Description of input and examples for PHREEQC version 3: A computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations
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Chapter 43 of Section A, Groundwater Book 6, Modeling Techniques 1 0 320 seconds Distance, in centimeters Distance, in centimeters 10 10 5 0 0 5 0 Cerium(4), in millimoles per liter Cover Techniques and Methods 6-A43 U.S. Department of the Interior U.S
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The minteq.v4.dat database shows a log_Ksp of −10.58, while the phreeqc.dat database has a log_Ksp of −11.13 for rhodochrosite.
“For instance, whereas the minteq.v4.dat database [36] showed a log_Ksp of − 10.58, the phreeqc.dat database had a log_Ksp of − 11.13 [21, 37].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [21]
The Introduction (p. 9) describes the supplied databases as compilations of equilibrium constants, and the Description of Data Input (p. 23) explains how log K is defined. Neither passage gives a rhodochrosite value; searches for “rhodochrosite,” “MnCO3,” and “−11.13” found no value in our truncated copy. The −10.58 value is attached to a different citation in the citing sentence. (LLM, conf=0.72)
Experimental — accuracy not yet measuredThe minteq.v4.dat and phreeqc.dat databases show a log_Ksp of −8.48 for CaCO3.
“For instance, both the minteq.v4.dat database and the phreeqc.dat database showed a log_Ksp of − 8.48 [21, 36, 37].”
From Dissolution and solubility of calcite-rhodochrosite solid solutions [(Ca1-xMnx)CO3] at 25 °C (2021) · cites this paper as [21]
The Capabilities of PHREEQC Version 3 section identifies phreeqc.dat and minteq.v4.dat as databases, and Description of Data Input (p. 23) explains how log K values are defined. Neither passage, nor the additional searches for −8.48 and calcite solubility, gives a CaCO3 log Ksp value for either database. Our copy is truncated, so the claimed value cannot be verified from it. (LLM, conf=0.74)
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“2) [21], and then the ion activity products (IAPs) were calculated after the definitions, which equaled the solubility products (Ksp) of the (Ca1-xMnx)CO3 solid solutions at equilibrium.”
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- Authors
- Parkhurst, D. L., & Appelo, C. A. J.
- Affiliations
- United States Geological Survey (US)
- ORCID
- Parkhurst, David L.
- Venue
- Techniques and Methods
- Publisher
- US Geological Survey
- Published
- 2013
- ISSN
- 2328-7047 (ISSN-L)
- 2328-7055
- OpenAlex
- W1251722559
- Cited by
- 3,779
- References
- 61
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- Type
- report
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Techniques and methods (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Groundwater and Isotope Geochemistry
- Physical Sciences › Environmental Science › Environmental Engineering › Groundwater flow and contamination studies
- Physical Sciences › Environmental Science › Water Science and Technology › Water Quality and Resources Studies
- Keywords
- PHREEQC, speciation calculations, one-dimensional transport, hydrogeochemistry, input file format, cerium(IV)
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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