Student or educator? Sign up with your school email and get 6 months of Pro free.
Cited by 702

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

A review of direct air capture (DAC): scaling up commercial technologies and innovating for the future

Open access
McQueen, Noah, Gomes, Katherine Vaz, McCormick, Colin, Blumanthal, Katherine, Pisciotta, Maxwell, Wilcox, Jennifer·2021·Progress in Energy

Abstract

Direct air capture (DAC) can provide an impactful, engineered approach to combat climate change by removing carbon dioxide (CO 2) from the air. However, to meet climate goals, DAC needs to be scaled at a rapid rate. Current DAC approaches use engineered contactors filled with chemicals to repeatedly capture CO 2 from the air and release high purity CO 2 that can be stored or otherwise used. This review article focuses on two distinctive, commercial DAC processes to bind with CO 2: solid sorbents and liquid solvents. We discuss the properties of solvents and sorbents, including mass transfer, heat transfer and chemical kinetics, as well as how these properties influence the design and cost of the DAC process. Further, we provide a novel overview of the considerations for deploying these DAC technologies, including concepts for learning-by-doing that may drive down costs and material requirements for scaling up DAC technologies.

Overview

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1088/2516-1083/abf1ce

Cites

2 of 2 references verified0 citation errors · 0 not checkable

Statistics

Verification

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Citations

Cites

Show all 2 references

Research works printed but not linked: 77

  1. Agee, 2013, CO2 snow deposition in Antarctica to curtail anthropogenic global warming, J. Appl. Meteorol. Climatol., 52, 281, 10.1175/JAMC-D-12-0110.1 · DOI
  2. Agee, 2016, An initial laboratory prototype experiment for sequestration of atmospheric CO2, J. Appl. Meteorol. Climatol., 55, 1763, 10.1175/JAMC-D-16-0135.1 · DOI
  3. von Hippel, 2018, Thermal removal of carbon dioxide from the atmosphere: energy requirements and scaling issues, Clim. Change, 148, 491, 10.1007/s10584-018-2208-0 · DOI
  4. Lackner, 2009, Capture of carbon dioxide from ambient air, Eur. Phys. J. Spec. Top., 176, 93, 10.1140/epjst/e2009-01150-3 · DOI · Paper page
  5. Wang, 2013, Moisture-swing sorption for carbon dioxide capture from ambient air: a thermodynamic analysis, Phys. Chem. Chem. Phys., 15, 504, 10.1039/C2CP43124F · DOI
  6. Shi, 2020, Moisture-driven CO2 sorbents, Joule, 4, 1823, 10.1016/j.joule.2020.07.005 · DOI
  7. Voskian, 2019, Faradaic electro-swing reactive adsorption for CO2 capture, Energy Environ. Sci., 12, 3530, 10.1039/C9EE02412C · DOI · Paper page
  8. McQueen, 2020, Ambient weathering of magnesium oxide for CO2 removal from air, Nat. Commun., 11, 3299, 10.1038/s41467-020-16510-3 · DOI · Paper page
  9. Brethomé, 2018, Direct air capture of CO2 via aqueous-phase absorption and crystalline-phase release using concentrated solar power, Nat. Energy, 3, 553, 10.1038/s41560-018-0150-z · DOI · Paper page
  10. Choi, 2011, Application of amine-tethered solid sorbents for direct CO2 capture from the ambient air, Environ. Sci. Technol., 45, 2420, 10.1021/es102797w · DOI · Paper page
  11. Holmes, 2012, An air-liquid contactor for large-scale capture of CO2 from air, Phil. Trans. R. Soc. A, 370, 4380, 10.1098/rsta.2012.0137 · DOI · Paper page
  12. Sinha, 2017, Systems design and economic analysis of direct air capture of CO2 through temperature vacuum swing adsorption using MIL-101(Cr)-PEI-800 and mmen-Mg2(dobpdc) MOF adsorbents, Ind. Eng. Chem. Res., 56, 750, 10.1021/acs.iecr.6b03887 · DOI · Paper page
