Solid-solution aqueous-solution equilibria; thermodynamic theory and representation

Glynn, P. D.; Reardon, E. J.

doi:10.2475/ajs.290.2.164

Cited by 219Chemical and Physical Properties in Aqueous SolutionsPhase Equilibria and ThermodynamicsCrystallization and Solubility Studies

Solid-solution aqueous-solution equilibria; thermodynamic theory and representation

Glynn, P. D., Reardon, E. J.·1990·American Journal of Science

DOI 10.2475/ajs.290.2.164

Open this paper in CoChat — free account

Integrity signals

Registry

Crossref · 10.2475/ajs.290.2.164

Cites

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

We couldn’t retrieve this paper’s full text, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Solid activity coefficients of CaCO3 and MnCO3 in terms of solid components can be estimated by the Redlich and Kister equations.
“The solid activity coefficients of CaCO3 () and MnCO3 () in terms of solid components (1−x, x) can be estimated by the Redlich and Kister equations [50, 54, 60], which are expressed as:1617 where 1−x and x are the molar ratios ( and ) of CaCO3 and MnCO3 in the (Ca1-xMnx)CO3 solid solutions, respectively.”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [50]
When stoichiometric saturation state was reached during dissolution, the excess free energy of mixing for (BxC1-x)A solid solutions can be estimated with Eq. (18).
“When the stoichiometric saturation state was reached during dissolution, the excess free energy of mixing for the (BxC1-x)A solid solutions (GE) can be estimated with the following:18 where KSS is the stoichiometric saturation constant and KCA and KBA are the solubility products of CA and BA, respectively [34, 50].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [50]

