The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Charge‐Induced Disorder Controls the Thermal Conductivity of Entropy‐Stabilized Oxides
Open accessAbstract
Manipulating a crystalline material's configurational entropy through the introduction of unique atomic species can produce novel materials with desirable mechanical and electrical properties. From a thermal transport perspective, large differences between elemental properties such as mass and interatomic force can reduce the rate at which phonons carry heat and thus reduce the thermal conductivity. Recent advances in materials synthesis are enabling the fabrication of entropy‐stabilized ceramics, opening the door for understanding the implications of extreme disorder on thermal transport. Measuring the structural, mechanical, and thermal properties of single‐crystal entropy‐stabilized oxides, it is shown that local ionic charge disorder can effectively reduce thermal conductivity without compromising mechanical stiffness. These materials demonstrate similar thermal conductivities to their amorphous counterparts, in agreement with the theoretical minimum limit, resulting in this class of material possessing the highest ratio of elastic modulus to thermal conductivity of any isotropic crystal.
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Cites
Analysis of heat flow in layered structures for time-domain thermoreflectance
Cahill, D. G. (2004) · Review of Scientific Instruments · doi:10.1063/1.1819431 · Cited by 1,543
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A frequency-domain thermoreflectance method for the characterization of thermal properties
Schmidt, A. J., Cheaito, R., & Chiesa, M. (2009) · Review of Scientific Instruments · doi:10.1063/1.3212673 · Cited by 543
Liu, J., Zhu, J., Tian, M., Gu, X., Schmidt, A., & Yang, R. (2013) · Review of Scientific Instruments · doi:10.1063/1.4797479 · Cited by 163
Ultralow thermal conductivity of fullerene derivatives
Wang, X., Liman, C. D., Treat, N. D., Chabinyc, M. L., & Cahill, D. G. (2013) · Physical Review B · doi:10.1103/physrevb.88.075310 · Cited by 132
Wei, C., Zheng, X., Cahill, D. G., & Zhao, J.-C. (2013) · Review of Scientific Instruments · doi:10.1063/1.4815867 · Cited by 110
Cited by
Oses, C., Toher, C., & Curtarolo, S. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0170-8 · Cited by 2,081
High‐Entropy Oxides: Fundamental Aspects and Electrochemical Properties
Sarkar, A., Wang, Q., Schiele, A., Chellali, M. R., Bhattacharya, S. S., Wang, D., Brezesinski, T., Hahn, H., Velasco, L., & Breitung, B. (2019) · Advanced Materials · doi:10.1002/adma.201806236 · Cited by 1,234
Review of high entropy ceramics: design, synthesis, structure and properties
Zhang, R.-Z., & Reece, M. J. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta05698j · Cited by 760
Understanding the Role of Entropy in High Entropy Oxides
Aamlid, S. S., Oudah, M., Rottler, J., & Hallas, A. M. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.2c11608 · Cited by 574
Zhao, B., Du, Y., Yan, Z., Rao, L., Chen, G., Yuan, M., Yang, L., Zhang, J., & Che, R. (2023) · Advanced Functional Materials · doi:10.1002/adfm.202209924 · Cited by 493
Metadata
- Authors
- Braun, J. L., Rost, C. M., Lim, M., Giri, A., Olson, D. H., Kotsonis, G. N., Stan, G., Brenner, D. W., Maria, J., & Hopkins, P. E.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-10-17
- Volume
- 30
- Issue
- 51
- Pages
- e1805004-e1805004
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2898600870
- Cited by
- 509
- References
- 6
- FWCI
- 11.84
- Type
- journal article
- Language
- en
- Open access
- green
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- Braun, J. L., Rost, C. M., Lim, M., Giri, A., Olson, D. H., Kotsonis, G. N., Stan, G., Brenner, D. W., Maria, J., & Hopkins, P. E. (2018). Charge‐Induced Disorder Controls the Thermal Conductivity of Entropy‐Stabilized Oxides. Advanced Materials. https://doi.org/10.1002/adma.201805004
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