Cited by 220biodegradable polymer synthesis and propertiesPolymer composites and self-healingAdvanced Polymer Synthesis and Characterization

Design principles for intrinsically circular polymers with tunable properties

Open access
Shi, Changxia, Reilly, Liam T., Phani Kumar, V. Sai, Coile, Matthew W., Nicholson, Scott R., Broadbelt, Linda J., Beckham, Gregg T., Chen, Eugene Y.-X.·2021·Chem

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Integrity signals

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Crossref · 10.1016/j.chempr.2021.10.004

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81 of 83 references verified0 citation errors · 0 not checkable

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  • Complete depolymerization back to monomer maximizes the number of chemical bonds that must be broken and reformed during recycling, necessitating extreme reaction efficiency and increased energy inputs.

    “the complete depolymerization back to monomer maximizes the number of chemical bonds that must be broken and reformed during the recycling process, necessitating extreme reaction efficiency and increased energy inputs”

    From Chemically recyclable polyolefin-like multiblock polymers (2023) · cites this paper as [14]

    The Perspective (p. 3) says intrinsically circular polymers can be completely deconstructed to monomer by catalysis through a low-energy pathway. It also describes minimizing the energy required for depolymerization under mild conditions. The paper does not state that complete depolymerization maximizes bond-breaking and re-forming or necessarily increases energy inputs. (LLM, conf=0.85)

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Research works printed but not linked: 1

  1. 62 Peters, M. S., Timmerhaus, K. D., and West, R. E. (2003). Plant Design and Economics for Engineers, (McGraw-Hill Chemical. Engineering).

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Authors
Shi, C., Reilly, L. T., Phani Kumar, V. S., Coile, M. W., Nicholson, S. R., Broadbelt, L. J., Beckham, G. T., & Chen, E. Y.-X.
Affiliations
  • Colorado State University (US)
  • Northwestern University (US)
  • National Laboratory of the Rockies (US)
Corresponding author
  • Broadbelt, Linda J.
  • Beckham, Gregg T.
  • Chen, Eugene Y.-X.
Venue
Chem
Publisher
Elsevier BV
Published
2021-11
Volume
7
Issue
11
Pages
2896-2912
ISSN
2451-9294 (ISSN-L)
OpenAlex
W3209227621
Cited by
219
References
82
Citations by year
2026: 36 · 2025: 62 · 2024: 49 · 2023: 45 · 2022: 26 · 2021: 1
FWCI
7.78
Type
journal article
Language
en
Open access
Locations
  • Chem (publishedVersion)
  • OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
Funders
  • Bioenergy Technologies Office (DE-AC36-08GO28308)
  • Advanced Manufacturing Office
  • Office of Energy Efficiency and Renewable Energy
  • U.S. Department of Energy
  • National Renewable Energy Laboratory
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
kinetic trapping, depolymerization, thermodynamics and kinetics, predictive modeling, life cycle assessment, techno-economic analysis, sustainable polymers

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