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Molecular beam epitaxy growth of epitaxial barium silicide, barium oxide, and barium titanate on silicon

McKee, R. A., Walker, F. J., Conner, J. R., Specht, E. D., Zelmon, D. E.·1991·Applied Physics Letters

Abstract

Thin-film epitaxial structures of BaSi2, BaO, and BaTiO3, have been grown on the (001) face of silicon using ultrahigh vacuum, molecular beam epitaxy (MBE) methods. Source shuttering for the metal species coordinated with a pulsed, or cyclic, oxygen arrival at the growing oxide surfaces significantly improves film quality. The epitaxial growth of BaO is accomplished without silica formation at the BaO/Si interface by stabilizing BaSi2 as a submonolayer template structure. In situ ellipsometric measurements of the indices of refraction for BaO and for BaTiO3 in a BaTiO3/BaO/Si multilayer gave n=1.96 for BaO and n=2.2 for the BaTiO3, within 10% of their bulk values. These values suggest that this structure can be developed as an optical waveguide. BaO is impermeable to silicon for films as thin as 10 nm at temperatures as high as 800 °C, and good epitaxy can be obtained from room temperature to 800 °C. The epitaxy is such that BaTiO3(001)∥BaO(001)∥Si(001) and BaTiO 3〈110〉∥BaO〈100〉∥Si〈100〉.

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Research works printed but not linked: 7

  1. 1988, Jpn. J. Appl. Phys., 27, L1025, 10.1143/JJAP.27.L1025 · doi:10.1143/jjap.27.l1025
  2. 1990, Appl. Phys. Lett., 57, 1161, 10.1063/1.104225 · doi:10.1063/1.104225
  3. 1991, Appl. Phys. Lett., 58, 419, 10.1063/1.104655 · doi:10.1063/1.104655
  4. 1978, J. Less-Common Met., 58, 58
  5. 1980, J. Less-Common Met., 69, 399, 10.1016/0022-5088(80)90299-4 · doi:10.1016/0022-5088(80)90299-4
  6. 1989, Phys. Rev. Lett., 62, 2476, 10.1103/PhysRevLett.62.2476 · doi:10.1103/physrevlett.62.2476
  7. 1988, MRS Bull., 16, Aug

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Metadata

Authors
McKee, R. A., Walker, F. J., Conner, J. R., Specht, E. D., & Zelmon, D. E.
Venue
Applied Physics Letters
Published
1991-08-12
Volume
59
Issue
7
Pages
782-784
ISSN
  • 0003-6951 (ISSN-L)
  • 1077-3118
OpenAlex
W2051121787
Cited by
205
References
0
FWCI
10.60
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Molecular beam epitaxy growth of epitaxial barium silicide, barium oxide, and barium titanate on silicon. https://app.cochat.ai/papers/10.1063/1.105341
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McKee, R. A., Walker, F. J., Conner, J. R., Specht, E. D., & Zelmon, D. E. (1991). Molecular beam epitaxy growth of epitaxial barium silicide, barium oxide, and barium titanate on silicon. Applied Physics Letters. https://doi.org/10.1063/1.105341

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