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Designed Formation of Double‐Shelled Ni–Fe Layered‐Double‐Hydroxide Nanocages for Efficient Oxygen Evolution Reaction

Open access
Zhang, Jintao, Yu, Le, Chen, Ye, Lu, Xue Feng, Gao, Shuyan, Lou, Xiong Wen (David)·2020·Advanced Materials

Abstract

Delicate design of nanostructures for oxygen‐evolution electrocatalysts is an important strategy for accelerating the reaction kinetics of water splitting. In this work, Ni–Fe layered‐double‐hydroxide (LDH) nanocages with tunable shells are synthesized via a facile one‐pot self‐templating method. The number of shells can be precisely controlled by regulating the template etching at the interface. Benefiting from the double‐shelled structure with large electroactive surface area and optimized chemical composition, the hierarchical Ni–Fe LDH nanocages exhibit appealing electrocatalytic activity for the oxygen evolution reaction in alkaline electrolyte. Particularly, double‐shelled Ni–Fe LDH nanocages can achieve a current density of 20 mA cm−2 at a low overpotential of 246 mV with excellent stability.

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Metadata

Authors
Zhang, J., Yu, L., Chen, Y., Lu, X. F., Gao, S., & Lou, X. W. (.
Venue
Advanced Materials
Publisher
Wiley
Published
2020-03-05
Volume
32
Issue
16
Pages
e1906432-e1906432
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W3010470949
Cited by
461
References
8
FWCI
15.95
Type
journal article
Language
en
Open access
bronze
Funders
  • National Research Foundation Singapore (NRF‐NRFI2016‐04)
  • Ministry of Education - Singapore (RG110/17, RG116/18)
  • National Natural Science Foundation of China (U1804255)

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Zhang, J., Yu, L., Chen, Y., Lu, X. F., Gao, S., & Lou, X. W. (. (2020). Designed Formation of Double‐Shelled Ni–Fe Layered‐Double‐Hydroxide Nanocages for Efficient Oxygen Evolution Reaction. Advanced Materials. https://doi.org/10.1002/adma.201906432

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