Sorted by citations

User's guide to PHREEQC (Version 2): A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
Parkhurst, D. L., & Appelo, C. A. J. (1999) · doi:10.3133/wri994259 · Cited by 7,647 · see citing works
“PHREEQC uses a Guggenheim approach for determining activities of components in nonideal, binary s solutions (Glynn and Reardon, 1990).”
Method
Description of input and examples for PHREEQC version 3: A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
Parkhurst, D. L., & Appelo, C. A. J. (2013) · Techniques and Methods · doi:10.3133/tm6a43 · Cited by 3,779 · see citing works
Mineral replacement reactions: from macroscopic observations to microscopic mechanisms
Putnis, A. (2002) · Mineralogical Magazine · doi:10.1180/0026461026650056 · Cited by 1,177 · see citing works
“The solubility diagram (from data of Durham et al., 1953) and the Lippmann diagram (Glynn et al., 1990) are shown in Figure 9.”
BackgroundMethod
Mineral Replacement Reactions
Putnis, A. (2009) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2009.70.3 · Cited by 1,160 · see citing works
Solid solution partitioning of Sr2+, Ba2+, and Cd2+ to calcite
Tesoriero, A. J., & Pankow, J. F. (1996) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(95)00449-1 · Cited by 568 · see citing works
Properties of magnesium silicate hydrates (M-S-H)
Nied, D., Enemark‐Rasmussen, K., L’Hôpital, E., Skibsted, J., & Lothenbach, B. (2015) · Cement and Concrete Research · doi:10.1016/j.cemconres.2015.10.003 · Cited by 394 · see citing works
Barite–Celestine Geochemistry and Environments of Formation
Hanor, J. S. (2000) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2000.40.4 · Cited by 359 · see citing works
Synthesis and characterization of hydrogarnet Ca3(AlxFe1−x)2(SiO4)y(OH)4(3−y)
Dilnesa, B. Z., Lothenbach, B., Guillaume Renaudin, A., Wichser, A., & Kulik, D. A. (2014) · Cement and Concrete Research · doi:10.1016/j.cemconres.2014.02.001 · Cited by 315 · see citing works
Initial responses of carbonate-rich shelf sediments to rising atmospheric pCO2 and “ocean acidification”: Role of high Mg-calcites
Morse, J. W., Andersson, A. J., & Mackenzie, F. T. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2006.08.017 · Cited by 324 · see citing works
Magnesium and calcium silicate hydrates
Lothenbach, B., Nied, D., L’Hôpital, E., et al. (2015) · Cement and Concrete Research · doi:10.1016/j.cemconres.2015.06.007 · Cited by 298 · see citing works
Geochemistry and the understanding of ground-water systems
Glynn, P. D., & Plummer, L. N. (2005) · Hydrogeology Journal · doi:10.1007/s10040-004-0429-y · Cited by 263 · see citing works
Self-citation
Rare earth and yttrium phosphate solubilities in aqueous solution
Liu, X., & Byrne, R. H. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00037-9 · Cited by 256 · see citing works
Application of Melt Extrusion in the Development of a Physically and Chemically Stable High-Energy Amorphous Solid Dispersion of a Poorly Water-Soluble Drug
Lakshman, J. P., Cao, Y., Kowalski, J., et al. (2008) · Molecular Pharmaceutics · doi:10.1021/mp8001073 · Cited by 238 · see citing works
Synthesis, characterization and stability of Cr(III) and Fe(III) hydroxides
Papassiopi, N., Vaxevanidou, K., Christou, C. N., et al. (2013) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2013.09.058 · Cited by 191 · see citing works
“On the assumption that both phases behave as solid solutions of the form [Fe(OH)3](1−x)·[Cr(OH)3]x, the Cr(III) content in solution can be estimated on the basis of the pure chromium hydroxide reaction constant, KCr, and the Cr(OH)3 activity in the solid solution [41] as Cr(OH)2+/(H+)2 = KCrxCr Cr = KCr ′ (2)”
Background
The role of sulfate groups in controlling CaCO3 polymorphism
Fernández-Dı́az, L., González, Á. F., & Rubio, M. P. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.08.010 · Cited by 186 · see citing works
Chemical model for cement-based materials: Temperature dependence of thermodynamic functions for nanocrystalline and crystalline C–S–H phases
Blanc, P., Bourbon, X., Lassin, A., & Gaucher, É. C. (2010) · Cement and Concrete Research · doi:10.1016/j.cemconres.2009.12.004 · Cited by 166 · see citing works
General model for calcite growth kinetics in the presence of impurity ions
Lammers, L. N., Yoreo, J. J. D., & DePaolo, D. J. (2013) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.04.001 · Cited by 162 · see citing works
Nucleation, growth, and zoning phenomena in crystallizing (Ba,Sr)CO3, Ba(SO4,CrO4), (Ba,Sr)SO4, and (Cd,Ca)CO3 solid solutions from aqueous solutions
