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Metal−Organic Framework‐Derived Nitrogen‐Doped Core‐Shell‐Structured Porous Fe/Fe3C@C Nanoboxes Supported on Graphene Sheets for Efficient Oxygen Reduction Reactions

Hou, Yang, Huang, Taizhong, Wen, Zhenhai, Mao, Shun, Cui, Shumao, Chen, Junhong·2014·Advanced Energy Materials

Abstract

A novel core-shell-structured hybrid as an oxygen reduction reaction catalyst, consisting of nitrogen-doped porous Fe/Fe3C@C nanoboxes supported on graphene sheets, is synthesized through simple pyrolysis of graphene oxide-supported iron-based metal−organic frameworks. The hybrid exhibits higher electrocatalytic activity than a commercial Pt/C catalyst, excellent long-term stability, and superior methanol tolerance due to the synergistic effect between N-doped Fe/Fe3C@C and N-doped graphene sheets.

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Metadata

Authors
Hou, Y., Huang, T., Wen, Z., Mao, S., Cui, S., & Chen, J.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2014-04-04
Volume
4
Issue
11
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2105870132
Cited by
563
References
10
FWCI
19.76
Type
journal article
Language
en
Open access
closed
Funders
  • U.S. Department of Energy (DE-EE0003208)
  • Research Growth Initiative Program of the University of Wisconsin-Milwaukee (UWM)

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CoChat. (2026). Citation check: Metal−Organic Framework‐Derived Nitrogen‐Doped Core‐Shell‐Structured Porous Fe/Fe3C@C Nanoboxes Supported on Graphene Sheets for Efficient Oxygen Reduction Reactions. https://app.cochat.ai/papers/10.1002/aenm.201400337
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Hou, Y., Huang, T., Wen, Z., Mao, S., Cui, S., & Chen, J. (2014). Metal−Organic Framework‐Derived Nitrogen‐Doped Core‐Shell‐Structured Porous Fe/Fe3C@C Nanoboxes Supported on Graphene Sheets for Efficient Oxygen Reduction Reactions. Advanced Energy Materials. https://doi.org/10.1002/aenm.201400337

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