Hydrodeoxygenation of microalgae oil to green diesel over Pt, Rh and presulfided NiMo catalysts
Abstract
The catalytic characteristics, activity and selectivity of 1% Pt/Al 2 O 3 , 0.5% Rh/Al 2 O 3 and presulfided NiMo/Al 2 O 3 catalysts have been investigated in the hydrodeoxygenation of microalgae ( Nannochloropsis salina ) oil to produce green diesel in a microreactor.
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Lawal and coworkers explored deoxygenation of algae oils from Nannochloropsis salina and Chlorella vulgaris over platinum, rhodium and nickel-molybdenum-based catalysts.
“Lawal and coworkers explored deoxygenation of algae oils from Nannochloropsis salina and Chlorella vulgaris over platinum, rhodium and nickel-molybdenum-based catalysts (83, 87, 88).”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [88]
Most reaction conditions explored by Lawal and coworkers showed significant catalyst deactivation within 7 h time on stream.
“While most reaction conditions explored showed significant catalyst deactivation within 7 h time on stream (TOS), Zhou and Lawal were able to find a set of conditions for both a NiMo/Al 2O3 and a Pt/Al2O3 catalyst that did not show significant deactivation within this timeframe, and obtained hydrocarbon yields above 60 wt% (87, 88).”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [88]
Zhou and Lawal found conditions for both NiMo/Al2O3 and Pt/Al2O3 catalysts that did not show significant deactivation within 7 h time on stream.
“While most reaction conditions explored showed significant catalyst deactivation within 7 h time on stream (TOS), Zhou and Lawal were able to find a set of conditions for both a NiMo/Al 2O3 and a Pt/Al2O3 catalyst that did not show significant deactivation within this timeframe, and obtained hydrocarbon yields above 60 wt% (87, 88).”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [88]
The optimal conditions for the platinum and nickel-molybdenum catalysts were significantly different.
“The optimal conditions for the platinum and nickelmolybdenum catalyst were significantly different, underscoring the need for reaction engineering studies for”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [88]
Zhou and Lawal obtained hydrocarbon yields above 60 wt% under those conditions.
“While most reaction conditions explored showed significant catalyst deactivation within 7 h time on stream (TOS), Zhou and Lawal were able to find a set of conditions for both a NiMo/Al 2O3 and a Pt/Al2O3 catalyst that did not show significant deactivation within this timeframe, and obtained hydrocarbon yields above 60 wt% (87, 88).”
From Catalytic Hydroprocessing of Single-Cell Oils to Hydrocarbon Fuels: Converting microbial lipids to fuels is a promising approach to replace fossil fuels (2021) · cites this paper as [88]
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- Authors
- Zhou, L., & Lawal, A.
- Affiliations
- Stevens Institute of Technology (US)
- Corresponding author
- Zhou, Lin
- ORCID
- Zhou, Lin
- Venue
- Catalysis Science & Technology
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2016
- Volume
- 6
- Issue
- 5
- Pages
- 1442-1454
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2155511853
- Cited by
- 81
- References
- 38
- Citations by year
- 2026: 6 · 2025: 4 · 2024: 6 · 2023: 8 · 2022: 10 · 2021: 9 · 2020: 5 · 2019: 8 · 2018: 7 · 2017: 13 · 2016: 5
- FWCI
- 8.18
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Science & Technology (publishedVersion)
- Funders
- Bioenergy Technologies Office
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Catalysis and Hydrodesulfurization Studies
- Physical Sciences › Engineering › Biomedical Engineering › Biodiesel Production and Applications
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- hydrodeoxygenation, microalgae oil, Nannochloropsis salina, renewable diesel, biofuels, Pt/Al2O3 catalyst, Rh/Al2O3 catalyst, microreactors, catalyst activity and selectivity
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