Prieto, M., Fernández-González, A., Putnis, A., & Fernández-Díaz, L. (1997) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(97)00160-9 · Cited by 156 · see citing works
Experimentally produced oscillatory zoning in the (Ba, Sr)SO4 solid solution
Putnis, A., Fernández-Dı́az, L., & Rubio, M. P. (1992) · Nature · doi:10.1038/358743a0 · Cited by 149 · see citing works
Dissolution of primary minerals of basalt in natural waters
Stefánsson, A. (2001) · Chemical Geology · doi:10.1016/s0009-2541(00)00263-1 · Cited by 148 · see citing works
Solid-Solution Solubilities and Thermodynamics: Sulfates, Carbonates and Halides
Glynn, P. D. (2000) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2000.40.10 · Cited by 148 · see citing works
“The series of minimum stoichiometric points for a series of solid-phase compositions ranging from x = 0 to x = 1 defines the minimum stoichiometric saturation curve (Glynn and Reardon 1990), also called the equal-G curve (Königsberger and Gamsjäger 1992).”
BackgroundSelf-citation
The role of magnesium in the growth of calcite: An AFM study
Astilleros, J. M., Fernández-Díaz, L., & Putnis, A. (2010) · Chemical Geology · doi:10.1016/j.chemgeo.2009.12.011 · Cited by 131 · see citing works
Direct observations of mineral fluid reactions using atomic force microscopy: the specific example of calcite
Ruíz-Agudo, E., & Putnis, C. V. (2012) · Mineralogical Magazine · doi:10.1180/minmag.2012.076.1.227 · Cited by 125 · see citing works
“dynamic principles governing solid-solution– aqueous-solution (SS AS) systems on which this assertion is made are well established (Glynn and Reardon, 1990; Tesoriero and Pankow, 1996) and have recently been reviewed by Prieto (2009).”
Background
Reaction paths and equilibrium end-points in solid-solution aqueous-solution systems
Glynn, P. D., Reardon, E. J., Plummer, L. N., et al. (1990) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(90)90317-e · Cited by 120 · see citing works
Self-citation
Calcium silicate hydrate (C-S-H) gel solubility data and a discrete solid phase model at 25 °C based on two binary non-ideal solid solutions
Walker, C. S., Sutou, S., Oda, C., et al. (2015) · Cement and Concrete Research · doi:10.1016/j.cemconres.2015.07.006 · Cited by 116 · see citing works
Microstructural evolution during the infiltration of boron carbide with molten silicon
Hayun, S., Weizman, A., Dariel, M. P., et al. (2009) · Journal of the European Ceramic Society · doi:10.1016/j.jeurceramsoc.2009.09.021 · Cited by 115 · see citing works
Solid-Solution Reactions in As(V) Sorption by Schwertmannite
Fukushi, K., Satō, T., & Yanase, N. (2003) · Environmental Science & Technology · doi:10.1021/es026427i · Cited by 98 · see citing works
The Behavior of Mixed Ca–Mn Carbonates in Water and Seawater: Controls of Manganese Concentrations in Marine Porewaters
Mucci, A. (2004) · Aquatic Geochemistry · doi:10.1023/b:aqua.0000038958.56221.b4 · Cited by 94 · see citing works
An isopiestic study of aqueous NaBr and KBr at 50 °C: Chemical equilibrium model of solution behavior and solubility in the NaBr–H2O, KBr–H2O and Na–K–Br–H2O systems to high concentration and temperature
Christov, C. (2007) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2007.05.007 · Cited by 95 · see citing works
Synthesis, characterization, and thermodynamic study of selected Na-based zeolites
Ma, B., & Lothenbach, B. (2020) · Cement and Concrete Research · doi:10.1016/j.cemconres.2020.106111 · Cited by 90 · see citing works
Direct calculation of thermodynamic properties of the barite/celestite solid solution from molecular principles
Becker, U., González, Á. F., Rubio, M. P., et al. (2000) · Physics and Chemistry of Minerals · doi:10.1007/s002690050258 · Cited by 87 · see citing works
In situ AFM observations of the interaction between calcite ( 1 0 1 ¯ 4 ) surfaces and Cd-bearing aqueous solutions
Pérez-Garrido, C., Fernández-Dı́az, L., Pina, C. M., & Rubio, M. P. (2007) · Surface Science · doi:10.1016/j.susc.2007.09.021 · Cited by 87 · see citing works
Mineral replacement reactions in solid solution-aqueous solution systems: Volume changes, reactions paths and end-points using the example of model salt systems
Pollok, K., Putnis, C. V., & Putnis, A. (2011) · American Journal of Science · doi:10.2475/03.2011.02 · Cited by 87 · see citing works
“A Lippmann phase diagram can be used to visualize SS-AS equilibrium states (Lippmann, 1977, 1980; Glynn and Reardon, 1990; Putnis and others, 1995; Glynn, 2000; Prieto, 2009) and the thermodynamic framework is given below.”
Method
Gibbs energy minimization approach to modeling sorption equilibria at the mineral-water interface: Thermodynamic relations for multi-site-surface complexation
