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Molybdenum Isotope Evidence for Widespread Anoxia in Mid-Proterozoic Oceans

Arnold, G. L., Anbar, A. D., Barling, J., Lyons, T. W.·2004·Science

DOI 10.1126/science.1091785

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Abstract

How much dissolved oxygen was present in the mid-Proterozoic oceans between 1.8 and 1.0 billion years ago is debated vigorously. One model argues for oxygenation of the oceans soon after the initial rise of atmospheric oxygen approximately 2.3 billion years ago. Recent evidence for H(2)S in some mid-Proterozoic marine basins suggests, however, that the deep ocean remained anoxic until much later. New molybdenum isotope data from modern and ancient sediments indicate expanded anoxia during the mid-Proterozoic compared to the present-day ocean. Consequently, oxygenation of the deep oceans may have lagged that of the atmosphere by over a billion years.

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Authors: Arnold, G. L., Anbar, A. D., Barling, J., & Lyons, T. W.
Affiliations: University of Rochester (US)
Corresponding author: Arnold, G. L.
Barling, J.
ORCID: Arnold, G. L.
Anbar, A. D.
Barling, J.
Lyons, T. W.
Venue: Science
Publisher: American Association for the Advancement of Science (AAAS)
Published: 2004-04-02
Volume: 304
Issue: 5667
Pages: 87-90
ISSN: 0036-8075 (ISSN-L)
1095-9203
DOI: 10.1126/science.1091785
OpenAlex: W2156107051
Cited by: 689
References: 28
Citations by year: 2026: 22 · 2025: 23 · 2024: 24 · 2023: 24 · 2022: 20 · 2021: 50 · 2020: 32 · 2019: 30 · 2018: 33 · 2017: 36 · 2016: 24 · 2015: 33 · 2014: 20 · 2013: 38 · 2012: 39
FWCI: 35.07
Type: journal article
Language: en
Open access: closed
Locations: Science (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Earth and Planetary Sciences › Paleontology › Paleontology and Stratigraphy of Fossils
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geochemistry and Elemental Analysis
Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Geological and Geochemical Analysis
Keywords: molybdenum isotopes, ocean anoxia, atmospheric oxygenation, hydrogen sulfide, Precambrian sediments, paleoceanography, Great Oxidation

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Molybdenum Isotope Evidence for Widespread Anoxia in Mid-Proterozoic Oceans

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