Chen, Z. G., & De Hosson, J. T. M. (2010) · Journal of Materials Chemistry · doi:10.1039/b923238a · Cited by 96
Thermo-/chemo-responsive shape memory/change effect in a hydrogel and its composites
Zhang, J. L., Huang, W., Lu, H., & Sun, L. (2013) · Materials & Design (1980-2015) · doi:10.1016/j.matdes.2013.08.016 · Cited by 86
Clustering of solvents in membranes and its influence on membrane transport properties
Nguyen, Q. T., Favre, É., Ping, Z., & Néel, J. (1996) · Journal of Membrane Science · doi:10.1016/0376-7388(95)00219-7 · Cited by 83
Shape memorizing properties of a hydrogel of poly(vinyl alcohol)
Hirai, T., Maruyama, H., Suzuki, T., & Hayashi, S. (1992) · Journal of Applied Polymer Science · doi:10.1002/app.1992.070451019 · Cited by 82
Yang, B., Huang, W., Li, C., Li, L., & Chor, J. H. (2005) · Scripta Materialia · doi:10.1016/j.scriptamat.2005.03.009 · Cited by 81
Zhou, T., Qi, X., & Fu, Q. (2013) · eXPRESS Polymer Letters · doi:10.3144/expresspolymlett.2013.72 · Cited by 79
Self-citationHydrogen-bonded polymer network—poly(ethylene glycol) complexes with shape memory effect
Cao, Y., Guan, Y., Du, J., Luo, J., Peng, Y., Yip, C. W., & Chan, A. S. C. (2002) · Journal of Materials Chemistry · doi:10.1039/b207024n · Cited by 60
Qi, G.-Q., Cao, J., Bao, R., Liu, Z., Yang, W. M., Xie, B., & Yang, M. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta01360j · Cited by 57
Effect of chemical cross‐linking under elongation on shape restoring of poly(vinyl alcohol) hydrogel
Hirai, T., Maruyama, H., Suzuki, T., & Hayashi, S. (1992) · Journal of Applied Polymer Science · doi:10.1002/app.1992.070460815 · Cited by 55
Du, H., & Zhang, J. (2009) · Colloid & Polymer Science · doi:10.1007/s00396-009-2117-x · Cited by 49
Evidence for oxygen reduction reaction activity of a Ni(OH)2/graphene oxide catalyst
Farjami, E., Rottmayer, M. A., & Deiner, L. J. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta13351f · Cited by 45
Block copolymer of trans‐polyisoprene and urethane segment: Crystallization behavior and morphology
Sun, X., & Ni, X. (2004) · Journal of Applied Polymer Science · doi:10.1002/app.21016 · Cited by 29
Du, F., Ye, E., Tang, C. Y., Ng, S., Zhou, X., & Xie, X. (2012) · Journal of Applied Polymer Science · doi:10.1002/app.38807 · Cited by 29
Research works printed but not linked: 2
- Lendlein, 2002, Angew. Chem., Int. Ed., 41, 2034, 10.1002/1521-3773(20020617)41:12<2034::AID-ANIE2034>3.0.CO;2-M · DOI
- M. Morton , Weinheim, Wiley-VCH, 1987, p. 37
Cited by
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Cai, G., Wang, J., Qian, K., Chen, J., Li, S., & Lee, P. S. (2017) · Advanced Science · doi:10.1002/advs.201600190 · Cited by 921
Dai, H., Huang, Y., & Huang, H. (2017) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2017.12.073 · Cited by 517
Shape-memory polymers for multiple applications in the materials world
Pilate, F., Toncheva, A., Dubois, P., & Raquez, J.-M. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.05.004 · Cited by 332
Shape memory polymers for composites
Mu, T., Liu, L., Lan, X., Liu, Y., & Leng, J. (2018) · Composites Science and Technology · doi:10.1016/j.compscitech.2018.03.018 · Cited by 308
Metadata
- Authors
- Qi, X., Yao, X., Deng, S., Zhou, T., & Fu, Q.
- Affiliations
- Sichuan University (CN)
- Corresponding author
- Fu, Qiang
- Venue
- J. Mater. Chem. A
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2014
- Volume
- 2
- Issue
- 7
- Pages
- 2240-2249
- ISSN
- 2050-7488 (ISSN-L)
- 2050-7496
- OpenAlex
- W2107642160
- Cited by
- 293
- References
- 47
- Citations by year
- 2026: 6 · 2025: 12 · 2024: 13 · 2023: 11 · 2022: 23 · 2021: 33 · 2020: 26 · 2019: 36 · 2018: 31 · 2017: 36 · 2016: 38 · 2015: 19 · 2014: 8
- FWCI
- 15.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry A (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Engineering › Mechanical Engineering › Advanced Materials and Mechanics
- Physical Sciences › Materials Science › Biomaterials › Hydrogels: synthesis, properties, applications
- Keywords
- shape memory polymers, polyvinyl alcohol, graphene oxide, polymer nanocomposites, hydrogen bonding, physical crosslinking, water swelling, plasticization, glass transition temperature, storage modulus
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