Kulik, D. (2002) · American Journal of Science · doi:10.2475/ajs.302.3.227 · Cited by 82 · see citing works
The saturation state of the world’s ocean with respect to (Ba,Sr)SO4 solid solutions
Monnin, C., & Cividini, D. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2006.04.002 · Cited by 84 · see citing works
Manganese(II) partitioning during experimental precipitation of rhodochrosite–calcite solid solutions from aqueous solutions
Böttcher, M. E. (1998) · Marine Chemistry · doi:10.1016/s0304-4203(98)00039-5 · Cited by 79 · see citing works
The composition of solid solutions crystallising from aqueous solutions: the influence of supersaturation and growth mechanisms
Pina, C. M., Enders, M., & Putnis, A. (2000) · Chemical Geology · doi:10.1016/s0009-2541(00)00227-8 · Cited by 79 · see citing works
“Lippmann diagram Glynn and Reardon, 1990 , in which SP is represented on the ordinate and the composition of the solid and the aqueous phase are represented in a double scale on the abscissa.”
BackgroundMethod
Crystal-Plane Dependence of Critical Concentration for Nucleation on Hydrothermal ZnO Nanowires
He, Y. J., Yanagida, T., Nagashima, K., et al. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3113232 · Cited by 74 · see citing works
Solubility of pyromorphite Pb5(PO4)3Cl–mimetite Pb5(AsO4)3Cl solid solution series
Flis, J., Manecki, M., & Bajda, T. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.01.021 · Cited by 73 · see citing works
Metal-ion partitioning during low-temperature precipitation and dissolution of anhydrous carbonates and sulphates
Böttcher, M. E., & Dietzel, M. (2012) · doi:10.1180/emu-notes.10.4 · Cited by 72 · see citing works
Solid Solutions between CrO 4 - and SO 4 -Ettringite Ca 6 (Al(OH) 6 ) 2 [(CrO 4 ) x (SO 4 ) 1- x ] 3 *26 H 2 O
Leisinger, S. M., Saoût, G. L., Saoût, G. L., et al. (2010) · Environmental Science & Technology · doi:10.1021/es100554v · Cited by 68 · see citing works
Metastable phenomena on calcite {1014} surfaces growing from Sr2+–Ca2+–CO32− aqueous solutions
Astilleros, J. M., Pina, C. M., Fernández-Dı́az, L., et al. (2002) · Chemical Geology · doi:10.1016/s0009-2541(02)00228-0 · Cited by 66 · see citing works
Thermodynamic modeling of solid solutions between monosulfate and monochromate 3CaO • Al2O3 • Ca[(CrO4)x(SO4)1-x] • nH2O
Leisinger, S. M., Saoût, G. L., Saoût, G. L., et al. (2011) · Cement and Concrete Research · doi:10.1016/j.cemconres.2011.09.005 · Cited by 65 · see citing works
“7) [37,38].”
Study of bromide salts solubility in the (m1KBr + m2CaBr2)(aq) system at T= 323.15 K. Thermodynamic model of solution behaviour and (solid + liquid) equilibria in the ternaries (m1KBr + m2CaBr2)(aq), and (m1MgBr2+ m2CaBr2)(aq), and in the quinary (Na + K + Mg + Ca + Br + H2O) systems to high concentration and temperature
Christov, C. (2012) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2012.06.006 · Cited by 64 · see citing works
A method of estimateng the Gibbs free energies of formation of hydrated and dehydrated clay minerals
Tardy, Y., & Duplay, J. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90287-s · Cited by 65 · see citing works
Non-ideal solid solution aqueous solution modeling of synthetic calcium silicate hydrate
Walker, C. S., Savage, D., Tyrer, M., & Ragnarsdottir, K. V. (2007) · Cement and Concrete Research · doi:10.1016/j.cemconres.2006.12.002 · Cited by 63 · see citing works
Crystallization behavior of solid solutions from aqueous solutions: An environmental perspective
Rubio, M. P., Heberling, F., Rodríguez-Galán, R. M., & Brandt, F. (2016) · Progress in Crystal Growth and Characterization of Materials · doi:10.1016/j.pcrysgrow.2016.05.001 · Cited by 61 · see citing works
The kinetics of nucleation of solid solutions from aqueous solutions: a new model for calculating non-equilibrium distribution coefficients
Pina, C. M., & Putnis, A. (2002) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(01)00770-0 · Cited by 61 · see citing works
In situ AFM observations of Ca–Mg carbonate crystallization catalyzed by dissolved sulfide: Implications for sedimentary dolomite formation
Zhang, F., Yan, C., Teng, H. H., Roden, E., & Xu, H. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.11.010 · Cited by 60 · see citing works
Isopiestic investigation of the osmotic coefficients of MgBr2(aq) and study of bromide salts solubility in the (m1KBr + m2MgBr2)(aq) system at T= 323.15 K. Thermodynamic model of solution behaviour and (solid + liquid) equilibria in the MgBr2(aq), and (m1KBr + m2MgBr2)(aq) systems to high concentration and temperature
