The Effect of Biodegradable Waste Pyrolysis Temperatures on Selected Biochar Properties
Open accessAbstract
Biochars produced during biodegradable waste pyrolysis are products with a wide range of environmental applications. The effect of impact biochars depends on their properties which determine the course of specific processes. The main aim of the study was to investigate the effect of pyrolysis temperature on selected properties of biochar produced from various plant wastes (beech wood chips, walnut shells, wheat-rye straw), the valorization of which is of key importance for the implementation of the circular economy. Biochars were produced at temperatures of: 400 °C, 500 °C, 600 °C and 700 °C in a nitrogen atmosphere. An increase in the pyrolysis temperature caused a drop in the biochar production yield. As the temperature increased, higher carbon content and lower hydrogen content could be seen in the products obtained. An increase in the pH and total organic carbon (TOC) values also found. The influence of temperature on ash content, observed in the case of BWS (biochar from walnut shell) and BWRS (biochar from wheat and rye straw), did not occur in the case of BWC (biochar from beech wood chips). Another parameter that demonstrated a growing tendency with increasing temperature was the BET specific surface area (except for biochars from wheat and rye straw). An increase in pyrolysis temperature caused a decrease in the diversity and density of the surface functional groups of biochars. The influence of the type of precursor used in the production of biochar on the presence of surface functional groups was demonstrated. The presence of intense stretching vibrations of C–O bonds, having a potential impact on the sorption capacity of biochars, was determined in the FTIR spectra of BWC600 and BWC700 biochars, this feature, combined with the large BET surface area, may affect the sorption potential of these biochars. The presence of this type of high-intensity vibrations was also observed in the spectra of biochar BWRS600 and BWRS700. This can compensate for the low BET surface value and play an important role when using these biochars in sorption processes for organic and inorganic compounds.
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Increasing pyrolysis temperature to 800 °C drove further deoxygenation and dehydrogenation, with Van Krevelen parameters H/C = 0.21 and O/C = 0.05.
“Increasing pyrolysis temperature to 800 • C via B800 drove further deoxygenation and dehydrogenation, with Van Krevelen parameters (H/C = 0.21; O/C = 0.05) confirming heightened aromaticity and carbon enrichment [69,70].”
From Pilot-Scale Slow Pyrolysis, Post-Heat Treatment, and Self-Heating Performance of Biochar Fuels Derived from Construction, Renovation, and Demolition (CRD) Wood Waste (2026) · cites this paper as [70]
The Conclusions report that increasing temperature raised carbon content and lowered hydrogen content, and Results §3.2 links a falling H/C ratio to increased aromaticity. But Methods §2.2 lists pyrolysis temperatures only up to 700 °C. The paper therefore does not support the claimed B800 result or its H/C = 0.21 and O/C = 0.05 values; page numbers are unavailable in our copy. (LLM, conf=0.89)
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BackgroundGutiérrez, M., Siles, J. A., Diz, J., Chica, A., & Martín, M. A. (2017) · Waste Management · doi:10.1016/j.wasman.2016.09.045 · Cited by 54
Mia, S., Uddin, M. E., Kader, M. A., Ahsan, A., Mannan, M. A., Hossain, M. M., & Solaiman, Z. M. (2018) · Waste Management · doi:10.1016/j.wasman.2018.01.038 · Cited by 54 · see citing works
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“These groups are of large importance for the formation of organometallic complexes immobilizing heavy metals in soil (Pb (II), Cu (II), Ni (II) and Cd (II)) [9,41,92].”
BackgroundGiudicianni, P., Pindozzi, S., Grottola, C. M., Stanzione, F., Faugno, S., Fagnano, M., Fiorentino, N., & Ragucci, R. (2017) · Waste Management · doi:10.1016/j.wasman.2017.01.031 · Cited by 50 · cited 7× · see citing works
“(2017) [60] achieved a wide specific surface range for biochars produced from plant biomass, which, however, had been earlier subject to the impact of steam.”
