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Handbook of Ring‐Opening Polymerization
Abstract
THERMODYNAMICS AND KINETICS OF RING-OPENING POLYMERIZATION Introduction Thermodynamics of the Ring-Opening Polymerization Kinetics of Ring-Opening Polymerization GENERAL MECHANISMS IN RING-OPENING POLYMERIZATION Introduction Anionic Ring-Opening Polymerization Cationic Ring-Opening Polymerization Radical Ring-Opening Polymerization SILOXANE-CONTAINING POLYMERS Introduction Polydimethylsiloxanes Functional Silicones Polycarbosiloxanes SULFUR-NITROGEN-PHOSPHOROUS-CONTAINING POLYMERS Introduction Mechanism and Methods in Ring-Opening Polymerization (ROP) of Halogenated Cyclotriphosphazanes Ring-Opening Polymerization and Chemistry of Nonhalogenated Phosphazane Rings Incorporation of Sulfur into Phosphazane Ring Systems and Their Polymerization Chemistry POLYMERIZATION OF CYCLIC DEPSIPEPTIDES, UREAS AND URETHANES Introduction Polydepsipeptides Monomers Ring-Opening Polymerization Enzymatic Polymerization Ring Expansion Polyureas Polyurethanes POLYETHERS AND POLYOXAZOLINES Introduction Polyethers Polyoxazolines POLYAMIDES Introduction Mechanism of the Anionic Polymerization of Lactams Initiators for the Anionic Polymerization of Lactams Activators for Anionic Polymerization of Lactams Nonactivated Polymerization Cyclic Oligomers of Epsilon-Caprolactam Block Copolymers of Lactams Anionic Copolymerization of Epsilon-Caprolactam with Omega-Laurolactam Copolymerization of Lactams with Lactones (Epsilon-Caprolactone) Powdered Polyamide Nanocomposites Anionic Polymerization of 2-Pyrrolidone RING-OPENING METATHESIS POLYMERIZATION General Introduction Introduction to Ring-Opening Metathesis Polymerization (ROMP) Well-Defined Catalysts for ROMP 'Living? ROMP Selected Recent Applications and Developments POLYESTERS FROM BETA-LACTONES Introduction Beta-Lactones Preparation Ionic Polymerization Coordination Process Carbene-Based Polymerization Enzymatic Polymerization Illustrative Experimental Section POLYESTERS FROM DILACTONES Introduction General Concepts and ROP Promoted by Metallic Recent Advances in ROP Macromolecular Engineering Applications POLYESTERS FROM LARGE LACTONES Introduction Controlled Synthesis of Linear Polyesters Physical Properties of Polymers POLYCARBONATES Introduction Polymerization of Cyclic Carbonates: Homopolymers and Block Copolymers POLYMERIZATION OF CYCLOALKANES Introduction General Overview and Thermodynamic Requirements Structure-Reactivity Relationships Based on a Comprehensive Survey of the Current Literature METAL-FREE CATALYSIS IN RING-OPENING POLYMERIZATION Introduction Nucleophilic ROP Metal-Free Ionic ROP ENZYME-MEDIATED RING-OPENING POLYMERIZATION Introduction Characteristics of Enzymatic ROP Classes of Monomer Polymer Architectures Employing Enzymatic ROP
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In the citing paper
“for most ROP the driving force is the ring strain and associated steric considerations.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [1]
In the citing paper
“there is the consideration of the ring chain equilibrium, which leads to the considerable influence of the initial monomer concentration and temperature on the microstructure of the products.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [1]
In the citing paper
“RROP offers novel routes to polyesters and polyketones particularly using vinyl substituted cyclic monomers (see Section 2.2) [6].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [6]
In the citing paper
“For the propagation step the Δ H p ≈ 0 kJ mol -1 , but due to the increased rotational freedom of the side chains the Δ S p = +6.7 J mol -1 polymerization does occur.”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [119]
In the citing paper
“Cyclic siloxanes can also undergo ROP via anionic intermediates employing alkali metal oxides or hydroxides as initiators [119].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [119]
In the citing paper
“If other siloxanes with different (e.g., phenyl or methyl) substituents are mixed with D4 statistical copolymers are obtained [119].”
From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [119]
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- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- ring-opening polymerization, ring-opening metathesis polymerization, anionic polymerization, cationic polymerization, radical polymerization, lactam polymerization, caprolactam, cyclic depsipeptides, urethane, polyesters, β-lactones, dilactones, cyclic carbonates, polyoxazoline, polyethers, siloxane-containing polymers, enzymatic polymerization, block copolymers, macromolecular engineering
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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