  13. Gebald, 2013, Stability of amine-functionalized cellulose during temperature-vacuum-swing cycling for CO2 capture from air, Environ. Sci. Technol., 47, 10063, 10.1021/es401731p · DOI
  14. Fasihi, 2019, Techno-economic assessment of CO2 direct air capture plants, J. Cleaner Prod., 224, 957, 10.1016/j.jclepro.2019.03.086 · DOI · Paper page
  15. Beuttler, 2019, The role of direct air capture in mitigation of anthropogenic greenhouse gas emissions, Front. Clim., 1, 10, 10.3389/fclim.2019.00010 · DOI · Paper page
  16. McQueen, 2020, Cost analysis of direct air capture and sequestration coupled to low-carbon thermal energy in the U.S, Environ. Sci. Technol., 54, 7551, 10.1021/acs.est.0c00476 · DOI
  17. Sadiq, 2020, Engineered porous nanocomposites that deliver remarkably low carbon capture energy costs, Cell Rep. Phys. Sci., 3, 10.1016/j.xcrp.2020.100070 · DOI
  18. Sinha, 2019, A parametric study of the techno-economics of direct CO2 air capture systems using solid adsorbents, AIChE J., 65, 10.1002/aic.16607 · DOI
  19. Nandi, 2017, Ultralow parasitic energy for postcombustion CO2 capture realized in a nickel isonicotinate metal-organic framework with excellent moisture stability, J. Am. Chem. Soc., 139, 1734, 10.1021/jacs.6b10455 · DOI · Paper page
  20. Mazzotti, 2013, Direct air capture of CO2 with chemicals: optimization of a two-loop hydroxide carbonate system using a countercurrent air-liquid contactor, Clim. Change, 118, 119, 10.1007/s10584-012-0679-y · DOI
  21. Breyer, 2020, Carbon dioxide direct air capture for effective climate change mitigation based on renewable electricity: a new type of energy system sector coupling, Mitig. Adapt. Strateg. Glob. Change, 25, 43, 10.1007/s11027-019-9847-y · DOI
  22. Wevers, 2020, What does it take to go net-zero-CO2? A life cycle assessment on long-term storage of intermittent renewables with chemical energy carriers, Front. Energy Res., 8, 104, 10.3389/fenrg.2020.00104 · DOI
  23. Arpagaus, 2018, High temperature heat pumps: market overview, state of the art, research status, refrigerants, and application potentials, Energy, 152, 985, 10.1016/j.energy.2018.03.166 · DOI · Paper page
  24. McQueen, 2021, Natural gas vs. electricity for solvent-based direct air capture, Front. Clim., 2, 10.3389/fclim.2020.618644 · DOI
  25. Haynes, 1976, Energy use in petroleum refineries, 10.2172/7261027 · doi:10.2172/7261027
  26. Chun-Che Huang, 1998, Modularity in design of products and systems, IEEE Trans. Syst. Man Cybern. A, 28, 66, 10.1109/3468.650323 · doi:10.1109/3468.650323
  27. Baker, 2020, Getting to neutral: options for negative carbon emissions in California, 10.2172/1597217 · DOI
  28. Tollefson, 2018, Sucking carbon dioxide from air is cheaper than scientists thought news, Nature, 558, 173, 10.1038/d41586-018-05357-w · DOI
  29. Hölttä-Otto, 2007, Degree of modularity in engineering systems and products with technical and business constraints, Concurr. Eng., Res. Appl., 15, 113, 10.1177/1063293X07078931 · DOI
  30. Wilcox, 2014, Revisiting film theory to consider approaches for enhanced solvent-process design for carbon capture, Energy Environ. Sci., 7, 1769, 10.1039/c4ee00001c · DOI
  31. McKittrick, 2003, Toward single-site functional materials—preparation of amine-functionalized surfaces exhibiting site-isolated behavior, Chem. Mater., 15, 1132, 10.1021/cm020952z · doi:10.1021/cm020952z
  32. Li, 2010, Structural changes of silica mesocellular foam supported amine-functionalized CO2 adsorbents upon exposure to steam, ACS Appl. Mater. Interfaces, 2, 3363, 10.1021/am100786z · DOI
  33. Sumida, 2012, Carbon dioxide capture in metal-organic frameworks, Chem. Rev., 112, 724, 10.1021/cr2003272 · DOI · Paper page
  34. Ramaswamy, 2014, MOFs as proton conductors-challenges and opportunities, Chem. Soc. Rev., 43, 5913, 10.1039/C4CS00093E · doi:10.1039/c4cs00093e
