The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Living Radical Polymerization by the RAFT Process
Abstract
This paper presents a review of living radical polymerization achieved with thiocarbonylthio compounds [ZC(=S)SR] by a mechanism of reversible addition–fragmentation chain transfer (RAFT). Since we first introduced the technique in 1998, the number of papers and patents on the RAFT process has increased exponentially as the technique has proved to be one of the most versatile for the provision of polymers of well defined architecture. The factors influencing the effectiveness of RAFT agents and outcome of RAFT polymerization are detailed. With this insight, guidelines are presented on how to conduct RAFT and choose RAFT agents to achieve particular structures. A survey is provided of the current scope and applications of the RAFT process in the synthesis of well defined homo-, gradient, diblock, triblock, and star polymers, as well as more complex architectures including microgels and polymer brushes.
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Citations
Cites
Chong, ). Y. K., Le, T. P. T., Moad, G., Rizzardo, E., & Thang, S. H. (1999) · Macromolecules · doi:10.1021/ma981472p · Cited by 850
Self-citationYou, Y., Hong, C., Wang, W., Lu, W., & Pan, C. (2004) · Macromolecules · doi:10.1021/ma048444t · Cited by 151
He, T., Zou, Y.-F., & Pan, C.-Y. (2002) · Polymer Journal · doi:10.1295/polymj.34.138 · Cited by 47
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Universal (switchable) RAFT agents
Benaglia, M., Chiefari, J., Chong, Y. K., Moad, G., Rizzardo, E., & Thang, S. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja901955n · Cited by 302
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Toy, A. A., Chaffey-Millar, H., Davis, T. P., Stenzel, M. H., Izgorodina, E. I., Coote, M. L., & Barner-Kowollik, C. (2006) · Chemical Communications · doi:10.1039/b515561d · Cited by 64
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Kim, I., & Li, S. (2019) · Polymer Reviews · doi:10.1080/15583724.2019.1579227 · Cited by 30
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Metadata
- Authors
- Moad, G., Rizzardo, E., & Thang, S. H.
- Venue
- Australian Journal of Chemistry
- Publisher
- CSIRO Publishing
- Published
- 2005-06-14
- Volume
- 58
- Issue
- 6
- Pages
- 379-410
- ISSN
- 0004-9425 (ISSN-L)
- 1445-0038
- OpenAlex
- W2104018884
- Cited by
- 2,288
- References
- 3
- FWCI
- 88.12
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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