BackgroundResultInfluentialClosing nutrient cycles with biochar- from filtration to fertilizer
Barber, S. T., Yin, J., Draper, K., & Trabold, T. A. (2018) · Journal of Cleaner Production · doi:10.1016/j.jclepro.2018.06.136 · Cited by 43 · cited 1× · see citing works
“These products could be incorporated into the environmental cycle while, at the same time, closing the nutrient cycles [6].”
BackgroundThe Use of Biochar for the Production of Organic Fertilizers
Czekała, W., Jeżowska, A., & Chełkowski, D. (2019) · Journal of Ecological Engineering · doi:10.12911/22998993/93869 · Cited by 38 · cited 1× · see citing works
“Biochars can be used as additives improving soil properties [33–35], reducing [36] the bioavailability of contaminants [37], enhancing plant growth and yield [33,34], and affecting the mobility of heavy metals [8,38–42] and their accumulation in plant biomass [43].”
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“These groups are of large importance for the formation of organometallic complexes immobilizing heavy metals in soil (Pb (II), Cu (II), Ni (II) and Cd (II)) [9,41,92].”
BackgroundWystalska, K., Malińska, K., Włodarczyk, R., & Chajczyk, O. (2018) · doi:10.1051/e3sconf/20184400197 · Cited by 18
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“, CH2 and CH3), present in aliphatic compounds [49], was observed in the case of biochar produced at any temperature (400, 500, 600, 700 °C) in the range of approximately 3032–2915 cm−1 of the FTIR spectrum (Figure 4).”
BackgroundMolenda, J., Swat, M., & Osuch-Słomka, E. (2018) · Engineering and Protection of Environment · doi:10.17512/ios.2018.3.7 · Cited by 11 · cited 3×
“The signals observed, corresponding to the wave number in the range of approximately 1576 cm−1, might be related to the vibrations of the C=C grouping in an aromatic ring, coupled with the C=O carbonyl group [91]; this could indicate the generation of products with their structure containing an organooxygen structural…”
BackgroundInfluentialCharacterization of bio char derived from tapioca skin
Hasnan, F., Iamail, K. N., Musa, M., Jaapar, J., Alwi, H., & Hamid, K. (2018) · IOP Conference Series Materials Science and Engineering · doi:10.1088/1757-899x/334/1/012016 · Cited by 8 · see citing works
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Xiang, L., Harindintwali, J. D., Wang, F., Redmile-Gordon, M. A., Chang, S. X., Fu, Y., He, C., Muhoza, B., Brahushi, F., Bolan, N. S., et al. (2022) · Environmental Science & Technology · doi:10.1021/acs.est.2c02976 · Cited by 460 · see citing works
Impact of pyrolysis process conditions on the structure of biochar obtained from apple waste
Barszcz, W., Łożyńska, M., & Molenda, J. (2024) · Scientific Reports · doi:10.1038/s41598-024-61394-8 · Cited by 124 · see citing works
“H bond 48–50 .”
Enhancing the Potential of Polymer Composites Using Biochar as a Filler: A Review
Aboughaly, M., Babaei‐Ghazvini, A., Dhar, P., Patel, R., & Acharya, B. (2023) · Polymers · doi:10.3390/polym15193981 · Cited by 116 · see citing works
“Therefore, optimal charring temperatures and residence times should be specified to produce biochar with high intra-porosity [155].”
