Effects of pyrolysis temperature on soybean stover-and peanut shell-derived biochar properties and TCE adsorption in water
Abstract
Conversion of crop residues into biochars (BCs) via pyrolysis is beneficial to environment compared to their direct combustion in agricultural field. Biochars developed from soybean stover at 300 and 700 °C (S-BC300 and S-BC700, respectively) and peanut shells at 300 and 700 °C (P-BC300 and P-BC700, respectively) were used for the removal of trichloroethylene (TCE) from water. Batch adsorption experiments showed that the TCE adsorption was strongly dependent on the BCs properties. Linear relationships were obtained between sorption parameters (K(M) and S(M)) and molar elemental ratios as well as surface area of the BCs. The high adsorption capacity of BCs produced at 700 °C was attributed to their high aromaticity and low polarity. The efficacy of S-BC700 and P-BC700 for removing TCE from water was comparable to that of activated carbon (AC). Pyrolysis temperature influencing the BC properties was a critical factor to assess the removal efficiency of TCE from water.
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High pyrolysis temperature leads to increased biochar surface area, higher pH, and higher %C content but lower %N content.
“Numerous studies reported that high pyrolysis temperature led to increased biochar surface area (Ahmad et al., 2012; Zhang et al., 2015), higher pH (Hossain et al., 2011), %C content but lower %N content (Zhang et al., 2017).”
From Effect of Pyrolysis Temperature on PhysicoChemical Properties and Acoustic-Based Amination of Biochar for Efficient CO2 Adsorption (2020) · cites this paper as Ahmad et al., 2012
Surface area increases during pyrolysis due to decomposition of cellulose and hemicelluloses, and formation of channel structures.
“Surface area increases during pyrolysis due to the decomposition of cellulose and hemicelluloses, and the formation of channel structures”
From Biochar physicochemical properties: pyrolysis temperature and feedstock kind effects (2020) · cites this paper as Ahmad et al. 2012
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- Authors
- Ahmad, M., Lee, S. S., Dou, X., Mohan, D., Sung, J.-K., Yang, J. E., & Ok, Y. S.
- Affiliations
- Kangwon National University (KR)
- Beijing Forestry University (CN)
- Jawaharlal Nehru University (IN)
- National Academy of Agricultural Science (KR)
- Corresponding author
- Ok, Yong Sik
- Venue
- Bioresource Technology
- Publisher
- Elsevier BV
- Published
- 2012-08
- Volume
- 118
- Pages
- 536-544
- ISSN
- 0960-8524 (ISSN-L)
- OpenAlex
- W2031493035
- Cited by
- 1,357
- References
- 37
- Citations by year
- 2026: 76 · 2025: 119 · 2024: 133 · 2023: 122 · 2022: 152 · 2021: 161 · 2020: 135 · 2019: 101 · 2018: 86 · 2017: 89 · 2016: 58 · 2015: 71 · 2014: 31 · 2013: 19 · 2012: 3
- FWCI
- 35.96
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Bioresource Technology (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Ministry of Environment, Republic of Korea (173-092-010)
- National Research Foundation of Korea (2009-0071439)
- Topics
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Physical Sciences › Engineering › Biomedical Engineering › Thermochemical Biomass Conversion Processes
- Keywords
- biochar, pyrolysis temperature, peanut shell, trichloroethylene, water treatment, adsorption isotherms, biochar surface area, aromaticity, activated carbon comparison
- MeSH terms
- Adsorption, Biodegradation, Environmental, Charcoal, Elements, Hydrogen-Ion Concentration, Kinetics, Arachis, Glycine max, Surface Properties, Temperature, Trichloroethylene, Waste Products, Water, Water Pollutants, Chemical, Water Purification
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