Design principles for intrinsically circular polymers with tunable properties
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Complete depolymerization back to monomer maximizes the number of chemical bonds that must be broken and reformed during recycling, necessitating extreme reaction efficiency and increased energy inputs.
“the complete depolymerization back to monomer maximizes the number of chemical bonds that must be broken and reformed during the recycling process, necessitating extreme reaction efficiency and increased energy inputs”
From Chemically recyclable polyolefin-like multiblock polymers (2023) · cites this paper as [14]
The Perspective (p. 3) says intrinsically circular polymers can be completely deconstructed to monomer by catalysis through a low-energy pathway. It also describes minimizing the energy required for depolymerization under mild conditions. The paper does not state that complete depolymerization maximizes bond-breaking and re-forming or necessarily increases energy inputs. (LLM, conf=0.85)
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- Authors
- Shi, C., Reilly, L. T., Phani Kumar, V. S., Coile, M. W., Nicholson, S. R., Broadbelt, L. J., Beckham, G. T., & Chen, E. Y.-X.
- Affiliations
- Colorado State University (US)
- Northwestern University (US)
- National Laboratory of the Rockies (US)
- Corresponding author
- Broadbelt, Linda J.
- Beckham, Gregg T.
- Chen, Eugene Y.-X.
- ORCID
- Venue
- Chem
- Publisher
- Elsevier BV
- Published
- 2021-11
- Volume
- 7
- Issue
- 11
- Pages
- 2896-2912
- ISSN
- 2451-9294 (ISSN-L)
- OpenAlex
- W3209227621
- Cited by
- 219
- References
- 82
- Citations by year
- 2026: 36 · 2025: 62 · 2024: 49 · 2023: 45 · 2022: 26 · 2021: 1
- FWCI
- 7.78
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Licence
- Locations
- Chem (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Bioenergy Technologies Office (DE-AC36-08GO28308)
- Advanced Manufacturing Office
- Office of Energy Efficiency and Renewable Energy
- U.S. Department of Energy
- National Renewable Energy Laboratory
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- kinetic trapping, depolymerization, thermodynamics and kinetics, predictive modeling, life cycle assessment, techno-economic analysis, sustainable polymers
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