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Adsorption of vanadium (V) ions from the aqueous solutions on different biomass-derived biochars
Kończyk, J., Kluziak, K., & Kołodyńska, D. (2022) · Journal of Environmental Management · doi:10.1016/j.jenvman.2022.114958 · Cited by 68 · see citing works
Acclimatized activated sludge for enhanced phenolic wastewater treatment using pinewood biochar
Kamali, M., Aminabhavi, T. M., Tarelho, L. A. C., Hellemans, R., Cuypers, J., Capela, I., Costa, M. E. V., Dewil, R., & Appels, L. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131708 · Cited by 67 · see citing works
A Thermogravimetric Analysis of Biomass Conversion to Biochar: Experimental and Kinetic Modeling
Călin, C., Sȋrbu, E.-E., Tănase, M., Győrgy, R., Popovici, D. R., & Banu, I. (2024) · Applied Sciences · doi:10.3390/app14219856 · Cited by 41 · see citing works
The emerging role of biochar in the carbon materials family for hydrogen production
Bhakta, A. K., Fiorenza, R., Jlassi, K., Mekhalif, Z., Ali, A. M. A., & Chehimi, M. M. (2022) · Process Safety and Environmental Protection · doi:10.1016/j.cherd.2022.09.028 · Cited by 36 · see citing works
Physical-Chemical Characterization of Different Carbon-Based Sorbents for Environmental Applications
Marzeddu, S., Décima, M. A., Camilli, L., Bracciale, M. P., Genova, V., Paglia, L., Marra, F., Damizia, M., Stoller, M., Chiavola, A., et al. (2022) · Materials · doi:10.3390/ma15207162 · Cited by 35 · see citing works
“1%, 1%, 5%, and 10% by mass) were added to 45 mL of ultrapure water at a known initial pH: as the quantity of carbonaceous material increases, the equilibrium pH of the solution tends progressively to an asymptotic value, which is, in fact, the point of zero charges (pHPZC) [98,99].”
BackgroundTannery waste-derived biochar as a carrier of micronutrients essential to plants
Skrzypczak, D., Szopa, D., Mikula, K., Izydorczyk, G., Baśladyńska, S., Hoppe, V., Pstrowska, K., Wzorek, Z., Kominko, H., Kułażyński, M., et al. (2022) · Chemosphere · doi:10.1016/j.chemosphere.2022.133720 · Cited by 38 · see citing works
Functionalized biochar from waste as a slow-release nutrient source: Application on tomato plants
Rosa, D., Petruccelli, V., Iacobbi, M. C., Brasili, E., Badiali, C., Pasqua, G., & Palma, L. D. (2024) · Heliyon · doi:10.1016/j.heliyon.2024.e29455 · Cited by 32 · see citing works
“Additionally, hydrogen (H), oxygen (O), and inorganic mineral substances evaporation contribute to an increase in specific surface area and pores formation resulting in a porous structure in biochar, as reported by several authors [57 – 59].”
BackgroundVeeramalai, S., Ramlee, N. N., Mahdi, H. I., Manas, N. H. A., Ramli, A. N. M., Illias, R. M., & Azelee, N. I. W. (2022) · Industrial Crops and Products · doi:10.1016/j.indcrop.2022.114823 · Cited by 39 · see citing works
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“According to the research, a higher temperature of pyrolysis leads to an increase of specific surface area, which subsequently results in increased levels of water absorption in soil [28,37].”
BackgroundEfficient copper removal using low-cost H3PO4 impregnated red-gram biochar-MnO2 nanocomposites
Siddiqui, S., Bhatnagar, P., Sireesha, S., Sopanrao, K. S., & Sreedhar, I. (2022) · Bioresource Technology Reports · doi:10.1016/j.biteb.2022.101304 · Cited by 17 · see citing works
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“Biochar is a C-rich solid product generated through the thermal decomposition of biomass, a process governed by key factors such as pyrolysis temperature, residence time, and feedstock composition 29–31 .”
Chebbi, M., Ounoki, S., Youcef, L., Chergui, F. N., & Amrane, A. (2024) · Sustainable Chemistry and Pharmacy · doi:10.1016/j.scp.2024.101565 · Cited by 15 · see citing works
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“It means that it is less prone to breakdown or thermal degradation when it is exposed to high temperatures in subsequent applications (Wystalska and Kwarciak-Kozłowska 2021).”
BackgroundMoussa, O., & makkawi, Y. T. (2026) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2026.108928 · Cited by 13 · see citing works
Exploring Biochar Briquettes from Biomass Waste for Sustainable Energy
Heriyanti, A. P., Bakri, S. N. S., Jabbar, A., Kholil, P. A., Amelia, R. N., Savitri, E. N., Rifa'atunnisa, Dewi, S. H., & Sultan, H. (2025) · Advance Sustainable Science, Engineering and Technology · doi:10.26877/7mhm6t05 · Cited by 9
“Pyrolysis Conditions : The biomass was carbonized in a furnace under limited oxygen conditions at 500°C for 4 hours [31].”
