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Cited by 546biodegradable polymer synthesis and propertiesAdvanced Polymer Synthesis and CharacterizationPolymer crystallization and properties

Handbook of Ring‐Opening Polymerization

·2009·Wiley eBooks
DOI 10.1002/9783527628407
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Abstract

THERMODYNAMICS AND KINETICS OF RING-OPENING POLYMERIZATION Introduction Thermodynamics of the Ring-Opening Polymerization Kinetics of Ring-Opening Polymerization GENERAL MECHANISMS IN RING-OPENING POLYMERIZATION Introduction Anionic Ring-Opening Polymerization Cationic Ring-Opening Polymerization Radical Ring-Opening Polymerization SILOXANE-CONTAINING POLYMERS Introduction Polydimethylsiloxanes Functional Silicones Polycarbosiloxanes SULFUR-NITROGEN-PHOSPHOROUS-CONTAINING POLYMERS Introduction Mechanism and Methods in Ring-Opening Polymerization (ROP) of Halogenated Cyclotriphosphazanes Ring-Opening Polymerization and Chemistry of Nonhalogenated Phosphazane Rings Incorporation of Sulfur into Phosphazane Ring Systems and Their Polymerization Chemistry POLYMERIZATION OF CYCLIC DEPSIPEPTIDES, UREAS AND URETHANES Introduction Polydepsipeptides Monomers Ring-Opening Polymerization Enzymatic Polymerization Ring Expansion Polyureas Polyurethanes POLYETHERS AND POLYOXAZOLINES Introduction Polyethers Polyoxazolines POLYAMIDES Introduction Mechanism of the Anionic Polymerization of Lactams Initiators for the Anionic Polymerization of Lactams Activators for Anionic Polymerization of Lactams Nonactivated Polymerization Cyclic Oligomers of Epsilon-Caprolactam Block Copolymers of Lactams Anionic Copolymerization of Epsilon-Caprolactam with Omega-Laurolactam Copolymerization of Lactams with Lactones (Epsilon-Caprolactone) Powdered Polyamide Nanocomposites Anionic Polymerization of 2-Pyrrolidone RING-OPENING METATHESIS POLYMERIZATION General Introduction Introduction to Ring-Opening Metathesis Polymerization (ROMP) Well-Defined Catalysts for ROMP 'Living? ROMP Selected Recent Applications and Developments POLYESTERS FROM BETA-LACTONES Introduction Beta-Lactones Preparation Ionic Polymerization Coordination Process Carbene-Based Polymerization Enzymatic Polymerization Illustrative Experimental Section POLYESTERS FROM DILACTONES Introduction General Concepts and ROP Promoted by Metallic Recent Advances in ROP Macromolecular Engineering Applications POLYESTERS FROM LARGE LACTONES Introduction Controlled Synthesis of Linear Polyesters Physical Properties of Polymers POLYCARBONATES Introduction Polymerization of Cyclic Carbonates: Homopolymers and Block Copolymers POLYMERIZATION OF CYCLOALKANES Introduction General Overview and Thermodynamic Requirements Structure-Reactivity Relationships Based on a Comprehensive Survey of the Current Literature METAL-FREE CATALYSIS IN RING-OPENING POLYMERIZATION Introduction Nucleophilic ROP Metal-Free Ionic ROP ENZYME-MEDIATED RING-OPENING POLYMERIZATION Introduction Characteristics of Enzymatic ROP Classes of Monomer Polymer Architectures Employing Enzymatic ROP

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  • For most ring-opening polymerizations, the driving force is ring strain and associated steric considerations rather than conversion of a multiple to a single bond.

    “for most ROP the driving force is the ring strain and associated steric considerations.”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [1]

  • Ring chain equilibrium leads to a considerable influence of initial monomer concentration and temperature on the microstructure of ROP products.

    “there is the consideration of the ring chain equilibrium, which leads to the considerable influence of the initial monomer concentration and temperature on the microstructure of the products.”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [1]

  • RROP offers novel routes to polyesters and polyketones, particularly using vinyl substituted cyclic monomers.

    “RROP offers novel routes to polyesters and polyketones particularly using vinyl substituted cyclic monomers (see Section 2.2) [6].”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [6]

  • For the propagation step of D4 AROP, ΔHp is approximately 0 kJ mol-1, but due to increased rotational freedom of the side chains ΔSp is +6.7 J mol-1, so polymerization does occur.

    “For the propagation step the Δ H p ≈ 0 kJ mol -1 , but due to the increased rotational freedom of the side chains the Δ S p = +6.7 J mol -1 polymerization does occur.”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [119]

  • Cyclic siloxanes can undergo ROP via anionic intermediates employing alkali metal oxides or hydroxides as initiators.

    “Cyclic siloxanes can also undergo ROP via anionic intermediates employing alkali metal oxides or hydroxides as initiators [119].”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [119]

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Venue
Wiley eBooks
Publisher
Wiley
Published
2009-01-28
DOI
10.1002/9783527628407
OpenAlex
W600467921
Cited by
544
References
0
Citations by year
2026: 11 · 2025: 20 · 2024: 33 · 2023: 20 · 2022: 30 · 2021: 34 · 2020: 38 · 2019: 43 · 2018: 48 · 2017: 40 · 2016: 42 · 2015: 38 · 2014: 35 · 2013: 35 · 2012: 29
FWCI
15.15
Type
book
Language
en
Open access
closed
Licence
doi.wiley.com/10.1002/tdm_license_1.1 (tdm)
Locations
  • Wiley eBooks (publishedVersion)
  • PolyPublie (École Polytechnique de Montréal) (submittedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
Keywords
ring-opening polymerization, ring-opening metathesis polymerization, anionic polymerization, cationic polymerization, radical polymerization, lactam polymerization, caprolactam, cyclic depsipeptides, urethane, polyesters, β-lactones, dilactones, cyclic carbonates, polyoxazoline, polyethers, siloxane-containing polymers, enzymatic polymerization, block copolymers, macromolecular engineering

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