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Studies on Charging Lithium-Ion Cells at Low Temperatures
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The charge and discharge voltage profiles obtained with the conventional constant current–constant voltage charging and pulse charging protocols at low temperatures were studied. There are two peaks in the charge and subsequent discharge voltage profiles, which suggests that lithium plating can occur in two stages during the low-temperature charging. The first stage may occur shortly after the charging at while the second stage occurs in the later part of charging. The lithium deposited on the negative surface during the low-temperature charging can rapidly diffuse into the graphite negative at room temperature while it cannot diffuse into the graphite negative at . It appears that the lithium solid diffusion in the graphite negative is the ultimate rate-limiting factor for charging lithium-ion cells at low temperatures. The effects on cell properties such as cell capacity, rate capability, impedance, and cycle life from low-temperature charging with different charging protocols were also studied. Directions for improving the low-temperature charge capability of the lithium-ion cells and designing low-temperature charging protocols are discussed.
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“The LT effects on charging and discharging are asymmetric: the charge transfer resistance at LTs in the discharged state is substantially higher, making it much more challenging when charging a discharged LIB at LTs [14,15].”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [15]
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Energy-Conscious Warm-Up of Li-Ion Cells From Subzero Temperatures
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BackgroundLow temperature performance of LiFePO4 cathode material for Li-ion batteries
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Carbonaceous Materials as Anodes for Lithium-Ion and Sodium-Ion Batteries
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Suppression of lithium deposition at sub-zero temperatures on graphite by surface modification
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Metadata
- Authors
- Fan, J., & Tan, S.
- ORCID
- Fan, Jiang
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2006
- Volume
- 153
- Issue
- 6
- Pages
- A1081
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2047172256
- Cited by
- 211
- References
- 22
- Citations by year
- 2026: 10 · 2025: 15 · 2024: 16 · 2023: 18 · 2022: 21 · 2021: 17 · 2020: 12 · 2019: 16 · 2018: 10 · 2017: 17 · 2016: 16 · 2015: 14 · 2014: 9 · 2013: 8 · 2012: 2
- FWCI
- 5.68
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Journal of The Electrochemical Society (publishedVersion)
- Topics
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Keywords
- lithium-ion cells, low-temperature charging, lithium plating, graphite anode, lithium ion diffusion, constant current constant voltage charging, pulse charging, voltage profile, rate capability, cycle life, cell impedance, capacity retention
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