Enhancing denitrifying anaerobic methane oxidation for nitrogen removal with low-temperature biochar
Chong, W., Wang, S., Cheng, J., Lou, X., Wan, X., Sun, X., Wang, M., Kuang, S., Chen, H., & Liu, S. (2025) · Bioresource Technology · doi:10.1016/j.biortech.2025.132322 · Cited by 9 · see citing works
Adsorption Properties of Fishbone and Fishbone-Derived Biochar for Cadmium in Aqueous Solution
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“Lower temperatures (300–400 °C) favor higher yield and functional groups, while higher temperatures (500–700 °C) enhance carbonization and surface area 33,34 .”
Wystalska, K., Kowalczyk, M., Kamizela, T., Worwąg, M., & Zabochnicka-Świątek, M. (2024) · Materials · doi:10.3390/ma17112646 · Cited by 3 · see citing works
“Bonds of this type are usually broken down during the process carried out at temperatures of 600 ◦ C and higher, which results in the loss of this type of structure in pyrolysis products [28,78].”
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“Wystalska and Kwarciak-Kozlowska (2021) found that the higher pyrolysis temperature will make the surface area of the sample greater [22].”
BackgroundCavitated Charcoal—An Innovative Method for Affecting the Biochemical Properties of Soil
Gondek, K., Mierzwa–Hersztek, M., Grzymala, W., Głąb, T., & Bajda, T. (2021) · Materials · doi:10.3390/ma14092466 · Cited by 3 · see citing works
“Their effect is also conditioned by, among others, the type of feedstock, production conditions, material rate, location of tests and the type of plant cultivated [2,15,16].”
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“…to the cereal-based tarhana dough— have been pyrolysed at 400, 500, 600 and 700 °C; at 400– 500 °C, the resulting biochars show a useful compromise between yield, increasing carbon content, rising pH and the gradual development of surface area (Wystalska and Kwarciak-Kozłowska 2021).”
Potential Application of Ferrate-Modified Commercial Biochar to Control Ammonia and Hydrogen Sulfide
Kim, Y., & Kim, S.-H. (2026) · Applied Sciences · doi:10.3390/app16105140 · Cited by 1
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“Similarly, Wystalska & Kwarciak-Kozłowska [41] observed that increasing pyrolysis temperature across multiple lignocellulosic feedstocks resulted in a marked increase in soil surface area due to intensified devolatilization and pore formation mechanisms.”
Collins, B. A., Birzer, C. H., Kidd, S. P., Hall, T., & Medwell, P. R. (2025) · Bioresource Technology Reports · doi:10.1016/j.biteb.2025.102219 · Cited by 1 · see citing works
Removal of Bunker Oil in Contaminated Seawater Using Biochar from Chicken Bones Via Slow Pyrolysis
Decembrano, K. M., Hamor, M. A. K., Sison, D., Binay, J. D., Roque, E. C., Rubi, R. V. C., & Olay, J. G. (2024) · IOP Conference Series Materials Science and Engineering · doi:10.1088/1757-899x/1318/1/012026 · Cited by 1 · see citing works
Modeling the kinetics of pyrolysis of date seeds using artificial neural networks
Felobes, R. A., & Abadir, M. F. (2024) · Renewable Energy and Sustainable Development · doi:10.21622/resd.2024.10.1.811 · Cited by 1 · see citing works
“Its use as adsorbing material necessitates, however, increasing the temperature to more than 600 o C to ensure the formation of enough porosity to allow for its use to that aim [54].”