  35. Park, 2013, Enhanced isosteric heat, selectivity, and uptake capacity of CO2 adsorption in a metal-organic framework by impregnated metal ions, Chem. Sci., 4, 685, 10.1039/C2SC21253F · DOI
  36. Liu, 2017, Heat capacities and thermodynamic properties of Cr-MIL-101, J. Therm. Anal. Calorim., 129, 509, 10.1007/s10973-017-6168-9 · doi:10.1007/s10973-017-6168-9
  37. Lang, 1947, Engineering approaches to preliminary cost estimates, Chem. Eng., 54, 130
  38. Lang, 1947, Cost relationships in preliminary cost estimation, Chem. Eng., 54, 27
  39. Dysert, 2003, Sharpen your cost estimating skills, Cost Eng., 45, 22
  40. Tanzer, 2019, When are negative emissions negative emissions?, Energy Environ. Sci., 12, 1210, 10.1039/C8EE03338B · DOI
  41. Darunte, 2019, Moving beyond adsorption capacity in design of adsorbents for CO2 capture from ultradilute feeds: kinetics of CO2 adsorption in materials with stepped isotherms, Ind. Eng. Chem. Res., 58, 366, 10.1021/acs.iecr.8b05042 · DOI
  42. Azarabadi, 2019, A sorbent-focused techno-economic analysis of direct air capture, Appl. Energy, 250, 959, 10.1016/j.apenergy.2019.04.012 · DOI · Paper page
  43. Gupta, 1998, 10.1201/9780367802301 · doi:10.1201/9780367802301
  44. Wright, 1936, Factors affecting the cost of airplanes, J. Aeronaut. Sci., 3, 122, 10.2514/8.155 · DOI · Paper page
  45. McDonald, 2001, Learning rates for energy technologies, Energy Policy, 29, 255, 10.1016/S0301-4215(00)00122-1 · DOI · Paper page
  46. Nagy, 2013, Statistical basis for predicting technological progress, PLoS One, 8, 10.1371/journal.pone.0052669 · DOI · Paper page
  47. Rubin, 2015, A review of learning rates for electricity supply technologies, Energy Policy, 86, 198, 10.1016/j.enpol.2015.06.011 · DOI · Paper page
  48. Schmidt, 2017, The future cost of electrical energy storage based on experience rates, Nat. Energy, 2, 10.1038/nenergy.2017.110 · DOI · Paper page
  49. Arrow, 1962, The economic implications of learning by doing, Rev. Econ. Stud., 29, 155, 10.2307/2295952 · DOI · Paper page
  50. Samadi, 2018, The experience curve theory and its application in the field of electricity generation technologies—a literature review, Renew. Sustain. Energy Rev., 82, 2346, 10.1016/j.rser.2017.08.077 · DOI
  51. Kavlak, 2018, Evaluating the causes of cost reduction in photovoltaic modules, Energy Policy, 123, 700, 10.1016/j.enpol.2018.08.015 · DOI · Paper page
  52. Grubler, 2010, The costs of the French nuclear scale-up: a case of negative learning by doing, Energy Policy, 38, 5174, 10.1016/j.enpol.2010.05.003 · DOI · Paper page
  53. Fukui, 2017, Experience curve for natural gas production by hydraulic fracturing, Energy Policy, 1, 263, 10.1016/j.enpol.2017.02.027 · doi:10.1016/j.enpol.2017.02.027
  54. Rubin, 2004, Experience curves for power plant emission control technologies, Int. J. Energy Technol. Policy, 2, 52, 10.1504/IJETP.2004.004587 · DOI
  55. Yeh, 2007, A centurial history of technological change and learning curves for pulverized coal-fired utility boilers, Energy, 32, 1996, 10.1016/j.energy.2007.03.004 · DOI
  56. Hayashi, 2018, Gone with the wind: a learning curve analysis of China’s wind power industry, Energy Policy, 1, 38, 10.1016/j.enpol.2018.05.012 · doi:10.1016/j.enpol.2018.05.012
  57. Deutz, 2021, Life-cycle assessment of an industrial direct air capture process based on temperature–vacuum swing adsorption, Nat. Energy, 6, 203, 10.1038/s41560-020-00771-9 · DOI · Paper page
  58. Hoskins, 1989, Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments, J. Am. Chem. Soc., 111, 5962, 10.1021/ja00197a079 · DOI · Paper page
  59. Seyyedi, 2015, Metal-organic frameworks: a new class of crystalline porous materials, Johns. Matthey Technol. Rev., 59, 123, 10.1595/205651315X687425 · doi:10.1595/205651315x687425
