The emergence of sulfoxides as efficient ligands in transition metal catalysis

Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis

Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824

Recent Developments in the Synthesis and Utilization of Chiral Sulfoxides

Fernández, I., & Khiar, N. (2003) · Chemical Reviews · doi:10.1021/cr990372u · Cited by 1,187

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

Gunanathan, C., & Milstein, D. (2011) · Accounts of Chemical Research · doi:10.1021/ar2000265 · Cited by 1,078

Chiral Bis(oxazoline) Copper(II) Complexes: Versatile Catalysts for Enantioselective Cycloaddition, Aldol, Michael, and Carbonyl Ene Reactions

Johnson, J. S., & Evans, D. A. (2000) · Accounts of Chemical Research · doi:10.1021/ar960062n · Cited by 1,046

Phosphorus ligand exchange equilibriums on zerovalent nickel. Dominant role for steric effects

Tolman, C. A. (1970) · Journal of the American Chemical Society · doi:10.1021/ja00713a007 · Cited by 754

Phosphoramidites: Marvellous Ligands in Catalytic Asymmetric Conjugate Addition

Feringa, B. L. (2000) · Accounts of Chemical Research · doi:10.1021/ar990084k · Cited by 703

An efficient asymmetric oxidation of sulfides to sulfoxides

Pitchen, P., Dunach, E., Deshmukh, M. N., & Kagan, H. B. (1984) · Journal of the American Chemical Society · doi:10.1021/ja00338a030 · Cited by 618

Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols

Izawa, Y., Pun, D., & Stahl, S. S. (2011) · Science · doi:10.1126/science.1204183 · Cited by 464

Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones

Diao, T., & Stahl, S. S. (2011) · Journal of the American Chemical Society · doi:10.1021/ja206575j · Cited by 402

Structure and bonding in metal sulfoxide complexes

Calligaris, M. (1996) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(95)01193-5 · Cited by 329

Mechanistic Study of Alcohol Oxidation by the Pd(OAc)2/O2/DMSO Catalyst System and Implications for the Development of Improved Aerobic Oxidation Catalysts

Steinhoff, B. A., Fix, S. R., & Stahl, S. S. (2002) · Journal of the American Chemical Society · doi:10.1021/ja016806w · Cited by 328

Palladium-Catalyzed Synthesis of 2-Substituted Benzothiazoles via a C−H Functionalization/Intramolecular C−S Bond Formation Process

Inamoto, K., Hasegawa, C., Hiroya, K., & Doi, T. (2008) · Organic Letters · doi:10.1021/ol802033p · Cited by 290

Comparing the Enantioselective Power of Steric and Electrostatic Effects in Transition‐Metal‐Catalyzed Asymmetric Synthesis

Poater, A., Ragone, F., Mariz, R., Dorta, R., & Cavallo, L. (2010) · Chemistry – A European Journal · doi:10.1002/chem.201001938 · Cited by 255

Total synthesis and study of 6-deoxyerythronolide B by late-stage C–H oxidation

Stang, E. M., & White, M. C. (2009) · Nature Chemistry · doi:10.1038/nchem.351 · Cited by 241

Chiral sulfur-containing ligands for asymmetric catalysis

Pellissier, H. (2007) · Tetrahedron · doi:10.1016/j.tet.2006.09.068 · Cited by 226

Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)2(TFA)2: Evidence for Ligand-Controlled Chemoselectivity

Diao, T., Pun, D., & Stahl, S. S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4031648 · Cited by 182

Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta‐Substituted Phenols

Izawa, Y., Zheng, C., & Stahl, S. S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209457 · Cited by 149

Catalyst-Controlled C–O versus C–N Allylic Functionalization of Terminal Olefins

Strambeanu, I. I., & White, M. C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja405394v · Cited by 118

N -Boc Amines to Oxazolidinones via Pd(II)/Bis-sulfoxide/Brønsted Acid Co-Catalyzed Allylic C–H Oxidation

Osberger, T. J., & White, M. C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja506036q · Cited by 101

A method to measure the size of phosphorus ligands in coordination complexes

Immirzi, A., & Musco, A. (1977) · Inorganica Chimica Acta · doi:10.1016/s0020-1693(00)95635-4 · Cited by 99

Sequential Allylic C–H Amination/Vinylic C–H Arylation: A Strategy for Unnatural Amino Acid Synthesis from α-Olefins

Jiang, C., Covell, D. J., Stepan, A. F., Plummer, M. S., & White, M. C. (2012) · Organic Letters · doi:10.1021/ol300063t · Cited by 79

Catalytic activity of chiral β-hydroxysulfoxides in the enantioselective addition of diethylzinc to benzaldehyde.

Carreño, M. C., Ruano, J. L. G., Carreño, M. C., & Cabrejas, L. M. M. (1993) · Tetrahedron Asymmetry · doi:10.1016/s0957-4166(00)80181-0 · Cited by 46

Preparation of new ruthenium–allenylidene catalysts and their use in polymerisation of cyclic olefins

Abdallaoui, I. A., Sémeril, D., & Dixneuf, P. H. (2002) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(01)00498-8 · Cited by 38

Carboxybenzyl Group as an O-Nucleophile in the C–H Allylic Oxidation: Total Synthesis of (−)-Castanospermine

Malik, M., Witkowski, G., & Jarosz, S. (2014) · Organic Letters · doi:10.1021/ol501730p · Cited by 28

Steric properties of sulfoxide ligands. Synthesis and crystal structure of mer-[RuCl3(Ph2So)3]

Calligaris, M., Faleschini, P., Todone, F., et al. (1995) · Journal of the Chemical Society Dalton Transactions · doi:10.1039/dt9950001653 · Cited by 13

Artificial Metalloenzymes: Reaction Scope and Optimization Strategies

Schwizer, F., Okamoto, Y., Heinisch, T., Gu, Y., Pellizzoni, M. M., Lebrun, V., Reuter, R., Köhler, V., Lewis, J. C., & Ward, T. R. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00014 · Cited by 831