Efficient direct seawater electrolysers using selective alkaline NiFe-LDH as OER catalyst in asymmetric electrolyte feeds
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Increasing the performance of seawater electrolyser and enabling direct natural seawater feed by asymmetric electrolyte flow scheme.
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Under alkaline conditions, chlorine is converted into hypochlorite with an onset potential of around 490 mV, which is higher than that of the OER.
“Under alkaline conditions, chlorine is converted into hypo chlorite, with an onset potential of around 490 mV, which is higher than that of the OER.”
From Wood aerogel-derived sandwich-like layered nanoelectrodes for alkaline overall seawater electrosplitting (2021) · cites this paper as [14]
The introductory passage gives a standard potential of 1.71 V vs RHE for hypochlorite formation at high pH, about 480 mV above the OER value of 1.23 V. It describes chloride, not chlorine, being oxidized to hypochlorite. The Seawater electrolysis selectivity section instead identifies an observed hypochlorite onset at about 2.4 V cell, so 490 mV is not the onset potential reported by this paper. (LLM, conf=0.86)
Experimental — accuracy not yet measuredThe main issue for seawater splitting is competition between the oxygen evolution reaction (OER) and the chlorine evolution reaction (CER) at the anode.
“The main issue for seawater splitting technique lies in the competion between the OER and the chlorine evolution reaction (CER) at the anode [13,14].”
From Wood aerogel-derived sandwich-like layered nanoelectrodes for alkaline overall seawater electrosplitting (2021) · cites this paper as [14]
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- Authors
- Dresp, S., Ngo Thanh, T., Klingenhof, M., Brückner, S., Hauke, P., & Strasser, P.
- Affiliations
- Technische Universität Berlin (DE)
- Department of Chemistry
- Corresponding author
- Strasser, Peter
- Venue
- Energy & Environmental Science
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2020
- Volume
- 13
- Issue
- 6
- Pages
- 1725-1729
- ISSN
- 1754-5692 (ISSN-L)
- 1754-5706
- OpenAlex
- W3026430433
- Cited by
- 459
- References
- 15
- Citations by year
- 2026: 71 · 2025: 94 · 2024: 98 · 2023: 86 · 2022: 60 · 2021: 43 · 2020: 7
- FWCI
- 9.69
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Locations
- Energy & Environmental Science (publishedVersion, cc-by)
- Funders
- Bundesministerium für Wirtschaft und Energie (03EIV041F)
- Deutsche Forschungsgemeinschaft (STR 596/12-1)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- seawater electrolysis, oxygen evolution reaction, NiFe layered double hydroxide, alkaline electrocatalysts, water splitting
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