The DOI matches its Crossref record; 33 of the 33 references it cites were found in a registry or an index.
Identifying Capacity Limitations in the Li/Oxygen Battery Using Experiments and Modeling
Open accessAbstract
The Li/oxygen battery may achieve a high practical specific energy as its theoretical specific energy is Li assuming is the product. To help understand the physics of the Li/oxygen battery we present the first physics-based model that incorporates the major thermodynamic, transport, and kinetic processes. We obtain a good match between porous-electrode experiments and simulations by using an empirical fit to the resistance of the discharge products (which include carbonates and oxides when using carbonate solvents) as a function of thickness that is obtained from flat-electrode experiments. The experiments and model indicate that the discharge products are electronically resistive, limiting their thickness to tens of nanometers and their volume fraction in one of our discharged porous electrodes to a few percent. Flat-electrode experiments, where pore clogging is impossible, show passivation similar to porous-electrode experiments and allow us to conclude that electrical passivation is the dominant capacity-limiting mechanism in our cells. Although in carbonate solvents is not the dominant discharge product, we argue that the implications of this model, (i.e., electrical passivation by the discharge products limits the capacity) also apply if is the discharge product, as it is an intrinsic electronic insulator.
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Cites
Projector augmented-wave method
Blöchl, P. E. (1994) · Physical Review B · doi:10.1103/physrevb.50.17953 · Cited by 92,732
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Lithium−Air Battery: Promise and Challenges
Girishkumar, G., McCloskey, B., Luntz, A. C., Swanson, S., & Wilcke, W. (2010) · The Journal of Physical Chemistry Letters · doi:10.1021/jz1005384 · Cited by 2,528
Self-citationA Polymer Electrolyte‐Based Rechargeable Lithium/Oxygen Battery
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Simulation and Optimization of the Dual Lithium Ion Insertion Cell
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Cited by
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Challenges Facing Lithium Batteries and Electrical Double‐Layer Capacitors
Choi, N., Chen, Z., Freunberger, S. A., Ji, X., Sun, Y., Amine, K., Yushin, G., Nazar, L. F., Cho, J., & Bruce, P. G. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201429 · Cited by 2,700
Metal–air batteries: from oxygen reduction electrochemistry to cathode catalysts
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Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li–O2 Batteries
McCloskey, B. D., Speidel, A., Scheffler, R., Miller, D. C., Viswanathan, V., Hummelshøj, J. S., Nørskov, J. K., & Luntz, A. C. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz300243r · Cited by 1,073
Self-citationA Critical Review of Li/Air Batteries
Christensen, J., Albertus, P., Sanchez-Carrera, R. S., Lohmann, T., Kozinsky, B., Liedtke, R., Ahmed, J., & Kojic, A. (2011) · Journal of The Electrochemical Society · doi:10.1149/2.086202jes · Cited by 1,041
Self-citation
Metadata
- Authors
- Albertus, P., Girishkumar, G., McCloskey, B., Sánchez-Carrera, R. S., Kozinsky, B., Christensen, J., & Luntz, A. C.
- Venue
- Journal of The Electrochemical Society
- Publisher
- The Electrochemical Society
- Published
- 2011
- Volume
- 158
- Issue
- 3
- Pages
- A343
- ISSN
- 0013-4651 (ISSN-L)
- OpenAlex
- W2082941808
- Cited by
- 301
- References
- 33
- FWCI
- 24.51
- Type
- journal article
- Language
- en
- Open access
- bronze
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