Cited by 73Thermochemical Biomass Conversion ProcessesAdsorption and biosorption for pollutant removalSoil Carbon and Nitrogen Dynamics

The Effect of Biodegradable Waste Pyrolysis Temperatures on Selected Biochar Properties

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Wystalska, Katarzyna, Kwarciak-Kozłowska, Anna·2021·Materials

Abstract

Biochars produced during biodegradable waste pyrolysis are products with a wide range of environmental applications. The effect of impact biochars depends on their properties which determine the course of specific processes. The main aim of the study was to investigate the effect of pyrolysis temperature on selected properties of biochar produced from various plant wastes (beech wood chips, walnut shells, wheat-rye straw), the valorization of which is of key importance for the implementation of the circular economy. Biochars were produced at temperatures of: 400 °C, 500 °C, 600 °C and 700 °C in a nitrogen atmosphere. An increase in the pyrolysis temperature caused a drop in the biochar production yield. As the temperature increased, higher carbon content and lower hydrogen content could be seen in the products obtained. An increase in the pH and total organic carbon (TOC) values also found. The influence of temperature on ash content, observed in the case of BWS (biochar from walnut shell) and BWRS (biochar from wheat and rye straw), did not occur in the case of BWC (biochar from beech wood chips). Another parameter that demonstrated a growing tendency with increasing temperature was the BET specific surface area (except for biochars from wheat and rye straw). An increase in pyrolysis temperature caused a decrease in the diversity and density of the surface functional groups of biochars. The influence of the type of precursor used in the production of biochar on the presence of surface functional groups was demonstrated. The presence of intense stretching vibrations of C–O bonds, having a potential impact on the sorption capacity of biochars, was determined in the FTIR spectra of BWC600 and BWC700 biochars, this feature, combined with the large BET surface area, may affect the sorption potential of these biochars. The presence of this type of high-intensity vibrations was also observed in the spectra of biochar BWRS600 and BWRS700. This can compensate for the low BET surface value and play an important role when using these biochars in sorption processes for organic and inorganic compounds.

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  • Increasing pyrolysis temperature to 800 °C drove further deoxygenation and dehydrogenation, with Van Krevelen parameters H/C = 0.21 and O/C = 0.05.

    “Increasing pyrolysis temperature to 800 • C via B800 drove further deoxygenation and dehydrogenation, with Van Krevelen parameters (H/C = 0.21; O/C = 0.05) confirming heightened aromaticity and carbon enrichment [69,70].”

    From Pilot-Scale Slow Pyrolysis, Post-Heat Treatment, and Self-Heating Performance of Biochar Fuels Derived from Construction, Renovation, and Demolition (CRD) Wood Waste (2026) · cites this paper as [70]

    The Conclusions report that increasing temperature raised carbon content and lowered hydrogen content, and Results §3.2 links a falling H/C ratio to increased aromaticity. But Methods §2.2 lists pyrolysis temperatures only up to 700 °C. The paper therefore does not support the claimed B800 result or its H/C = 0.21 and O/C = 0.05 values; page numbers are unavailable in our copy. (LLM, conf=0.89)

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Research works printed but not linked: 6

  1. [15]Malińska K. Dach J. Biochar as a supplementary material for biogas production Ecol. Eng. 2015 41 117 124 (In Polish) 10.12912/23920629/1835 · DOI
  2. [46]Franciski M.A. Peres E.C. Godinho M. Perondi D. Foletto E.L. Collazzo G.C. Dotto G.L. Development of CO2 activetd biochar from solid waste of a beer industry and its application for methylene blue adsorption Waste Manag. 2018 78 630 638 10.1016/j.wasman.2018.06.040 32559954 · DOI
  3. [61]Shoi S. Lopez-Capel E. Krull E. Bol R. Biochar climate and soil, A review to guide future research CSIRO Land Water Sci. Rep. 2009 5 1 59
  4. [63]Dai Y. Zhang N. Chuanming X. Cui Q. Sun Q. The adsorption, regeneration and engineering application of biochar for removal organic pollutants Chemosphere 2019 223 12 27 10.1016/j.chemosphere.2019.01.161 30763912 · DOI · Paper page
  5. [77]Rittl T.F. Butterbach-Bahl K. Basile C.M. Pereira L.A. Alms V. Dannenmann M. Couto E.G. Ceri C.E.P. Greenhouse gas emissions from soil amended with agricultural residua biochars: Effects of feedstock type, production temperature and soil moisture Biomass Bioenergy 2017 117 1 9 10.1016/j.biombioe.2018.07.004 · DOI · Paper page
  6. [87]EBC European Biochar Certificate—Guidelines for Sustainable Production of Biochar. European Biochar Foundation EBC Arbaz, Switzerland 2012 Available online: http://www.european-biochar.org/en/download (accessed on 30 August 2018) 10.13140/RG.2.1.4658.7043 · DOI

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Authors
Wystalska, K., & Kwarciak-Kozłowska, A.
Affiliations
  • Częstochowa University of Technology (PL)
  • Faculty of Infrastructure and Environment, Czestochowa University of Technology, 42-200 Czestochowa, Poland
Corresponding author
Wystalska, Katarzyna
Venue
Materials
Publisher
MDPI AG
Published
2021-03-27
Volume
14
Issue
7
Pages
1644
ISSN
1996-1944 (ISSN-L)
OpenAlex
W3143371710
Cited by
73
References
96
Citations by year
2026: 26 · 2025: 15 · 2024: 13 · 2023: 6 · 2022: 9 · 2021: 4
FWCI
2.43
Type
journal article
Language
en
Open access
Locations
  • Materials (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Topics
  • Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
  • Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
  • Life Sciences › Agricultural and Biological Sciences › Soil Science › Soil Carbon and Nitrogen Dynamics
Keywords
biochar, pyrolysis temperature, biodegradable waste, walnut shell, carbon content, ash content, BET surface area, surface functional groups, C-O bond, sorption capacity, total organic carbon, pH, circular economy, biomass valorization

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