  60. Yaghi, 1995, Selective binding and removal of guests in a microporous metal–organic framework, Nature, 378, 703, 10.1038/378703a0 · DOI · Paper page
  61. Dey, 2014, Crystalline metal-organic frameworks (MOFs): synthesis, structure and function, Acta Crystallogr. B, 70, 3, 10.1107/S2052520613029557 · DOI · Paper page
  62. Sharmin, 2016, 10.5772/64797 · doi:10.5772/64797
  63. Cheng, 2020, Practical MOF nanoarchitectonics: new strategies for enhancing the processability of MOFs for practical applications, Langmuir, 36, 4231, 10.1021/acs.langmuir.0c00236 · DOI
  64. Scott, 2017, The next big thing, again, C&EN Glob. Enterp., 95, 18
  65. Rubio-Martinez, 2017, New synthetic routes towards MOF production at scale, Chem. Soc. Rev., 46, 3453, 10.1039/C7CS00109F · DOI · Paper page
  66. Feng, 2014, Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal-organic frameworks, Nat. Commun., 5, 5723, 10.1038/ncomms6723 · doi:10.1038/ncomms6723
  67. Stock, 2012, Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites, Chem. Rev., 112, 933, 10.1021/cr200304e · DOI · Paper page
  68. Sung, 2005, Microwave synthesis of a nanoporous hybrid material, chromium trimesate, Bull. Korean Chem. Soc., 26, 880, 10.5012/bkcs.2005.26.6.880 · doi:10.5012/bkcs.2005.26.6.880
  69. Ding, 2019, Improving MOF stability: approaches and applications, Chem. Sci., 10, 10209, 10.1039/C9SC03916C · DOI · Paper page
  70. Yilmaz, 2012, Industrial outlook on zeolites and metal organic frameworks, Cuihua Xuebao/Chin. J. Catal., 33, 3, 10.1016/S1872-2067(10)60302-6 · DOI
  71. Gaab, 2012, The progression of Al-based metal-organic frameworks—from academic research to industrial production and applications, Microporous Mesoporous Mater., 15, 131, 10.1016/j.micromeso.2011.08.016 · DOI · Paper page
  72. Wilson, 2020, Direct dry air capture of CO2 using VTSA with faujasite zeolites, Ind. Eng. Chem. Res., 59, 8783, 10.1021/acs.iecr.9b04803 · DOI
  73. Cundy, 2003, The hydrothermal synthesis of zeolites: history and development from the earliest days to the present time, Chem. Rev., 103, 663, 10.1021/cr020060i · DOI · Paper page
  74. Pourazar, 2020, Preparation of 13X zeolite powder and membrane: investigation of synthesis parameters impacts using experimental design, Mater. Res. Express, 7, 10.1088/2053-1591/ab7217 · DOI
  75. Casci, 2005, 217, 10.1016/j.micromeso.2005.01.035 · DOI
  76. Shi, 2015, 1, 10.1007/978-1-4614-6431-0_83-1 · DOI
  77. Chatterjee, 2020, Unrealistic energy and materials requirement for direct air capture in deep mitigation pathways, Nat. Commun. Nat. Res., 11, 1, 10.1038/s41467-019-10842-5 · DOI · Paper page

Cited by

See all 702

Metadata

Authors
McQueen, N., Gomes, K. V., McCormick, C., Blumanthal, K., Pisciotta, M., & Wilcox, J.
Venue
Progress in Energy
Published
2021-04-16
Volume
3
Issue
3
Pages
032001
ISSN
2516-1083 (ISSN-L)
OpenAlex
W3137007811
Cited by
702
References
2
FWCI
41.08
Type
journal article
Language
en
Open access
hybrid
Licence
Funders
  • William and Flora Hewlett Foundation
  • ClimateWorks Foundation

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

How to cite

Cite CoChat for the checks on this page, and the paper for its own findings.

This page
CoChat. (2026). Citation check: A review of direct air capture (DAC): scaling up commercial technologies and innovating for the future. https://app.cochat.ai/papers/10.1088/2516-1083/abf1ce
The paper
McQueen, N., Gomes, K. V., McCormick, C., Blumanthal, K., Pisciotta, M., & Wilcox, J. (2021). A review of direct air capture (DAC): scaling up commercial technologies and innovating for the future. Progress in Energy. https://doi.org/10.1088/2516-1083/abf1ce

Data sources

Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.