Christov, C. (2010) · The Journal of Chemical Thermodynamics · doi:10.1016/j.jct.2010.10.006 · Cited by 59 · see citing works
Incorporation of Pb at the Calcite (104)–Water Interface
Callagon, E. B. R., Fenter, P., Nagy, K. L., et al. (2014) · Environmental Science & Technology · doi:10.1021/es5014888 · Cited by 59 · see citing works
Characterization, dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(PbxCa1−x)5(PO4)3OH] at 25 °C and pH 2–9
Zhu, Y., Huang, B., Zhu, Z., Liu, H., Huang, Y., Zhao, X., & Liang, M. (2016) · Geochemical Transactions · doi:10.1186/s12932-016-0034-8 · Cited by 60 · see citing works
“In constructing the Lippmann diagram, the total solubility product (ΣΠ) for (PbxCa1‒x)(PO4)3/5OH1/5 can be expressed as [47]:”
Background
Solid-solution aqueous-solution reactions between jarosite (KFe3(SO4)2(OH)6) and its chromate analog
Baron, D., & Palmer, C. D. (2002) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(02)00880-3 · Cited by 58 · see citing works
Thermodynamic study of cement/rock interactions using experimentally generated solubility data of zeolites
Ma, B., & Lothenbach, B. (2020) · Cement and Concrete Research · doi:10.1016/j.cemconres.2020.106149 · Cited by 58 · see citing works
“According to the three models, the Lippmann's total solubility product (ΣΠ) and Ksp values of each zeolite were calculated ([55,56], see details in Text A1) and plotted in Fig.”
Method
Reactive transport modeling of CO2 through cementitious materials under CO2 geological storage conditions
Shen, J., Dangla, P., & Thiéry, M. (2013) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2013.07.003 · Cited by 56 · see citing works
Nanoscale phenomena during the growth of solid solutions on calcite {101¯4} surfaces
Astilleros, J. M., Pina, C. M., Fernández-Dı́az, L., et al. (2005) · Chemical Geology · doi:10.1016/j.chemgeo.2005.08.025 · Cited by 54 · see citing works
Aqueous Solubility Diagrams for Cementitious Waste Stabilization Systems. 1. The C-S-H Solid-Solution System
Kersten, M. (1996) · Environmental Science & Technology · doi:10.1021/es950681b · Cited by 53 · see citing works
Evolution of calcite growth morphology in the presence of magnesium: Implications for the dolomite problem
Hong, M., Xu, J., & Teng, H. H. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.09.022 · Cited by 52 · see citing works
(Ca,Sr)CO3 aqueous–solid solution systems: From atomistic simulations to thermodynamic modelling
Kulik, D. A., Vinograd, V. L., Paulsen, N., et al. (2010) · Physics and Chemistry of the Earth Parts A/B/C · doi:10.1016/j.pce.2010.04.011 · Cited by 48 · see citing works
“(Glynn and Reardon, 1990; Lippmann, 1980; Prieto, 2009) defined as”
Supersaturation functions in binary solid solution–aqueous solution systems
Astilleros, J. M., Pina, C. M., Fernández-Dı́az, L., et al. (2003) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(02)01166-3 · Cited by 48 · see citing works
Nanoscale growth of solids crystallising from multicomponent aqueous solutions
Astilleros, J. M. (2003) · Surface Science · doi:10.1016/j.susc.2003.08.031 · Cited by 47 · see citing works
Solid-solute phase equilibria in aqueous solution. V: The system CdCO3-CaCO3-CO2-H2O
Königsberger, E., Hausner, R., & Gamsjäger, H. (1991) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(91)90051-6 · Cited by 47 · see citing works
Mineral Precipitation Kinetics
Fritz, B., & Noguera, C. (2009) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2009.70.8 · Cited by 44 · see citing works
Incorporating solid solutions in reactive transport equations using a kinetic discrete-composition approach
Lichtner, P. C., & Carey, J. W. (2006) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2005.11.028 · Cited by 43 · see citing works
Thermochemistry of mixing strontianite [SrCO3(s)] and aragonite [CaCO3(s)] to form CaxSr1−xCO3(s) solid solutions
Casey, W. H., Chal, L., Navrotsky, A., et al. (1996) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(96)00441-3 · Cited by 43 · see citing works
Dissolution of aragonite-strontianite solid solutions in nonstoichiometric Sr (HCO3)2−Ca (HCO3)2−CO2-H2O solutions
Plummer, L. N., Busenberg, E., Glynn, P. D., & Blum, A. E. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90289-u · Cited by 43 · see citing works
Self-citation
Application of Gibbs Energy Minimization to ModelEarly-Diagenetic Solid-Solution Aqueous-Solution EquilibriaInvolving Authigenic Rhodochrosites in Anoxic BalticSea Sediments
Kulik, D. A., Kersten, M., Heiser, U., & Neumann, T. (2000) · Aquatic Geochemistry · doi:10.1023/a:1009694703207 · Cited by 42 · see citing works