Agbebunmi, T., Kisiela-Czajka, A. M., Czajka, K., & Michalak, I. (2026) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2026.109452 · Cited by 1 · see citing works
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Enhanced Diclofenac Removal From Aqueous Solution Using Activated Betel Nut Husk Biochar
Arya, S., Kamble, R. T., Remya, N., & Sujana, M. G. (2026) · ChemistrySelect · doi:10.1002/slct.74560
Catalytic and Non-Catalytic Pyrolysis of Pine Wood Residues: A Temperature-Based Study
Mammadova, T., Ahmadova, G., Aliyeva, N., & Mammadova, E. (2026) · Periodica Polytechnica: Chemical Engineering · doi:10.3311/ppch.43653
“Lignin is the most ther - mally stable component of biomass and decomposes over a broader temperature range than cellulose and hemicel - lulose, thereby contributing significantly to char forma - tion [88–91].”
Click-Functionalized Biochar as a Spacer-Engineered Interface for Electrochemical Biosensing
Licheri, A., Mattarelli, V., Bartolucci, L., Cancelliere, R., Mazzuca, C., Mele, P., Orlanducci, S., Micheli, L., & Salvio, R. (2026) · ACS Omega · doi:10.1021/acsomega.6c01575
Kaiaidarova, A. K., Bobrova, V., Kasperovich, A., Lezhnev, S. N., Panin, E., Nechipurenko, S., & Efremov, S. (2026) · Polymers · doi:10.3390/polym18161967
“However, in a study [107], as the pyrolysis temperature increased from 400 to 700 ◦ C for beech wood chips, walnut shells, and wheat straw, there was a decrease in the intensity of the C=C bond valence vibration signals, which was attributed to the fact that high temperatures can lead to the…”
InfluentialSharma, A., Shivanna, J. M., Rujiralai, T., & Hegde, G. (2026) · Biomass Conversion and Biorefinery · doi:10.1007/s13399-026-07241-4 · Cited by 1 · see citing works
Date Palm Fronds and Chicken Manure Biochar with Carbon Nanotubes for Capacitive Deionization
Kyaw, H. H., Jellali, S., Al-Abri, M. Z., Al-Raeesi, A., Al-Wardy, M., & Myint, M. T. Z. (2026) · Water · doi:10.3390/w18151808
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Bianasari, A. A., Bakar, M. S. A., Khaled, M. S., Saepurahman, S., Mansur, D., & Азад, А. К. (2025) · International Journal of Renewable Energy Development · doi:10.61435/ijred.2026.61234 · Cited by 1 · see citing works
“Previous studies indicate that higher pyrolysis temperatures result in a decrease in the yield of bio-char formation (Devi, 2014; Mujtaba et al., 2023; Wystalska & Kwarciak-Kozłowska, 2021) .”
Wahyuni, T., Purwantana, B., Ngadisih, Martini, T., Susilawati, H. L., Meidaliyantisyah, M., Dewi, R. E. P., Maftukhah, R., Keiblinger, K. M., & Sasongko, N. A. (2025) · IOP Conference Series Earth and Environmental Science · doi:10.1088/1755-1315/1469/1/012035
- Authors
- Wystalska, K., & Kwarciak-Kozłowska, A.
- Affiliations
- Częstochowa University of Technology (PL)
- Faculty of Infrastructure and Environment, Czestochowa University of Technology, 42-200 Czestochowa, Poland
- Corresponding author
- Wystalska, Katarzyna
- Venue
- Materials
- Publisher
- MDPI AG
- Published
- 2021-03-27
- Volume
- 14
- Issue
- 7
- Pages
- 1644
- ISSN
- 1996-1944 (ISSN-L)
- PMC
- PMC8037663
- OpenAlex
- W3143371710
- Cited by
- 73
- References
- 96
- Citations by year
- 2026: 26 · 2025: 15 · 2024: 13 · 2023: 6 · 2022: 9 · 2021: 4
- FWCI
- 2.43
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Materials (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Life Sciences › Agricultural and Biological Sciences › Soil Science › Soil Carbon and Nitrogen Dynamics
- Keywords
- biochar, pyrolysis temperature, biodegradable waste, walnut shell, carbon content, ash content, BET surface area, surface functional groups, C-O bond, sorption capacity, total organic carbon, pH, circular economy, biomass valorization
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