“The values of interaction parameters in these equations for (pseudo)binary systems can be predicted theoretically, as done above, or simply adjusted in graphical fitting of the solidus and solutus curves against the empirical 65 points on the Lippmann diagram plots (Glynn and Reardon, 1990).”
Method
Simulation of the nucleation and growth of simple clay minerals in weathering processes: The NANOKIN code
Fritz, B., Clément, A., Amal, Y., et al. (2008) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2008.11.043 · Cited by 42 · see citing works
Synthesis, characterization, and thermodynamic study of selected K-based zeolites
Ma, B., & Lothenbach, B. (2021) · Cement and Concrete Research · doi:10.1016/j.cemconres.2021.106537 · Cited by 41 · see citing works
Dual-thermodynamic estimation of stoichiometry and stability of solid solution end members in aqueous–solid solution systems
Kulik, D. A. (2005) · Chemical Geology · doi:10.1016/j.chemgeo.2005.08.014 · Cited by 42 · see citing works
Computing Lippmann Diagrams from Direct Calculation of Mixing Properties of Solid Solutions: Application to the Barite-Celestite System
Rubio, M. P., González, Á. F., Becker, U., & Putnis, A. (2000) · Aquatic Geochemistry · doi:10.1023/a:1009642619137 · Cited by 40 · see citing works
The solubility of (Ba,Sr)SO4 precipitates: Thermodynamic equilibrium and reaction path analysis
Felmy, A. R., Rai, D., & Moore, D. A. (1993) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(93)90487-h · Cited by 40 · see citing works
Heteroepitaxial growth of cadmium carbonate at dolomite and calcite surfaces: Mechanisms and rates
Callagon, E. B. R., Lee, S. S., Eng, P. J., Laanait, N., Sturchio, N. C., Nagy, K. L., & Fenter, P. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.12.007 · Cited by 40 · see citing works
Lippmann Diagrams: Theory and Application to Carbonate Systems
Gamsjäger, H., Königsberger, E., & Preis, W. (2000) · Aquatic Geochemistry · doi:10.1023/a:1009690502299 · Cited by 39 · see citing works
Precipitation and mixing properties of the “disordered” (Mn,Ca)CO3 solid solution
Katsikopoulos, D., González, Á. F., & Rubio, M. P. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2009.07.001 · Cited by 39 · see citing works
Trivalent actinide coprecipitation with powellite (CaMoO4): Secondary solid solution formation during HLW borosilicate-glass dissolution
Bosbach, D., Rabung, T., Brandt, F., et al. (2004) · Radiochimica Acta · doi:10.1524/ract.92.9.639.54976 · Cited by 39 · see citing works
“However, following Lippmann theory [28] the solution composition is supersaturated with respect to an intermediate composition Ca0.”
Background
The anion exchange properties of AFm (hydrocalumite-group) minerals defined from solubility experiments and crystallographic information
Appelo, C. A. J. (2020) · Cement and Concrete Research · doi:10.1016/j.cemconres.2020.106270 · Cited by 38 · see citing works
Miscibility in the CaSO4·2H2O–CaSeO4·2H2O system: Implications for the crystallisation and dehydration behaviour
González, Á. F., Andara, A., Alía, J. M., & Rubio, M. P. (2005) · Chemical Geology · doi:10.1016/j.chemgeo.2005.08.019 · Cited by 37 · see citing works
Nanoscale observations of the epitaxial growth of hashemite on barite (001)
Shtukenberg, A. G., Astilleros, J. M., & Putnis, A. (2005) · Surface Science · doi:10.1016/j.susc.2005.06.013 · Cited by 37 · see citing works
Improvement of excess parameters from thermodynamic and phase diagram data by a sequential Bayes algorithm
Königsberger, E. (1991) · Calphad · doi:10.1016/0364-5916(91)90027-h · Cited by 37 · see citing works
Characterization and Crystallization of Ba(SO<sub>4</sub>,SeO<sub>4</sub>) Solid Solution
Andara, A. J., Heasman, D. M., Fernández-González, Á., & Prieto, M. (2005) · Crystal Growth & Design · doi:10.1021/cg0497290 · Cited by 37 · see citing works
From Uranothorites to Coffinite: A Solid Solution Route to the Thermodynamic Properties of USiO4
Szenknect, S., Costin, D., Clavier, N., et al. (2013) · Inorganic Chemistry · doi:10.1021/ic400272s · Cited by 35 · see citing works
“From Glynn and Reardon (1990),36 the standard Gibbs free energy associated with the congruent dissolution reaction of a real solid solution can be expressed in terms of the standard Gibbs free energy associated with the dissolution of an ideal solid solution, ΔRG°,id with the same composition and…”
Background
Unraveling the Effects of Strontium Incorporation on Barite Growth—In Situ and Ex Situ Observations Using Multiscale Chemical Imaging
Weber, J., Bracco, J. N., Poplawsky, J. D., Ievlev, A. V., More, K. L., Lorenz, M., Bertagni, A. L., Jindra, S. A., Starchenko, V., Higgins, S. R., et al. (2018) · Crystal Growth & Design · doi:10.1021/acs.cgd.8b00839 · Cited by 35 · see citing works
The growth mechanisms of solid solutions crystallising from aqueous solutions
Pina, C. M., Putnis, A., & Astilleros, J. M. (2004) · Chemical Geology · doi:10.1016/j.chemgeo.2003.12.002 · Cited by 34 · see citing works
Henry’s and non-Henry’s law behavior of Br in simple marine systems
Siemann, M. G., & Schramm, M. (2002) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(01)00857-2 · Cited by 34 · see citing works
ChemInform Abstract: Assessment of the Radium—Barium Co‐precipitation and Its Potential Influence on the Solubility of Ra in the Near‐Field
Grandía, F., Merino, J., & Bruno, J. (2011) · ChemInform · doi:10.1002/chin.201110221 · Cited by 33 · see citing works
Ni Enrichment and Stability of Al-Free Garnierite Solid-Solutions: A Thermodynamic Approach
Galí, S., Soler, J. M., Proenza, J. A., et al. (2012) · Clays and Clay Minerals · doi:10.1346/ccmn.2012.0600203 · Cited by 33 · see citing works
“Equilibria between one solid solution and the aqueous solution were plotted in a Lippmann phase diagram (Lippmann, 1980; Glynn and Reardon, 1990; Prieto, 2009).”
Method
The aqueous dissolution kinetics of the barium/lead sulfate solid solution series at 25 and 60°C
Kornicker, W. A., Presta, P. A., Paige, C. R., et al. (1991) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(91)90053-8 · Cited by 33 · see citing works
The influence of DMSO and ether via fast-dipping treatment for a perovskite solar cell
Hwang, K.-H., Nam, S.-H., Kim, D. I., et al. (2017) · Solar Energy Materials and Solar Cells · doi:10.1016/j.solmat.2017.10.024 · Cited by 31 · see citing works
Method for the prediction of nuclear waste solution decontamination by coprecipitation of strontium ions with barium sulphate using the experimental data obtained in non-radioactive environment
Pacary, V., Barrè, Y., & Plasari, E. (2010) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2010.01.006 · Cited by 31 · see citing works
“Then thermodynamicmodelswere proposed (Lippmann, 1977; Glynn and Reardon, 1990) based on mixing properties of solid solutions, but their utility is limited to conditions near equilibrium.”
Background
Effect of ferrous iron on the nucleation and growth of CaCO 3 in slightly basic aqueous solutions
Lorenzo, F. D., Burgos-Cara, A., Ruíz-Agudo, E., Putnis, C. V., & Rubio, M. P. (2016) · CrystEngComm · doi:10.1039/c6ce02290a · Cited by 30 · see citing works
Stable Isotope Fractionation by Transport and Transformation
Druhan, J. L., Winnick, M. J., & Thullner, M. (2019) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2019.85.8 · Cited by 30 · see citing works
Lead Solubility and Mineral Structures of Coprecipitated Lead/Calcium Oxalates
McBride, M. B., Kelch, S. E., Schmidt, M. P., et al. (2019) · Environmental Science & Technology · doi:10.1021/acs.est.9b05638 · Cited by 30 · see citing works
Experimental constraints on the evaporation of partially oxidized acid-sulfate waters at the martian surface
Tosca, N. J., & McLennan, S. M. (2008) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2008.11.015 · Cited by 30 · see citing works
Hydrochemical effects of saltwater intrusion in a limestone and dolomitic limestone aquifer in Lebanon
Khadra, W. M., Stuyfzand, P. J., & van Breukelen, B. M. (2017) · Applied Geochemistry · doi:10.1016/j.apgeochem.2017.02.005 · Cited by 30 · see citing works
Calculation of individual isotope equilibrium constants for geochemical reactions
Thorstenson, D. C., & Parkhurst, D. L. (2004) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2003.11.027 · Cited by 30 · see citing works
Calculated aqueous-solution-solid-solution relations in the low-temperature system CaO-MgO-FeO-CO2-H2O
Woods, T. L., & Garrels, R. M. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90288-t · Cited by 29 · see citing works
The transformation of aragonite to Mn Ca(1 − )CO3 solid-solutions at 20 °C: An experimental study
Böttcher, M. E. (1997) · Marine Chemistry · doi:10.1016/s0304-4203(96)00096-5 · Cited by 28 · see citing works
Characterization, dissolution and solubility of cadmium–calcium hydroxyapatite solid solutions at 25 °C
Zhu, Y., Zhu, Z., Zhao, X., et al. (2016) · Chemical Geology · doi:10.1016/j.chemgeo.2016.01.004 · Cited by 28 · see citing works
The origin of sulfate mineralization and the nature of the BaSO4–SrSO4 solid-solution series in the Ain Allega and El Aguiba ore deposits, Northern Tunisia
Abidi, R., Slim‐Shimi, N., Marignac, C., et al. (2012) · Ore Geology Reviews · doi:10.1016/j.oregeorev.2012.03.003 · Cited by 27 · see citing works

Authors: Glynn, P. D., & Reardon, E. J.
ORCID: Glynn, P. D.
Venue: American Journal of Science
Publisher: American Journal of Science (AJS)
Published: 1990-02-01
Volume: 290
Issue: 2
Pages: 164-201
ISSN: 0002-9599 (ISSN-L)
DOI: 10.2475/ajs.290.2.164
OpenAlex: W1981362259
Cited by: 219
References: 0
Citations by year: 2026: 3 · 2025: 6 · 2024: 5 · 2023: 3 · 2022: 7 · 2021: 5 · 2020: 6 · 2019: 3 · 2018: 9 · 2017: 12 · 2016: 7 · 2015: 6 · 2014: 8 · 2013: 7 · 2012: 18
FWCI: 12.55
Type: journal article
Language: en
Open access: closed
Locations: American Journal of Science (publishedVersion)
Topics: Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
Physical Sciences › Engineering › Biomedical Engineering › Phase Equilibria and Thermodynamics
Physical Sciences › Materials Science › Materials Chemistry › Crystallization and Solubility Studies
Keywords: aqueous solution equilibria, thermodynamic theory, phase equilibria, chemical thermodynamics

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Solid-solution aqueous-solution equilibria; thermodynamic theory and representation

Integrity signals

Claims the paper makes

Claims other papers make about this one

Cited by

Related

Record

About these checks